Polyurethane shape memory polymer: structure characterization and estimation of energy storage and dissipation during the tension process

• Autorzy: Staszczak Maria , Gradys Arkadiusz , Golasiński Karol , Pieczyska Elżbieta A.

Identyfikatory

DOI

10.24425/bpasts.2023.147343

• Języki publikacji: EN

Abstrakty

EN

Shape memory polymers (SMP) are new multifunctional materials raising increasing interest in various functional applications. Among them, polyurethane shape memory polymers (PU-SMP) are particularly attractive due to their combination of shape memory, high strength and biocompatible properties. Developing new applications for PU-SMP requires comprehensive research on their characteristics. This work involved investigating the structure and mechanical behavior as well as characterizing the energy storage and dissipation of a thermoplastic PU-SMP with a glass transition temperature (Tg) of 25_C during tensile loading-unloading. The process of energy storage and dissipation in the PU-SMP was investigated based on the stress-strain curves recorded by a quasi-static testing machine and the temperature changes, accompanying the deformation process, obtained by using a fast and sensitive infrared camera. The results showed that the thermomechanical behavior of the examined PU-SMP depends significantly on the strain rate. At a higher strain rate, there are higher stress and related temperature changes, which lead to greater energy dissipation. However, the energy storage values estimated during the deformation process turned out to be not significant, indicating that the work supplied to the PU-SMP structure during loading is mainly converted into heat. It should also be noted that the structural investigation revealed no crystalline phase in the investigated PU-SMP.

Słowa kluczowe

EN

shape memory polymer; SMP; infrared camera; energy storage; energy dissipation; tension test; thermomechanical coupling

PL

polimer z pamięcią kształtu; SMP; kamera na podczerwień; magazynowanie energii; rozpraszanie energii; sprzęgło termomechniczne; próba napięciowa

• Wydawca: Polska Akademia Nauk, Wydział IV Nauk Technicznych
• Czasopismo: Bulletin of the Polish Academy of Sciences. Technical Sciences
• Rocznik: 2023
• Tom: Vol. 71, nr 6
• Strony: art. no. e147343
• Opis fizyczny: Bibliogr. 62 poz., rys., tab.

Twórcy

autor

Staszczak Maria

• Institute of Fundamental Technological Research, Polish Academy of Sciences, Pawińskiego 5B, 02-106 Warsaw, Poland

• https://orcid.org/0000-0002-2593-9482

autor

Gradys Arkadiusz

• Multidisciplinary Research Center, Cardinal Stefan Wyszyński University in Warsaw, Dewajtis 5, 01-815 Warsaw, Poland

• https://orcid.org/0000-0002-9489-6236

autor

Golasiński Karol

• Institute of Fundamental Technological Research, Polish Academy of Sciences, Pawińskiego 5B, 02-106 Warsaw, Poland

• https://orcid.org/0000-0002-0314-9543

autor

Pieczyska Elżbieta A.

• Institute of Fundamental Technological Research, Polish Academy of Sciences, Pawińskiego 5B, 02-106 Warsaw, Poland

• https://orcid.org/0000-0001-9231-8056

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).