Angular overlap treatment of cis-bis(2,2'-bipyridyl)dichlorochromium(III) chloride dihydrate in aqueous solution

• Autorzy: Kurzak K. , Biernacki K.
• Języki publikacji: EN

Abstrakty

EN

Six-coordinate cis-[CrCL2(bipy)2](+) complex (bipy=2,2'-bipyridyl) has been prepared. Electron spectrum of aqueous solution of this complex has been recorded and explained by the angular overlap model (AOM), assuming C-2v symmetry. All transition energies are derived from Gaussian analysis of the spectrum. The calculations of the ligand field parameters take into account all the transitions required in the ligand field (LF) theory (except those energetically higher than the range of the spectrum recorded).

Słowa kluczowe

EN

angular overlap model; electronic spectra; complexes; molecular structure; synthesis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 4
• Strony: 660--666
• Opis fizyczny: Bibliogr. 18 poz. tab., wykr.

Twórcy

autor

Kurzak K.

autor

Biernacki K.

• Department of Chemistry Pedagogical University 08-110 Siedlce Poland