Hybrid nanobiocomposites based on poly(3-hydroxybutyrate) : characterization, thermal and mechanical properties

• Autorzy: Zarzycka Iwona , Czerniecka-Kubicka Anna , Szyszkowska Agnieszka , Pyda Marek , Frącz Wiesław , Byczyński Łukasz , Sedlarik Vladimir

Identyfikatory

DOI

10.37190/ABB-01473-2019-02

• Języki publikacji: EN

Abstrakty

EN

Poly(3-hydroxybutyrate) is a biopolymer used to production of implants in the human body. On the other hand, the physical and mechanical properties of poly(3-hydroxybutyrate) are compared to the properties of isotactic polypropylene what makes poly(3-hydroxybutyrate) possible substitute for polypropylene. Unfortunately, the melting point of poly(3-hydroxybutyrate) is almost equal to its degradation temperature what gives very narrow window of its processing conditions. Therefore, numerous attempts are being made to improve the poly(3-hydroxybutyrate) properties. In the present work, hybrid nanobiocomposites based on poly(3-hydroxybutyrate) as a matrix with the use of organic nanoclay – Cloisite 30B and linear polyurethane as a second filler have been manufactured. The linear polyurethane was based on diphenylmethane 4,4′-diisocyanate and diol with imidazoquinazoline rings. The obtained nanobiocomposites were characterized by X-ray diffraction, scanning and transmission electron microscopies, thermogravimetry, differential scanning calorimetry and their selected mechanical properties were tested. The resulting hybrid nanobiocomposites have intercalated/exfoliated structure. The nanobiocomposites are characterized by a higher thermal stability and a wider range of processing temperatures compared to the unfilled matrix. The plasticizing influence of nanofillers was also observed. In addition, the mechanical properties of the discussed nanobiocomposites were examined and compared to those of the unfilled poly(3-hydroxybutyrate). The new-obtained nanobiocomposites based on poly(3-hydroxybutyrate) containing 1% Cloisite 30B and 5 wt. % of the linear of polyurethane characterized the highest improvement of processing conditions. They have the biggest difference between the temperature of degradation and the onset melting temperature, about 100 °C.

Słowa kluczowe

EN

hybrid nanobiocomposites poly(3-hydroxybutyrate); nanoclay; linear polyurethanes; thermal stability; mechanical properties

PL

nanoglinka; stabilność termiczna; właściwości mechaniczne

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Acta of Bioengineering and Biomechanics
• Rocznik: 2020
• Tom: Vol. 22, no. 1
• Strony: 97--110
• Opis fizyczny: Bibliogr. 25 poz., rys., tab., wykr.

Twórcy

autor

Zarzycka Iwona

• Department of Organic Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland

autor

Czerniecka-Kubicka Anna

• Department of Experimental and Clinical Pharmacology, Faculty of Medicine, The University of Rzeszow, Rzeszów, Poland
• Department of Integrated Design Systems and Tribology, Faculty of Mechanics and Technology, Rzeszow University of Technology, Stalowa Wola, Poland

autor

Szyszkowska Agnieszka

• Department of Organic Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland

autor

Pyda Marek

• Department of Organic Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland

autor

Frącz Wiesław

• Department of Integrated Design Systems and Tribology, Faculty of Mechanics and Technology, Rzeszow University of Technology, Stalowa Wola, Poland

autor

Byczyński Łukasz

• Department of Polymers and Biopolymers, Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland

autor

Sedlarik Vladimir

• Centre of Polymer Systems, Tomas Bata University in Zlin, Czech Republic

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).