The reaction of (methylthio)acetyliron complex with pentose terminal aldehydes

• Autorzy: Wiśniewski K. , Zamojski A.
• Języki publikacji: EN

Abstrakty

EN

The reaction between anion generated from (methylthio)acetyliron complex (1) and four stereoisomeric dialdo-1,4-furanoses was performed. Each aldehyde led to mixtures (6-8) of stereoisomeric aldols. Aldols were separated and their configaration was determined. Decomplexation of these products was studied with oxidative (NCS, Cl2, I2, CuCl2) and reducing (BH3xMe2S and NaBH4) reagents. Sugar derivatives were isolated and their structures were deduced.

Słowa kluczowe

EN

(methylthio)acetyliron complex; pentose aldehydes; aldol reaction; decomplexation; thiosugars

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 8
• Strony: 1937--1948
• Opis fizyczny: Bibliogr. 21 poz., tab.

Twórcy

autor

Wiśniewski K.

autor

Zamojski A.

• Institute of Organic Chemistry Polish Academy of Sciences Kasprzaka 44/52 01-224 Warsaw Poland