Mikrobiologiczny rozkład alkanów ropopochodnych

• Autorzy: Guzik U. , Wojcieszyńska D. , Krysiak M , Kaczorek E.

Warianty tytułu

EN

Microbiological degradation of petroleum alkanes

• Języki publikacji: PL

Abstrakty

PL

W środowisku naturalnym występują mikroorganizmy odznaczające się zdolnością do biodegradacji alkanów ropopochodnych; zarówno w warunkach tlenowych, jak i beztlenowych. W środowisku aerobowym rozkład prostołańcuchowych alkanów zachodzi trzema drogami: poprzez oksydację terminalną, subterminalną i diterminalną. Utlenianie cyklicznych alkanów przebiega poprzez utlenienie do formy laktonowej, której hydroliza prowadzi ostatecznie do kwasów dikarboksylowych. Degradacja w warunkach beztlenowych wymaga w środowisku obecności alternatywnych akceptorów elektronów. Utlenianie alkanów w środowisku anaerobowym prowadzi – podobnie jak w środowisku aerobowym – do produktów włączanych w centralny metabolizm.

EN

Numerous microorganisms able to utilizing of saturated hydrocarbons as a carbon and energy source under aerobic as well as anaerobic conditions in natural environment was observed. Degradation of aliphatic hydrocarbons in aerobic environment proceeds by terminal, subterminal or diterminal oxidation. Cycloalkanes are transformed by oxidase system to corresponding cyclic alcohols, which are then dehydrated. Monooxygenase lactonises the ring of ketone, subsequently opened by a lactone hydrolase. Product of hydrolysis, dicarboxylic acid is degraded further by beta-oxidation. For degradation under anaerobic conditions of aliphatic hydrocarbons presence of alternative electron acceptors in environment is necessary. Alkanes have to be activated by addition of a fumarate molecule to the alkane. Alkyl-succinate derivative is then linked to CoA and converted into an acyl-CoA, which can be further metabolized by the beta-oxidation.

Słowa kluczowe

PL

alkany ropopochodne; biodegradacja

EN

petroleum alkanes; biodegradation

• Wydawca: Instytut Nafty i Gazu - Państwowy Instytut Badawczy
• Czasopismo: Nafta-Gaz
• Rocznik: 2010
• Tom: R. 66, nr 11
• Strony: 1019--1027
• Opis fizyczny: Bibliogr. 45 poz., rys.

Twórcy

autor

Guzik U.

autor

Wojcieszyńska D.

autor

Krysiak M

autor

Kaczorek E.

• Uniwersytet Śląski, Katedra Biochemii, Katowice

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