Synthesis and reaction of organic compounds with a nitrogen atom. Part XII. Reaction of aplha- and beta-pyronene with bis (p-toluenesulfonyl)selenodiimide

• Autorzy: Ścianowski J. , Uzarewicz A.
• Języki publikacji: EN

Abstrakty

EN

Toluenesulfonamidation of alpha-pyronene (1,5,5,6-tetramethyl-1,3-cyclohexadiene) afforded two toluenesulfonamides: N,N'-(1',5',5',6'-tetramethyl-3'-cyclohexan-1',2'-diyl)ditoluenesulfonamide (9) and 4-methyl-N-(4',5',6',6'-tetramethyl-2',4'-cyclohexadien-1'-yl)benzensulfonamide (12). Toluenesulfonamidation of beta-pyronene (1,2,6,6-tetramethyl-1,3-cyclohexadiene) gave N,N'-(3',4',5',5'-tetramethyl-3'-cyclohexen-1',2'-diyl)ditoluenesulfonamide (16). Allylic mono- and ditoluenesulfonamides 9, 12, 16, were reduced by sodium in liquid ammonia to corresponding allylic mono- and diamines 17, 18 i 19.

Słowa kluczowe

EN

toluenesulfonamidation; allylic amines; reduction of toluenesulfonamides

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 1
• Strony: 93--98
• Opis fizyczny: Bibliogr. 12 poz.

Twórcy

autor

Ścianowski J.

autor

Uzarewicz A.

• Faculty of Chemistry Nicolaus Copernicus University 87-100 Toruń Poland