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Tytuł artykułu

Effect of nanosilica and ZnO nanoparticles on abrasion and UV resistance of waterborne polyurethane coating

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this paper, commercial nano zinc oxide (nano-ZnO) and nanosilica (nano-SiO2) were employed as fillers to improve the properties of abrasion and UV resistance in a waterborne polyurethane coating. Various dispersion techniques were studied to prevent the aggregation of primary nanoparticles in the polyol mixture. The nanoparticles dispersion was studied by OM and SEM. Polyols containing nanoparticles were mixed with the suitable isocyanate amount to obtain a polyurethane water based coatings. The resultant polyurethane nanocomposite was characterized according to abrasion resistance (ASTM D 4060) and QUV resistance (ASTM D 4587). Abrasion resistance was improved adding different percentages of nanosilica nanoparticles but no improvement was obtained regarding UV resistance. Nano zinc oxide nanoparticles contributed to enhance neither abrasion nor UV resistance, maybe due to catalytic reaction of nano-ZnO over PUR matrix.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
3--10
Opis fizyczny
Bibliogr. 14 poz., rys.
Twórcy
  • AIMPLAS Plastics Technology Centre, Spain
  • AIMPLAS Plastics Technology Centre, Spain
Bibliografia
  • 1. B.K. Kim et al. Properties of Waterborne Polyurethane/Nanosilica Composite. Macromol. Res., Vol. 11, No. 3, pp 198-201 (2003).
  • 2. S. Zhang et al. Effect of silica nanoparticles on structure and properties of waterborne UV-curable polyurethane nanocomposites. Poly. Bull. (2012) 68:1469-1482.
  • 3. Sung-II Lee et al. Polyurethane/silica composites, prepared via in-situ polymerization in the presence of chemically modified silicas. J. Ind. Eng. Chem., Vol.13, No 5 (2007) 786-792.
  • 4. M.M. Jalili et al. Investigating the variations in properties of 2-pack polyurethane clear coat through separate incorporation of hydrophilic and hydrophobic nano-silica. Progress in Organic Coatings 59 (2007) 81-87.
  • 5. Z, Ranjbar, S. Rastegar. The influence of surface chemistry of nano-silica on microestructure, optical and mechanical properties of the nano-silica containing clear-coats. Progress in Organic Coatings 65 (2009) 125-130.
  • 6. Jayashree Salla, Krishna K. Pandey, Kavyashree Srinivas. Improvement of UV resistance of wood surfaces by using ZnO nanoparticles. Polymer Degradation and Stability 97 (2012) 592-596.
  • 7. Wang Zhen Yu, Liu Fuchun et al. Effect of ZnO nanoparticles on anti-aging properties of polyurethane coating. Chinese science bulletin, 2009, 54:3464-3472.
  • 8. X-Y Ma, W.-D. Zhang. Effect of flower-like ZnO nano-whiskers on the mechanical, termal and antibacterial properties of waterborne polyurethane. Polymer Deg-radation and stability 94 (2009) 1103-1109.
  • 9. J.H. Li at al. Effects on ZnO nanoparticles on the mechanical and antibacterial properties of polyurethanes coatings. Progress in organic Coatings 64 (2009) 504-509.
  • 10. Dolatzadeth, Moradian and Jlili. Effect of nano silica on moisture absortion of polyurethane clear coats as studied by EIS and gravimetric methods. Prog. Color Colorants coat. 3 (2010), 92-100.
  • 11. A.M. Rabea et al. Surface analysis and anti-graffiti behavior of a weathered polyurethane based coating embedded with hydrophobic nanosilica. Applied Surface Science 258 (2012) 4391-4396.
  • 12. J.Salla et Al. Improvement of UV resistance of wood surfaces by using ZnO nanoparticles. Polymer Degra¬dation and stability 97 (2012] 592-596.
  • 13. S. K. Dhoke, Narayani Rajgopalan, A. S. Khanna. Effect of Nano-Zinc Oxide Particles on the Performance Behavior of Waterborne Polyurethane Composite Coatings. International Journal of Material Science IJMSCI Vol.2 Iss.2 2012, 47-55.
  • 14. M.Sudha, M.Rajarajan. Deactivation of photocatalytically active ZnO nanoparticle by surface capping with poly vinyl pyrrolidone. Journal of Aplied Chemistry. Volume 3, Issue 3 (Jan-Feb, 2013), 45-53.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-affaf266-d683-4fa7-98a1-ad93fd9117c1
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