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Supported liquids membranes are very promising products. They have been intensively inves-tigated in last two decades and widely used in many technologies especially in gas separation and purifi-cation processes. A key aspect in obtaining satisfying effectiveness and long membrane lifetime is a proper choice of ionic liquid and polymeric or ceramic support. Properties of both affect the processes of obtaining useful supported ionic liquid membranes. In comparison to polymeric membranes, ceramic ones are slightly thicker, however they are thermally and mechanically more stable. Our research was aimed at sintering fine glass particles of 500 to 45 μm in size in order to prepare porous membranes which can be used as supports for liquid membranes. Dextrin and borax were used as pore-making agents. The membranes, as disks 35 mm in diameter and 3 mm of thickness, were prepared. The porosity was determined using absorption method. It was found, that the porosity could be controlled by changing the applied pressure from 1 to 5 MPa, particle size distribution, sintering temperature, type and amount of pore-enhancing agents.
Słowa kluczowe
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Tom
Strony
287--300
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- Department of Chemical Technology, Chemical Faculty, Gdansk University of Technology, 80-952 Gdansk, Poland
autor
- Department of Chemical Technology, Chemical Faculty, Gdansk University of Technology, 80-952 Gdansk, Poland
autor
- Department of Chemical Technology, Chemical Faculty, Gdansk University of Technology, 80-952 Gdansk, Poland,
autor
- Department of Chemical Technology, Chemical Faculty, Gdansk University of Technology, 80-952 Gdansk
Bibliografia
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- 2. CIECIŃSKA M., 2007, Szkła odpadowe do produkcji specjalnych materiałów porowatych. Szkło i Ceramika, 58, 9–13.
- 3. GAMER A.O., ROSSBACHER R., KAUFMANN W., VAN RAVENZWAAY B., 2008, The inhalation toxicity of di- and triethanolamine upon repeated exposure. Food Chem. Toxicol., 46, 2173–2183.
- 4. HERNANDEZ-FERNANDEZ F.J., DE LOS RIOS A.P., ALONSO F.T., PALACIOS J.M., WILLORA G., 2009, Preparation of supported ionic liquid membranes: Influence of the ionic liquid immobilization method on their operational stability. J. Mem. Sci., 341, 172–177.
- 5. JOSKOWSKA M., KOPCZYNSKA I., DEBSKI B., HOLOWNIA-KEDZIA D., ARANOWSKI R., HUPKA J., 2012, Wetting of supports by ionic liquids used in gas separation processes. Physicochem. Probl. Miner. Process., 48, 129–140.
- 6. KITTEL J., IDEM R., GELOWITZ D., TONTIWACHWUTHIKUL P., PARRAIN G., BONNEAU A., 2009, Corrosion in MEA units for CO2 capture: pilot plant studies. Energy Procedia, 1, 791–797.
- 7. PN–EN 1389:2005, 2005, Techniczna ceramika zaawansowana – Kopozyty ceramiczne – Właściwości fizyczne – Oznaczanie gęstości i porowatości otwartej.
- 8. KOSMULSKI M., SANELUTA C., MARCZEWSKA-BOCZKOWSKA K., KURZYDŁOWSKI K., KONOPKA K., OZIĘBŁO A., SZAFRAN M.,LIPIEC W., Kompozyt ceramika ciecz–jonowa i sposób wytwarzania kompozytu ceramika–ciecz jonowa, P. Warszawska, Editor. 2009: Warszawa, Polska, 1–6.
- 9. KURAOKA K., AMAKAWA R., MATSUMOTO K., ZAYAWA T., 2000, Preparation of molecular+ sieving glass hollow fiber membranes based on phase separation. J. Mem. Sci., 175, 215–223.
- 10. KURAOKA K., QUN Z., KUSHIBE K., YAZAWA T., 1998, Trail for preparation of glass capillary membranes by elution of alkali metal ions. Sep. Purif. Technol., 33, 297–309.
- 11. LETCHER T.M., Thermodynamics, solubility and environmental issues, ed. Elsevier. 2007, Amsterdam: Elsevier.
- 12. PERNAK J., 2000, Ciecze jonowe – rozpuszczalniki XXI wieku. Przem. Chem., 79, 150–153.
- 13. SCHAFFER A., BRECHTEL K., SCHEFFKNECHT G., 2011, Comparative study on differently concentrated aqueous solutions of MEA and TETA for CO2 capture from flue gas. Fuel, doi:10.1016/j.fuel.2011.06.037.
- 14. SEHELEKHIN A.B., DIXON A.G., MA Y.H., 1992, Adsorption, permeation, and diffusion of gases in microporous membranes. II. Permeation of gases in microporous glass membranes. J. Mem. Sci., 75, 233–244.
- 15. SIEBOLD A., NARDIN M., SCHULTZ J., WALLISER A., OPPLIGER M., 2000, Effect of dynamic contact nagles on capillary rise phenomena. Colloid and Surfaces A, 161, 81–87.
- 16. STUDENBACKER M.L., SNOW C.W, 1955, The influence of ultimeta composition upon the wettability of carbon blacks. J. Phys. Chem., 59, 973–976.
- 17. TRONG D., HUPKA J., DRZYMAŁA J., 2006, Impact of roughness on hydrophobicity of paricles measured by the Washburn method. Physicochem. Probl. Miner. Process., 40, 45–52.
- 18. WALCZYK H., 2006, Niskotemperaturowa kondensacja lotnych związków organicznych w obecności gazu inertnego w spiralnym wymienniku ciepła. Prace Naukowe Instytutu Inżynierii Chemicznej PAN, 6, 7–127.
- 19. WASHBURN, E.W., 1921, The dynamics of capillary flow. Phys. Rev., 17, 273-283.
- 20. WAY J.D., ROBERTS D.L., 1992, Hollow Fiber Inorganic Membranes for Gas Separations. Sep. Purif. Technol., 27, 29–41.
- 21. WEIXING L., WEIHONG X., NANPING X., 2006, Modeling of relationship between water permeability and microstructure parameters of ceramic membranes. Desalination, 192, 340–345.
- 22. WOLFROM R.L., CHANDER S., HOGG R., 2002, Evaluation of capillary rise methods for determining wettability of powders. Miner. Metall. Proc., 19, 198–202.
- 23. YANAGISAWA K., BAO N., SHEN L., ONDA A., KAJIYOSHI K., MATAMORAS-VELOZA Z., RENDON-ANGELES J.C., 2006, Development of a technique to prepare porous materials from glasses. J. Eur. Ceram. Soc., 26, 761–765.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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