Electrochemical reactions of 1,8-anthraquinonedisulphonate potassium salt

• Autorzy: Socha A.
• Języki publikacji: EN

Abstrakty

EN

Electrochemical reduction of 1,8-anthraquinonedisulphonate potassium salt forms anion radicals (EPR) and anthraquinone after oxidation of reduction products. Linear dependence of E(1/2) of equinone moiety reduction on LUMO energy was used for estimation of reduction potential of probable reaction products. Reduction of quinone moiety is quasireversible and two electrons are exchanged. Desulphonation proceeds in consecutive electrode steps of reduction.

Słowa kluczowe

EN

electroreduction; anthraquinonedisulphonate; anion radicals; LUMO energy; desulphonation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 4
• Strony: 766--776
• Opis fizyczny: Bibliogr. 27 poz.,tab., wykr.

Twórcy

autor

Socha A.

• Institute of General and Ekological Chemistry Technical University of Łódź 90-924 Łódź Poland