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Recovery of Alum from Surabaya Water Treatment Sludge using Electrolysis with Carbon-Silver Electrodes

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Untreated alum sludge from Surabaya water treatment plant (WTP), which contained high concentration of alum was directly discharged into Surabaya River. It might cause problems because of the accumulation of aluminum in the lower part of the river. Alum could be recovered from the drinking water sludge using the electrolysis method. Aims of this study were to determine the optimum pH and electrical current for electrolysis using carbon-silver electrodes to recover aluminum coagulant from the sludge, and to determine the amount of the recovered alum. The sludge was acidified prior to electrolysis. Acidification was done by adding sulfuric acid at pH 3 and 4. Polarization test was conducted at 100, 200, and 300 mA, in order to determine the optimum electrical current. The electrolysis was performed in one compartment batch recirculation reactor, using silver as cathode and carbon as anode for 10 hours. Values of pH were measured every hour. The precipitated matter in the cathode was weighed, and analysed by means of Inductively Coupled Plasma. The optimum conditions of the electrolysis were achieved at initial pH 3 and electrical current 300 mA. The electrolysis resulted in the highest precipitate of 2.6112 g in the cathode.
Słowa kluczowe
Rocznik
Strony
126--133
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
  • Department of Environmental Engineering, Faculty of Civil, Environmental, and Geo-Engineering Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya, 60111, Indonesia
  • Department of Environmental Engineering, Faculty of Civil, Environmental, and Geo-Engineering Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya, 60111, Indonesia
  • Department of Environmental Engineering, Faculty of Civil, Environmental, and Geo-Engineering Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya, 60111, Indonesia
  • Department of Environmental Engineering, Faculty of Civil, Environmental, and Geo-Engineering Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya, 60111, Indonesia
Bibliografia
  • 1. Ahmad M.A. 2011. Analysis of the effect of electrical voltage to the thickness of chrome coating on steel plates with electroplating process [thesis]. Department of Mechanical Engineering, Universitas Hasanudin: Makassar. (In Indonesian)
  • 2. Ahmad T., Ahmad K., Alam M. 2016. Sustainable management of water treatment sludge through 3‘R’ concept. Journal of Cleaner Production, 124, 1–13.
  • 3. APHA. 2012. Standard methods for the examination of water and wastewater 22th ed. Washington, DC: American Public Health Association.
  • 4. Bahena J.L.R., Cabrera A.R., Valdivieso A.L., and Urbina R.H. 2002. Fluoride adsorption onto α-Al2O3 and its effect on the zeta potential at the alumina – aqueous electrolyte interface. Science Technology, 37, 1973–1987.
  • 5. Buddhi D., Kothari R., and Sawhney R.L. 2006. An experimental study on the effect of electrolytic concentration on the rate of hydrogen production. International Journal of Green Energy, 3 (4), 381–395.
  • 6. Chen X., Chen G., and Yue P.L. 2000. Separation of pollutants from restaurant wastewater by electrocoagulation. Sep. Purification Technologie, 19: 65–76.
  • 7. Cheng W.P., Fu C.H., Chen P.H., and Fang Y. 2012. Dynamics of aluminum leaching from water purification sludge. Journal of Hazardous Materials, 217, 149–155.
  • 8. Dahhou M. 2017. Drinking water sludge of the Moroccan capital: statistical analysis of its environmental aspects. Journal of Taibah University for Science, 749–758.
  • 9. Dassanayake K.B., Jayasinghe G.Y., and Surapaneni A. 2015. A review on alum sludge with special reference to agricultural applications and future challenges. Waste Management Journal, 38, 321–335.
  • 10. EPA (United States Environmental Protection Agency). 2011. Drinking water treatment plant residuals management technical report: EPA 820-R-11–003. United States: Environmental Protection Agency.
  • 11. Georgantas D.A. and Grigoropoulou H.P. 2005. Phosphorus removal from synthetic and municipal wastewater using spent alum sludge. Water Science & Technology, 52, 525–532.
  • 12. Hanim A., Azam M., Hidayanto E., and Nuraini E. 2007. Determination of aluminum, manganese, and silicon elements in the Code River to sampling time with AANC method. Berkala Fisika, 10 (1), 25–30. (In Indonesian)
  • 13. Huang C., Xu T., Zhang Y., Xue Y., and Chen G. 2007. Application of electrodialysis to the production of organic acids: state-of-the-art and recent developments. Journal of Membrane Science, 288: 1–12.
  • 14. Huitle C.A.M., Rodrigo M.A., and Scialdone O. 2018. Electrochemical water and wastewater treatment. Cambridge, Elsevie.
  • 15. Ippolito J.A., Barbarick K.A., and Elliott H.A. 2011. Drinking water treatment residuals: A review of recent uses. Journal of Environmental Quality, 40 (1), 1–12.
  • 16. Mortula M., Bard S.M., Walsh M.E., and Gagnon G.A. 2009. Aluminum toxicity and ecological risk assessment of dried alum residual into surface water. Journal of Civil Engineering, 36, 127–136.
  • 17. Primadipta I.W., and Titah H.S. 2017. Bioremediation of alum sludge using Aspergillus niger with adding sawdust as bulking agent. Jurnal Teknik ITS, 6 (1), 95–99. (In Indonesian).
  • 18. Selintung M. and Azikin. 2012. Handling of sludge from Somba Opu water treatment plant. Science & Tecnology Universitas Hasanuddin, 5 (2), 1–11. (In Indonesian)
  • 19. Selvakumar K.V., Badarinarayanan N.S., Umesh A., Ezhilkumar P., and Yuvanashree E. 2016. Acid dye degradation using electrochemical batch recirculation flow reactor. Journal of Chemical and Pharmaceutical Sciences, 9 (1), 308–312.
  • 20. Sengupta A.K. 2002. Process for selective coagulant recovery from water treatment plant sludge. Pat. No US 6945047 B1.
  • 21. Songa C., Chua C.J., Tanga Y., Zhanga J.L., Lib J., Zhanga J., Wang K., McDermidb S., and Kozakb P. 2008. Voltage jump during polarization of a PEM fuel cell operated at low relative humidities. Int. Journal Hydrogen Energy, 33.
  • 22. Varcoe J.R., Atanassov P., Dekel D.R., Herring A.M., Nijmeijer K., Scott K., Xu T., and Zhuang L. 2014. Anion exchange membranes in electrochemical energy sytems. Energy Environment Science, 7: 3135–3191.
  • 23. Widayatno T., Gupita L.T., Novitasari P., and Imaswati S. 2016. Silver recovery from wastewater of washing X-ray photos: electrochemical characterization. Simposium Nasional RAPI XV UMS. (In Indonesian)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-af1daf80-378d-49d4-9058-13471a27f5cc
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