Fuel recovery from plastic and organic wastes with the help of mineralogical catalysts

• Autorzy: Sarıkap Mehmet Can , Çebi Fatma Hoş

Identyfikatory

DOI

10.24425/aep.2023.147325

• Języki publikacji: EN

Abstrakty

EN

Plastics are one of the most widely used materials, and, in most cases, they are designed to have long life spans. Since plastic and packaging waste pollute the environment for many years, their disposal is of great importance for the environment and human health. In this paper, a system was developed to store liquid fuel from plastic and organic waste mixes without solidification, which then can be used as fuel in motor vehicles and construction machinery. For this purpose, polyethylene terephthalate (PET), polyvinyl chloride (PVC), and organic wastes and clay, zeolite, and MCS23-code materials (50% magnetite-%25 calcium oxide-%25 sodium chloride) were heated in a closed medium at temperatures ranging from 300 to 400°C and subsequently re-condensed. The study conducted twenty tests, involving various types and rates of plastic and organic materials, as well as different rates of catalysts. Among these tests, the highest liquid fuel yield (67.47%) was achieved in Test 9, where 50% PVC50% PET waste, 75 g of clinoptilolite, and 500 g of MCS23 waste were collectively used. Notably, Test 12 exhibited the highest density value (79.8 kg/m3), while the best viscosity value (2.794 mm2/s) was observed in Test 2. Across all samples, flash point values were found to be below 40°C. The most favorable yield point value was recorded in Test 2 (-6°C). The samples displayed ash content within the range of 0 to 0.01% (m/m)] and combustion heat values of 35.000> J/g which fall within the standard range. The incorporation of MCS23 with clinoptilolite additives is believed to have a significant impact on obtaining high-yield products with improved fuel properties.

Słowa kluczowe

EN

geologic catalyst; clinoptilolite; plastic waste; organic waste; liquid fuel

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2023
• Tom: Vol. 49, no 3
• Strony: 16--25
• Opis fizyczny: Bibliogr. 41 poz., rys., tab., wykr.

Twórcy

autor

Sarıkap Mehmet Can

• Office of Project and Technology, İstanbul University-Cerrahpaşa, İstanbul, Türkiye

autor

Çebi Fatma Hoş

•  Department of Geological Engineering, Karadeniz Technical University, Trabzon, Türkiye

Bibliografia

• 1. Allende S., Brodie G. & Jacob M.V. (2022) Energy recovery from sugarcane bagasse under varying microwave-assisted pyrolysis conditions, Bioresource Technology Reports, 20, 101283, ISSN 2589-014X, DOI: 10.1016/j.biteb.2022.101283
• 2. Damodharan D., Kumar B.R., Gopal K., De Poures M.V. & Sethuramasamyraja B., (2019). Utilization of waste plastic oil in diesel engines: a review. Reviews in Environmental Science and Bio/Technology. 18, pp. 681-697. DOI: 10.1007/s11157-019-09516-x
• 3. DIN, DIN 51900-2, 2003. Petroleum products – Petroleum products – Determination of Heat of Combustion – Bomb Calorimetry Method, Berlin. DOI: 10.31030/9447973
• 4. Dorado C., Mullen C.A. & Boateng A.A., (2014). Origin of carbon in aromatic and olefin products derived from HZSM-5catalyzed co-pyrolysis of cellulose and plastics via isotopic labeling. Applied CatalysisB: Environmental. 162, pp. 338-345. DOI: 10.1016/j.apcatb.2014.07.006
• 5. Erşen T, & Pehlivan D, 2011. High density polyethylene – Co-pyrolysis of wood blends. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 26, pp. 607-612.
• 6. Kalargaris I., Tian G. & Gu S., (2017). The utilisation of oils produced from plastic waste at different pyrolysis temperatures in a DI diesel engine. Energy. 131, pp. 179-185. DOI: 10.1016/j.energy.2017.05.024
• 7. Kaminsky W. & Kim J.S., (1999). Pyrolysis of mixed plastics into aromatics. Journal of Analytical and Applied Pyrolysis. 51, pp. 127-134. DOI: 10.1016/S01652370(99)00012-1
• 8. Kaminsky W., Predel M. & Sadiki A., (2004). Feedstock recycling of polymers by pyrolysis in a fluidised bed. Polymer Degradation and Stability. 85, pp. 1045-1050, 146. DOI: 10.1016/j.polymdegradstab.2003.05.002
• 9. Kirov N.Y. & Peck M.A. (1970). Characteristics of chars from fluid-bed coal carbonization, Fuel, 49( 4), pp. 375-394. DOI: 10.1016/S0016-2361(70)80003-5.
• 10. Krishnamurthy S., Shah Y.T. & Stiegalt G.J. (1980). Pyrolysis of coal liquids, Fuel, 59(11), pp. 738-746. DOI: 10.1016/0016-2361(80)90247-1
• 11. Lee D-J., (2022). Gasification of municipal solid waste (MSW) as a cleaner final disposal route: A mini-review. Bioresource Technology. 344, 126217. DOI: 10.1016/j.biortech.2021.126217
• 12. Liu B., Han Z., Li J. & Yan B. (2022). Comprehensive evaluation of municipal solid waste power generation and carbon emission potential in Tianjin based on Grey Relation Analysis and Long Short Term Memory. Process Safety and Environmental Protection, 168, pp. 918-927. DOI: 10.1016/j.psep.2022.10.065
• 13. Liu Q., Sheng Y. & Wang Z. (2023). Co-pyrolysis with pine sawdust reduces the environmental risks of copper and zinc in dredged sediment and improves its adsorption capacity for cadmium. Journal of Environmental Management, 334, 117502, DOI: 10.1016/j.jenvman.2023.117502
• 14. Mazumdar B.K. & Chatterjee N.N. (1973). Mechanism of coal pyrolysis in relation to industrial practice. Fuel, 52(1), pp. 11-19. DOI: 10.1016/0016-2361(73)90005-7
• 15. Ma J., Feng S., Zhang Z., Wang Z., Kong W., Yuan P., Shen B. & Mu L. (2022). Pyrolysis characteristics of biodried products derived from municipal organic wastes: Synergistic effect of bulking agents and modification of biodegradation, Environmental Research. 206, 112300., DOI: 10.1016/j.envres.2021.112300
• 16. Miranda R., Pakdel H., Roy C. & Vasile C., (2001). Vacuum pyrolysis of commingled plastics containing PVC II. Product analysis. Polymer Degradation and Stability. 73, pp.47-67. DOI: 10.1016/S0141-3910(01)00066-0
• 17. Öngen A., Karabag N., Yiğit H.S., Özcan H.K., Elmaslar Ö.E. & Aydın S., (2019). An Assessment of Pyrolysis Process for the Treatment of Agricultural and Forest Wastes. Recyclıng And Reuse Approaches For Better Sustaınabılıty. pp. 97110. DOI: 10.1007/978-3-319-95888-0_9
• 18. Öngen A., Özcan H.K. & Elmaslar Ozbas E. (2016). Gasification of biomass and treatment sludge in a fixed bed gasifier. Internatıonal Journal of Hydrogen Energy, vol.41(19), 8146-8153. DOI: 10.1016/j.ijhydene.2015.11.159
• 19. Öngen A., Özcan H.K., Elmaslar Özbaş, E. & Pangaliyev Y. (2019). Gasification of waste tires in a circulating fixed-bed reactor within the scope of waste to energy. Clean Technologies and Environmental Policy,.21,pp. 1281-1291. DOI: 10.1007/s10098-019-01705-0
• 20. Özcan H.K., Öngen A. & Pangaliyev Y., (2016). An Experimental Study of Recoverable Products from Waste Tire Pyrolysis. Global Nest Journal. 3, pp. 582-590. DOI: 10.30955/gnj.001907
• 21. Pan R. & Debenest G., (2022). Numerical investigation of a novel smoldering-driven reactor for plastic waste pyrolysis. Energy Conversion and Management, 257, 115439.DOI: 10.1016/j.enconman.2022.115439.
• 22. Pan R., Martins M.F. & Debenest G., (2022). Optimization of oil production through ex-situ catalytic pyrolysis of waste polyethylene with activated carbon. Energy, 248, 123514. DOI: 10.1016/j.energy.2022.123514
• 23. Pan R., Lougou B. G., Shuai Y. & Debenest G. (2023). A multidimensional numeric study on smoldering-driven pyrolysis of waste polypropylene. Process Safety and Environmental Protection, 172, pp. 305-316. DOI: 10.1016/j.psep.2023.02.018
• 24. Papari S., Bamdad H. & Berruti F. (2021). Pyrolytic conversion of plastic waste to value-added products and fuels: A Review. Materials. 14(10), 2586. DOI: 10.3390/ma14102586
• 25. Pinto F., Costa P., Gülyurtlu I. & Cabrita I. (1999). Pyrolysis of plastic wastes. 1. Effect of plastic waste composition on product yield. Journal of Analytical and Applied Pyrolysis. 51, pp. 39-55. DOI: 10.1016/S0165-2370(99)00007-8
• 26. Saliba M., Frantzi S. & Beukering P. (2022). Shipping spills and plastic pollution: A review of maritime governance in the North Sea. Marine Pollution Bulletin, 181, 113939, DOI: 10.1016/j.marpolbul.2022.113939
• 27. Schafer H.N.S. (1979). Pyrolysis of brown coals. 2. Decomposition of acidic groups on heating in the range 100–900 °C. Fuel, 58(9), pp. 673-679. DOI: 10.1016/0016-2361(79)90222-9
• 28. Sharma B.K., Moser B.R., Vermillion K.E., Doll K.M. & Rajagopalan N. (2014). Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags. Fuel Processing Technology. 122, pp. 79-90. DOI: 10.1016/j.fuproc.2014.01.019
• 29. Sogancioglu M., Ahmetli G. & Yel E. (2017). A Comparative Study on Waste Plastic Pyrolysis Liquid Products Quantity and Energy Recovery Potential. Energy Procedia, 118, pp.221-226. DOI: 10.1016/j.egypro.2017.07.020
• 30. TS, TS 1233 ISO 3016, (1997). Petroleum products-Determination of pour point, Ankara. https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073081055057051113111083082048090121
• 31. TS, TS 1451 EN ISO 3104, (1999). Petroleum products-Transparent and opaque liquids-Kinematic viscosity determination and calculation of dynamic viscosity, Ankara. https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073083077102090084083076053089099056
• 32. TS, TS 6147 EN ISO 12937, (2002). Petroleum products- Water determination- Calometric Karl fischer titration method, Ankara. https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073081107087097053098049101074085051
• 33. TS, TS EN ISO 12185, (2007). Crude oil and petroleum products- Density determination - oscillating u-Tube method, Ankara. https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073087088047079051101109088047113066
• 34. TS, TS EN ISO 2719, (2016). Petroleum products and lubricants - Determination of flash point - Pensky Martens closed cup method, Ankara. https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073082090086090075081118122084111048
• 35. TS, TS EN ISO 6245, (2006). Petroleum products – Ash determination, Ankara. https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073084090047056119107056057109067090)
• 36. Williams P.T. & Williams E.A. (1999). Interaction of Plastics in Mixed-Plastics Pyrolysis. Energy & Fuels.13, pp. 188-196. DOI:10.1021/ef980163x
• 37. Williams P.T. & Slaney E. (2007). Analysis of products from the pyrolysis and liquefaction of single plastics and waste plastic mixtures. Resources, Conservation and Recycling. 51, pp. 754-769. DOI: 10.1016/j.resconrec.2006.12.002
• 38. Varank G., Öngen A., Guvenc S. Y., Ozcan H. K., Ozbas E. & Guven E.C. (2022). Modeling and optimization of syngas production from biomass gasification. International Journal of Envıronmental Science and Technology, 19(4), pp. 3345-3358. DOI: 10.1007/s13762-021-03374-3
• 39. Vinti G., Bauza V., Clasen T., Tudor T., Zurbrügg C. & Vaccari M. (2023). Health risks of solid waste management practices in rural Ghana: A semi-quantitative approach toward a solid waste safety plan. Environmental Research, 216(3), 114728. DOI: 10.1016/j.envres.2022.114728
• 40. Zhang C., Hu M., Maio F., Sprecher B., Yang X. & Tukker A. (2022). An overview of the waste hierarchy framework for analyzing the circularity in construction and demolition waste management in Europe. Science of The Total Environment, 803, 149892. DOI: 10.1016/j.scitotenv.2021.149892 .
• 41. Zhang J., Jin J., Wang M., Naidu R., Liu Y., Man Y.B., Liang X., Wong M.H., Christie P., Zhang Y., Song C. & Shan S. (2020). Co-pyrolysis of sewage sludge and rice husk/ bamboo sawdust for biochar with high aromaticity and low metal mobility. Environmental Research, 191, 110034. DOI: 10.1016/j.envres.2020.110034

Uwagi

PL

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).