Magnetic shielding tensors of sp-hybridized carbon nuclei

• Autorzy: Gryff-Keller A.
• Języki publikacji: EN

Abstrakty

EN

Experimental data concerning shielding tensors of the sp hybridized carbons including our own recent results have been reviewed. It appears, that the most general feature of shielding parameters for such carbons forms a linear relationship between the perpendicular chemical shift component and the isotropic chemical shift. Deviation from that interdependence informs about a distortion of the symmetry of the electron distribution around the given carbon and indirectly about various intra- or intermolecular interactons.

Słowa kluczowe

EN

shielding tensor; chemical shift anisotropy; sp hybridized carbons

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 2
• Strony: 154--162
• Opis fizyczny: Bibliogr. 60 poz., tab., wykr.

Twórcy

autor

Gryff-Keller A.

• Warsaw University of Technology Faculty of Chemistry ul. Noakowskiego 3 00-664 Warszawa Poland