Doświadczalne metody badań hydratów gazowych

• Autorzy: Lorenc M. , Warowny W.

Warianty tytułu

EN

Experimental investigations methods of gas hydrates

• Języki publikacji: PL

Abstrakty

PL

Poznanie natury hydratów gazowych opiera się głównie na badaniach doświadczalnych w skali laboratoryjnej i ćwierć-technicznej oraz na teorii popartej obliczeniami i symulacjami komputerowymi. W pracy przedstawiono metody pomiarowe dotyczące tworzenia lub/i zapobiegania tworzenia się hydratów gazowych, badania ich właściwości oraz wykorzystanie w nowych technologiach. Generalnie badania doświadczalne hydratów gazowych i hydratacji można podzielić na kilka grup tematycznych: doświadczalne i obliczeniowe wyznaczanie równowag fazowych, badania parametrów fizykochemicznych i strukturalnych, pomiary kinetyczne, w tym nukleacji i aglomeracji cząsteczek, badania wpływu na hydratację inhibitorów i surfaktantów, możliwość zastosowań technologicznych, w szczególności hydratu metanu, w tym wydobycia, przesyłu, magazynowania i oczyszczania, plus badania geologiczne i geofizyczne w celu oszacowania zasobów hydratu metanu.

EN

Knowledge of the nature gas hydrates is connected mainly with experimental studies in laboratory and pilot plant and theory supported by calculations and computer simulations. In work have been given methods of measurement dealing with: formation and/or prevention of formation gas hydrates, studies their properties, and utilization in new technologies. Generally, studies of the gas hydrates and hydratation can be divided on several thematic groups: experimental and calculated determination of phase equilibrium, studies of the physicochemical and structural parameters, kinetic measurements, including nucleation, and agglomeration of particles, studies influence of inhibitors and surfactants on the hydratation process, possibility of technological applications, especially hydrate of methane, including getting out, transport, storage and purification, plus geological and geophysical studies carried out in order to estimation methane hydrate deposits.

Słowa kluczowe

PL

nukleacja; hydrat; klatraty; metan; eksperymentalne; niestechiometryczne; inhibitor; wiązanie van der Waalsa; wiązanie wodorowe; krystaliczne

EN

hydrate; clathrate; methane; experimental; nucleation; nonstoichiometric; inhibitor; van der Waals bond; hydrogen bond; crystalline

• Wydawca: Wydawnictwa AGH
• Czasopismo: Wiertnictwo, Nafta, Gaz
• Rocznik: 2011
• Tom: T. 28, z. 1-2
• Strony: 227--251
• Opis fizyczny: Bibliogr. 43 poz., rys., tab., wykr.

Twórcy

autor

Lorenc M.

• Dział Informatyki, PGNiG w Warszawie Oddział w Sanoku

autor

Warowny W.

• Wydział Budownictwa, Mechaniki i Petrochemii, Politechnika Warszawska

Bibliografia

• [1] Ding T.: Gas Hydrates to Capture and Sequester CO2. Praca magisterska, Dave C. Swalm School of Chemical Engineering, Mississippi, 2004
• [2] Sloan Jr, E.D.: Clathrate hydrates of natural gases. Marcel Dekker, Inc., New York 1998
• [3] Huang, D., Fan S.: Thermal Conductivity of Methane Hydrate Formed from Sodium Dodecyl Sulfate Solution. J. Chem. Eng. Data, 49, 2004, 1479-1482
• [4] Waite W.F., Helgerud M.B., Nur A., Pinkston J.C., Stern L.A., Kirby S.H., Durham W.B.: Laboratory measurements of compressional and shear wave speeds through methane hydrate. Annals New York Academy of Sciences, Waite et.al.: Compressional and shear wave speeds, 1003-1010
• [5] Carroll J.J.: Natural gas hydrates, a guide for engineers. Gulf Professional Publishing, 2003
• [6] Sloan E.D. Jr.: COMMENTARIES, Clathrate Hydrates: The Other Common Solid Water Phase. Ind. Eng. Chem. Res., 39, 2000, 3123-3129
• [7] Uchida T., Okabe R., Mae S., Ebinuma T., Narita H., In Situ Observations of Methane Hydrate Formation Mechanisms by Raman Spectroscopy. Annals of the New York Academy of Sciences, (www.blackwell-synergy.com - Gas Hydrates: Challenges For The Future), 912, 2000, 593-601
• [8] Seo Y.-T., Lee H.: Multiple-Phase Hydrate Equilibria of the Ternary Carbon Dioxide, Methane, and Water Mixtures. J. Phys. Chem. B, 105, 2001, 10084-10090
• [9] Warowny W.: Hydraty. Gaz, Woda i Technika Sanitarna, 75(3), 2001, 88-94
• [10] Ohmura R., Uchida T., Takeya S., Nagao J., Minagawa H., Ebinuma T., Narita H.: Phase Equilibrium for Structure-H Hydrates Formed with Methane and either Pinacolone (3,3-Dimethyl-2-butanone) or Pinacolyl Alcohol (3,3-Dimethyl-2-butanol). J. Chem. Eng. Data, 48, 2003, 1337-1340
• [11] Ohmura R., Matsuda S., Uchida T., Ebinuma T., Narita H.: Phase Equilibrium for Structure-H Hydrates at Temperatures below the Freezing Point of Water. J. Chem. Eng. Data, 50, 2005, 993-996
• [12] Maekawa T., Imai N.: Equilibrium conditions of methane and ethane hydrates in aqueous electrolyte solutions. Annals New York Academy of Sciences, Maekawa & Imai: Equilibrium conditions, 932-939
• [13] Kini R.A., Dec S.F., Sloan E.D. Jr.: Methane + Propane Structure II Hydrate Formation Kinetics. J. Phys. Chem. A, 108, 2004, 9550-9556
• [14] Maekawa T., Imai M.: Hydrogen and Oxygen Isotope Fractionation in Water during Gas Hydrate Formation. Annals New York Academy of Sciences, Maekawa & Imai: Isotopic fractionation, 452-459
• [15] Lubaś J.: Doświadczalno-teoretyczne stadium zjawisk powstawania i dysocjacji hydratów gazu ziemnego. Prace Instytutu Górnictwa Naftowego i Gazownictwa, Nr 117, Kraków 2002
• [16] Mork M.: Formation rate of natural gas hydrate - reactor experiments and models, Rozprawa doktorska, Norwegian University of Science and Technology, Department of Petroleum Engineering and Applied Geophysics, 2002
• [17] Ostergaard K.K., Tohidi B., Burgass R.W., Danesh A., Todd A.C.: Hydrate phase equilibria of a near critical fluid: Effect of inhibition and separation, American Institute of Chemical Engineers. AIChE Journal, 47(7), ProQuest Science Journals, 2001, 1683
• [18] 0stergaard K.K., Tohidi B., Danesh A., Burgass R.W., Todd A.C., Baxter T.: A Novel Approach for Oil and Gas Separation by Using Gas Hydrate Technology. Annals New York Academy of Sciences, 0stergaard et al.: Oil and gas separation, 832-842
• [19] Karaaslan U., Parlaktuna M.: Promotion Effect of Polymers and Surfactants on Hydrate Formation Rate. Energy & Fuels, 16, 2002, 1413-1416
• [20] Ng H-J.: Hydrate Phase Composition for Multicomponent Gas Mixtures. Annals New York Academy of Sciences, Ng: Hydrate phase composition, 1034-1039
• [21] Eichholz C., Majumdar A., Clarke M.A., Oellrich L.R., Bishnoi P.R.: Experimental Investigation and Calculation of Methane Hydrate Formation Conditions in the Presence of Ethylene Glycol and Sodium Chloride. J. Chem. Eng. Data, 49, 2004 847-851
• [22] Kawamura T., Sakamoto Y., Ohtake M., Yamamoto Y., Komai T., Haneda H., Ji-Ho Yoon: Dissociation Behavior of Pellet-Shaped Methane Hydrate in Ethylene Glycol and Silicone Oil. Part 1: Dissociation above Ice Point. Ind. Eng. Chem. Res., 45, 2006, 360-364
• [23] Zhong Y., Rogers R.E.: Surfactant effects on gas hydrate formation. Pergamon, Chemical Engineering Science, 55, 2000, 4175-4187
• [24] Servio Ph., Englezos P.: Morphology Study of Structure H Hydrate Formation from Water Droplets. Crystal Growth & Design, 3(1), 2003, 61-66
• [25] Link D.D., Ladner E.P., Elsen H.A., Taylor Ch.E.: Formation and dissociation studies for optimizing the uptake of methane by methane hydrates. Elsevier, Fluid Phase Equilibria, 211, 2003, 1-10
• [26] Xie Y., Guo K., Liang D., Fan S., Gu J.: Steady gas hydrate growth along vertical heat transfer tube without stirring. Elsevier, Chemical Engineering Science, 60, 2005, 777-786
• [27] Bollavaram P., Devarakonda S., Selim M.S., Sloan E.D. Jr.: Growth Kinetics of Single Crystal sII Hydrates Elimination of Mass and Heat Transfer Effects. Annals of the New York Academy of Sciences, (www.blackwell-synergy.com - Gas Hydrates: Challenges For The Future), 912, 2000, 533-543
• [28] Hutter J.L., King H.E. Jr., Lin M.Y.: Polymeric Hydrate-Inhibitor Adsorption Measured by Neutron Scattering. Macromolecules, 33, 2000, 2670-2679
• [29] King H.E. Jr., Hutter J.L., Lin M.Y., Sund T.: Polymer conformations of gas-hydrate kinetic inhibitors: A small-angle neutron scattering study. Journal Of Chemical Physics, 112, 2000, 5
• [30] Mikami J., Masuda Y., Uchida T., Satoh T., Takeda H.: Dissociation of Natural Gas Hydrates Observed by X-ray CT Scanner. Annals New York Academy of Sciences, Mikami et al.: Dissociation of NGH, 1011-1020
• [31] Chapoy A., Coquelet Ch., Richon D.: Measurement of the Water Solubility in the Gas Phase of the Ethane + Water Binary System near Hydrate Forming Conditions. J. Chem. Eng. Data, 48, 2003, 957-966
• [32] Servio Ph., Englezos P.: Measurement of Dissolved Methane in Water in Equilibrium with Its Hydrate. J. Chem. Eng. Data, 47, 2002, 87-90
• [33] Fan S., Zhang Y., Tian G.,Liang D., Li D.: Natural Gas Hydrate Dissociation by Presence of Ethylene Glycol. Energy & Fuels, 20, 2006, 324-326
• [34] Kamata Y. i inni: Hydrogen sulfide separation using tetra-n-butyl ammonium bromide semi-clathrate (TBAB) hydrate. Energy & Fuels, 19, 2005, 1717-1722
• [35] Komai T., Yamamoto Y., Ohga K.: Dynamics of reformation and Replacement of CO2 and CH4 Gas Hydrates. Annals New York Academy of Sciences, Komai et al.: Reformation and Replacement of Gas Hydrates, 272-280
• [36] Peters D., Selim M.S., Sloan E.D. Jr.: Hydrate dissociation in pipelines by two-side depressurization. Annal New York Academy of Sciences, Peters et al.: Hydrate dissociation in pipelines, 304-313
• [37] Lee J.D., Susilo R., Englezos P.: Kinetics of Structure H Gas Hydrate. Energy & Fuels, 19, 2005, 1008-1015
• [38] Tsuji H., Ohmura R., Mori Y.H.: Forming Structure-H Hydrates Using Water Spraying in Methane Gas: Effects of Chemical Species of Large-Molecule Guest Substances. Energy & Fuels, 18, 2004, 418-424
• [39] Giavarini C., Maccioni F.: Self-Preservation at Low Pressures of Methane Hydrates with Various Gas Contents. Ind. Eng. Chem. Res., 43, 2004, 6616-6621
• [40] Sun Z-G., Wang R., Ma R., Guo K., Fan S.: Natural gas storage in hydrates with the presence of promoters. Pergamon, Energy Conversion and Management, 44, 2003, 2733-2742
• [41] Lorenc M.: Hydraty w transporcie gazu, Rurociągi, 1(47), 2007, 3-11
• [42] Warowny W., Lorenc M.: Hydraty w transporcie i magazynowaniu gazu ziemnego. Gaz, Woda i Technika Sanitarna, 10, 2006, 24-31
• [43] Lorenc M.: Separacja kwaśnych składników mieszanin gazowych z wykorzystaniem zjawiska hydratacji. Gaz, Woda i Technika Sanitarna, 1, 2007, 2-9