Effect of metal addition of Cu, Ni, and Fe on swelling Zeolit Alam Lampung (ZAL) to present amphoteric features on Cu-Ni-Fe/ZAL swelling

• Autorzy: Susmanto Prahady , Intang Ambo , Bustan Muhammad Djoni , Haryati Sri

Identyfikatory

DOI

10.2478/pjct-2024-0034

• Języki publikacji: EN

Abstrakty

EN

The main challenge in using Zeolit Alam Lampung (ZAL) as a catalyst lies in controlling its acidic nature which is influenced by the content of alkali metals, alkaline earth metals, transition metals, and Si/Al ratio. Controlling by reducing and adding metals with higher acidity is necessary. This research involved two stages: ZAL Swelling formation followed by adding Cu, Ni, and Fe metals to make a Cu-Ni-Fe/ZAL Swelling catalyst. The acid distribution analysis using the NH₃-TPD profile test showed that the Cu-Ni-Fe/ZAL swelling catalyst exhibited higher Lewis-type acidity and more uniform distribution compared to Brønsted acid. The addition of Cu, Ni, and Fe metals can modify the acidity strength of ZAL Swelling to form Cu-Ni-Fe/ZAL Swelling catalysts with Lewis and Brønsted sites at lower temperatures (120–550 °C) compared to ZAL Swelling (120–750 °C). This gives an idea about the optimization of the arrangement of Lewis and Bronsted acid sites to present amphoteric features.

Słowa kluczowe

EN

Zeolit Alam Lampung; Natural Zeolite; Bronsted Acid; Lewis Acid; Amphoteric Features

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2024
• Tom: Vol. 26, nr 4
• Strony: 8--16
• Opis fizyczny: Bibliogr. 61 poz., rys., tab., wz.

Twórcy

autor

Susmanto Prahady

• Department of Doctoral Engineering, Faculty of Engineering, Sriwijaya University, Indonesia
• Department of Chemical Engineering, Faculty of Engineering, Sriwijaya University, Indonesia

autor

Intang Ambo

• Department of Doctoral Engineering, Faculty of Engineering, Sriwijaya University, Indonesia

autor

Bustan Muhammad Djoni

• Department of Doctoral Engineering, Faculty of Engineering, Sriwijaya University, Indonesia
• Department of Chemical Engineering, Faculty of Engineering, Sriwijaya University, Indonesia

autor

Haryati Sri

• Department of Doctoral Engineering, Faculty of Engineering, Sriwijaya University, Indonesia
• Department of Chemical Engineering, Faculty of Engineering, Sriwijaya University, Indonesia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).