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The targeted modification of the material composition is a common procedure used to improve the parameters of the final products. This paper deals with the targeted modification of polymer systems composition using two various types of alternative fillers. The first type of alternative filler (SVD) has been obtained from energetics where it arises as a by-product of flue gas desulfurization. The second alternative filler used (KAL) is based on waste from glass production. The elastomeric systems designed for the production of car tires and solid wheels for transport systems were used in the role of modified polymer systems. Alternative fillers (SVD, KAL) have been applied as a substitution of commonly used fillers (carbon black, silica). The filler – elastomeric matrix interaction, rheology, cure characteristics, as well as hardness and rebound resilience of vulcanizates, which are important parameters for their industrial application, have been studied in the new prepared polymeric systems. The main output of the work is a new formulation of an elastomeric system for industrial applications with high rebound resilience and low rolling resistance, which is the subject of the international patent. The modification of composition using raw material substitution can also bring significant environmental and economic effects.
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Tom
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art. no. e136721
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Bibliogr. 21 poz., rys., tab.
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autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
autor
- Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
Bibliografia
- [1] D. Ondrušová, M. Pajtášová, and I. Labaj, “Elastomer mixture and method of its preparation”, Patent PCT/SK2019/050015(2020). Available on: https://patentscope.wipo.int/search/en/detail. jsf?docId=WO2020130952&_cid=P21-KBV9GG-52072-1
- [2] L.M. McKeen, “Thermoplastic Polyurethane Elastomers (TPU)”, in Permeability Properties of Plastics and Elastomers chapter 12.1 pp. 251‒285, (3rd Edition). USA, Elsevier, 2012.
- [3] I. Kücükrendeci, “The investigation of suitable welding parameters in polypropylene sheets joined with friction stir welding”, Bull. Pol. Acad. Sci. Tech. Sci. 67(1), 133‒140 (2019), doi: 10.24425/bpas.2019.127342.
- [4] D. Ondrušová, I. Labaj, M. Pajtášová, and J. Vršková, “Preparation and properties of new elastomeric systems containing alternative fillers”, MATEC Web of Conferences 254(8), 07003 (2019), doi: 10.1051/matecconf/201925407003.
- [5] D. Ondrušová, I. Labaj, J. Vršková, M. Pajtášová, and V. Mezencevová, “Application of alternative additives in the polymer composite systems used in automotive industry”, IOP Conf. Ser.: Mater. Sci. Eng. 776, 012101 (2020).
- [6] J. Vršková, D. Ondrušová, I. Labaj, and I. Kopal, “Effect of alternative filler from glass industry on the selected properties of friction polymermatrix in automotive industry”, IOP Conf. Ser.: Mater. Sci. Eng. 776, 012106 (2020).
- [7] M. Pajtášová, D. Ondrušová, R. Janík, Z. Mičicová, B. Pecušová, I. Labaj, M. Kohutiar, and K. Moricová, “Using of alternative fillers based on the waste and its effect on the rubber properties”, MATEC Web of Conferences 254(8), 04010 (2019).
- [8] I. Labaj, D. Ondrušová, J, Vršková, and M. Kohutiar, “The effect of various alternative filler granularity on the properties of elastomeric vulcanizate”, IOP Conf. Ser.: Mater. Sci. Eng. 776, 012098 (2020).
- [9] W. Dierkes, “Raw materials and compounds”, Twente: University of Twente, (2007). [Online]. http://laroverket.com/wpcontent/uploads/2015/03/Raw_materials_and_compounds.pdf
- [10] Z. Zhenglong, S. Bin, L. Jiangang, D. Zhiguang, and H. Zhongbo, “Research on ride comfort performance of a metal tire”, Bull. Pol. Acad. Sci. Tech. Sci. 68(3), 491‒502 (2020), doi: 10.24425/ bpasts.2020.133384.
- [11] P.E.P. Giannelis, “Polymer-layered silicate nanocomposites: synthesis, properties and applications”, Appl. Organomet. Chem. 12, 675–680 (1998).
- [12] A. Limper, Mixing of Rubber Compounds, p.192, Munich: Hanser Publishers, 2012.
- [13] J.S. Dick, “Technology – Compounding and Testing for Performance”, in Rubber Mixing, 2nd Edition, chapter XXIII, pp. 504‒522, Munich: Hanser Publishers, 2009.
- [14] J. D. Vicente, Rheology, p. 338, Rijeka: InTech, 2012.
- [15] ASTM D2084–01, 2001, Standard Test Method for Rubber Property—Vulcanization Using Oscillating Disk Cure Meter ,USA: Plan Tech Inc.
- [16] ASTM D2240–15, 2017, Standard Test Method for Rubber Property—Durometer Hardness, USA: Plan Tech Inc.
- [17] B. Banerjee, “Rubbers, Compounding Ingredients and their Criterion in Tyre Retreading” in Tyre Retreading, chapter I, pp. 1–29, Shawbury: Smithers Rapra Technology Ltd., 2015.
- [18] J.S. Dick, “ODR Cure Test Parameters”, in Basic Rubber Testing – Selecting Methods for A Rubber Test Program, USA: ASTM International, 2003
- [19] J.S. Dick, Rubber Technology – Compounding and Testing for Performance, p. 592, 2nd Edition, Hanser Publishers, Munich, 2009.
- [20] S.R. Khimi and K.L. Pickerink, “A New Method to Predict Optimum Cure Time of Rubber Compound Using Dynamic Mechanical Analysis”, J. Appl. Polym. Sci. 131, 1‒6 2014, doi: 10.1002/ app.40008.
- [21] S. Futamura, “Elastomer compositions for tire treads having low rolling resistance and good wet and dry grip traction”, European Patent Specification EP0234303B1, 1986. [Online]. https://patents.google.com/patent/EP0234303B1/en
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
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Bibliografia
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bwmeta1.element.baztech-aef6272b-155e-43eb-a8a6-fd086a951ac9