Coordination compounds of Pd(II) and Pt(II) with 3,4,5,6-tetrahydro-2-pyrimidinethiol

• Autorzy: Wiśniewski M. Z. , Głowiak T. , Surga W.J.
• Języki publikacji: EN

Abstrakty

EN

Coordination compounds of Pd(II) and Pt(II) with 3,4,5,6-tetrahydro-2-pyrimidinethiol (THPT) of the general formula M(THPT)4Cl2 H2O, where stands for Pd and Pt, have been obtained and characterized by elemental analysis, X-ray diffraction patterns, derivatography (TG, DTG, DTA), magnetic measurements, and the IR and far-IR spectroscopy. Crystal and molecular structure of the Pd(THPT)4Cl2 H2O have been determined. This compound crystalizes in the monoclinic system with a=8.555(2), b=14.999(3), c=23.324(5) A, beta=91.05(3) degree, V=2832.7(11) A(3) and Z=4; space group P2-1/c. The two compounds have been found to be isostuctural.

Słowa kluczowe

EN

crystal and molecular structure; Pd and Pt complexes

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 10
• Strony: 2226--2231
• Opis fizyczny: Bibliogr. 16 poz., rys., tab.

Twórcy

autor

Wiśniewski M. Z.

autor

Głowiak T.

autor

Surga W.J.

• Institute of Chemistry, Pedagogical University, ul. Chęcińska 5 25-020 Kielce, Poland