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Nickel oxide and chromia supported on ThO2, CeO2 and SiO2 have been tested in oxidative dehydrogenation of isobutane. Both NiO- and Cr2O3-based systems have been found active in this reaction already around 300 degree C, the catalytic performance being dependent on the nature of the support. Chromia-based catalysts are more active and selective as compared with the NiO-based ones. The highest activity and selectivity have been observed for CrOX/CeO2 system. The basicity of the catalysts determined by a probe reaction of the isopropanol dehydrogenation follows the same sequence as the total activity in the oxidative dehydrogenation of isobutane, which suggests an activation of theC-H bond on basic centres of the catalysts.
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Tom
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910--915
Opis fizyczny
Bibliogr. 20 poz., tab.
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- Institute of Catalysis and Surface Chemistry Polish Academy of Sciences 30-239 Kraków ul. Niezapominajek 3 Poland
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Bibliografia
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bwmeta1.element.baztech-article-BAR2-0002-0023