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Tytuł artykułu

Prognosis of energetic compounds stability in solid phase

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Results of the analysis and specification of phenomenological models of the monomolecular reactions running homogeneously in volume of undisturbed crystal lattice or localized on its defects are presented. It is shown, that within the limits of these models it is possible to calculate with satisfactory accuracy the ratio of rate constants in liquid and solid phases KT = kliq/ksol, and thus on known kliq to predict ksol, describing stability of substance.
Słowa kluczowe
Rocznik
Strony
31--44
Opis fizyczny
Bibliogr. 25 poz.
Twórcy
autor
  • Institute of Problems of Chemical Physics of Russian Academy of Sciences, (IPCP RAS), Semenov av.1, Chernogolovka, Moscow reg, 142432, Russia
Bibliografia
  • [1] Manelis G.B., Nazin G.M., Rubtsov Y.I., Strunin V.A., Thermal Decomposition and Combustion of Explosives and Propellants, Taylor & Francis, Inc., New York 2003, p. 363.
  • [2] Shu Y., Korsunskii B. L., Nazin G.M., The Mechanism of Thermal Decomposition of Secondary Nitramines, Rus. Chem. Revs., 2004, 73(3), 293-307.
  • [3] Lur’e B.A., Svetlov B.S., The Kinetic Parameters of the Primary Stage of the Thermal Decomposition of Organic Nitrates, Kinetics and Catalysis, 1994, 35(2), 165-175 (in Rus.).
  • [4] Stepanov R.S., Kruglyakova L.A., Buka E.S., Kinetics of Thermal Decomposition of Substituted Alkyl- And Arylazides, ibid., 1986, 27(2), 479-482, (in Rus.).
  • [5] Grebennikov V.N., Nazin G.M., Manelis G.B., Thermal Decomposition of α-(Difluoroamino)Polynitroalkanes, Russ. Chem. Bull., 1995, 44(4), 628-630.
  • [6] Stepanov R.S., Astakhov A.M., Kekin Yu.V., Kruglyakova L.A., Influence of the Primary Nitramines’ Structure on their Thermostability. Energetic materials - Production, Processing and Characterization, 29th International ICT-Conference, 1998, Karlsruhe, 128/1-128/7.
  • [7] K orsunskii B.L., Sitonina G.V., Fedorov B.S., Dubovitskii F.I., Eremenko L.T., Kinetics of the Thermal Decomposition of N,N-(Dinitro)Alkylamines, Russ. Chem. Bul., 1989, 38(4), 710-713.
  • [8] Manelis G.B., Some features of the solid-state reaction mechanism, in: Problems of Kinetics of Elementary Chemical Reaction, Nauka, Moscow 1973, 93-106, (In Rus.).
  • [9] D ubikhin V.V., Matveev V.G., Nazin G.M., Prokudin V.G., Stashina G.A., Shastin A.V., Thermal Decomposition of t-Butoxycarbonile Ester of Trimethilenehexahydrotriazine in Solid State, Khimicheskaya fizika (Chemical Physics), 2007, 26(5), 47-51, (in Rus.).
  • [10] Burov Yu.M., Nazin G.M., Manelis G.B., Retardation of Monomolecular Reactions in the Solid Phase., Russ. Chem. Bull., 1999, 48(7), 1250-1254.
  • [11] Hinshelwood C.N., Some Physico-chemical Problems connected with the Stability of Explosives, J. Chem. Soc., 1921, 119/120, 721-734.
  • [12] Z usman L.D. Gel’man A.B., The Theory of Dynamical Reorientation, J. Struct. Chem. (USSR), 1980, 21(1), 72-76 (in Rus.).
  • [13] Choo K.Y., Benson S.W., Arrhenius Parameters for the Alkoxy Radical Decomposition Reactions, Int. J. Chem. Kinetics, 1981, 13(9), 833-844.
  • [14] Benson S.W., Thermochemical kinetics, J. Wiley & Sons, N.Y.–L.–Sydney 1963, p. 223.
  • [15] Voskoboinikov I.M., Afanasenkov A.N., Bogomolov V.M., Generalized Shock Adiabat for Organic Liquids, Combustion, Explosion, and Shock Waves, 1967, 3(4), 285-371.
  • [16] Levitas V.I., Henson B.F., Smilowitz L.B., Asay W., Solid-Solid Phase Transformation via Internal Stress-induced Virtual Melting, Significantly below the Melting Temperature. Application to HMX Energetic Crystal, J. Phys. Chem., 2006, B 110, 10105-10119.
  • [17] Bon S., Decomposition of the Solid Organic Compounds, Ch. 10 in: Chemistry of the Solid State, (W.E. Garner Ed.), Butterworths Scientific Publications, London 1955.
  • [18] Goncharov T.K., Dubikhin V.V., Nazin G.M., Prokudin V.G., Effect of Oxygenated Substituents on Stability Compounds, Having Trinitromethyl Groups, Khimicheskaya fizika (Chemical Physics), 2006, 25(7), 33-37, (in Rus.).
  • [19] Goncharov T.K., Dubikhin V.V., Nazin G.M., Fedorov B.S., Shastin A.V., Determination of induction constant of succinimide group from thermolysis reactivity of nitroehters, Jurnal obchei khimii (J. Chemistry), 2005, 75(6), 954-957, (in Rus.).
  • [20] Maksimov Yu.Ya., Thermal Decomposition of HMX and RD X in: Theory of Explosives, Vysshaya Shkola, Moscow 1967, 53, 73-84, (in Rus.).
  • [21] Shu Yuanjie, Dubikhin V.V., Nazin G.M., Manelis G.B., Thermal Decomposition of Secondary Nitramines in Solutions, 31th Int. Ann. Conf of ICT, Karlsruhe, FRG., 2000, P. 7-1 – 7-13
  • [22] K orsunskii B., Nedelko V., Chukanov N., Larikova T., Folk F., Kinetics of Thermal Decomposition of Hexanitrohexaazaisowurtzitane, 30th Int. Ann. Conf. ICT, Karlsruhe, June 29 - July 2, 1999, 64-1 – 64-20.
  • [23] R obertson A.I.B., Thermal Decomposition of Explosives. II. Cyclotrimethylenetrinitroamine and Cyclotetramethylenetetranitroamine, Trans. Faraday Soс., 1949, 45, 85-93.
  • [24] Erofeev L.N., Tarasov V.P., Kalmykov Yu.B., Shu Yuanjie, Dubikhin V.V., Nazin G.M., Crystal Defects and Stability of RD X, Russ. Chem. Bull., 2001, 50(6), 1000-1002.
  • [25] Andreev K.K., Kaidymov B.I., Thermal Decomposition of Nitroesters. III. Thermal Decomposition of PETN, J. Phys. Chem. USSR, 1961, 35(11), 2676-2688, (in Rus.).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT1-0034-0022
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