The chlorinated synthetic diamond surface interaction with C-nucleophiles

• Autorzy: Korolkov V.V. , Tarasevich B.N. , Kulakova I.I. , Lisichkin G.V.
• Języki publikacji: EN

Abstrakty

EN

Several reactions of C-nucleophiles with the chlorinated surface of two types of diamond were implemented. Detonating nanodiamond "UDA-SF" and synthetic diamond "DALAN" have been employed in the above procedures. The incorporation of butyl and nitrile groups has been achieved. However the incorporating of phenyl groups via reaction with PhLi is still a problem. For the first time NMR-H1 spectroscopy of suspension was used for elucidating structure of grafting compounds was proposed.

Słowa kluczowe

EN

nanodiamonds; grafting compounds; surface chemistry; chemical functionalization

PL

nanodiamenty; chemia powierzchni

• Wydawca: Polskie Stowarzyszenie Biomateriałów
• Czasopismo: Inżynieria Biomateriałów
• Rocznik: 2006
• Tom: R. 9, nr 56-57
• Strony: 16--19
• Opis fizyczny: Bibliogr. 7 poz., rys., wykr.

Twórcy

autor

Korolkov V.V.

• Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1, Build. 3, Moscow, 119992, Russia

autor

Tarasevich B.N.

• Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1, Build. 3, Moscow, 119992, Russia

autor

Kulakova I.I.

• Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1, Build. 3, Moscow, 119992, Russia

autor

Lisichkin G.V.

• Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1, Build. 3, Moscow, 119992, Russia

Bibliografia

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• [3] Y. Liu, Z. Gu, J. L. Margrave, V.N. Khabashesku Functionalization of Nanoscale Diamond Powder: Fluoro-, Alkyl-, Amino-, and Amino Acid-Nanodiamond Derivates // Chem. Mater. - 2004, - 16, 20. – P. 3924-3930.
• [4] Yu Liu, V.N. Khabashesku, N.J. Halas Florinated Nanodiamond as a Wet Chemistry Precursor for Diamond Coatings Covalently Bonded to Glass Surface // JACS. - 2005. 127, 11. - P. 3712-3713.
• [5] A. Xiaoning, Z. Hanmin Functionalization of carbon nanobeads and their use as metal ion adsorbents // Carbon - 2003. - 41, 15. – P. 2889-2896.
• [6] Jiang Tianlai, Xu Kang, Ji Shengfu FTIR studies on the spectral changes of the surface functional groups of ultradispersed diamond powered synthesized by explosive detonation after treatment in hydrogen, nitrogen, methane and air at different temperatures // J. Chem. Soc. Faraday Trans. -1996. - 92, 18. - P. 3401-3406.
• [7] T. Jiang, K. Xu FTIR study of ultradispersed diamond powder synthesis by explosive detonation // Carbon. - 1995. - 33. - P. 1663-1671.