Efficient and sensitive quantification of polar tobacco volatile organic compounds by a micro thermal-assisted sampling device using reduced graphene oxide coupling with thermal desorption-gas chromatography/mass spektrometry

• Autorzy: Lai Yanhua , Han Bing , Wu Jiahui , Weng Shouhui , Chen Senlin , Wang Junxia , Wang Yu , Pan Xiaowei , Lin Yun , Tao Hong , Zhang Zhuomin , Li Gongke

Identyfikatory

DOI

10.1556/1326.2023.01161

• Języki publikacji: EN

Abstrakty

EN

It still remains a great challenge to selectively enrich and sensitively quantify the trace volatile organic compounds (VOCs) in real samples with complex matrix. In this study, an integration method combining a selective enrichment medium of reduced graphene oxide (rGO) with a specially designed micro thermal-assisted purge-and-trap sampling device was developed for efficient enrichment and sensitive quantification of trace tobacco VOCs coupling with thermal desorption (TD)-gas chromatography/ mass spectrometry (GC/MS). The prepared rGO has been proved to possess excellent enrichment selectivity and capacity for tobacco polar VOCs with the multi-layer structure, good thermal stability and large specific surface area. The specially designed sampling device was efficient and suitable for enriching and sampling trace polar tobacco VOCs coupling with rGO medium. Under the optimized sampling and analytical conditions, the established analytical method could be actually applied for quantification of typical tobacco polar VOCs with the good recoveries of 72.9–128% and the satisfied RSDs of 1.8–19.9% (n 5 3). The results suggested that the developed method was selective, sensitive and reliable for enrichment and quantification of trace tobacco polar VOCs.

Słowa kluczowe

EN

reduced graphene oxide; sampling devices; polar volatile organic compounds; thermal desorption; GC/MS

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2024
• Tom: Vol. 36, no. 3
• Strony: 263--272
• Opis fizyczny: Bibliogr. 39 poz., rys., wykr.

Twórcy

autor

Lai Yanhua

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Han Bing

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Wu Jiahui

• School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China

autor

Weng Shouhui

• School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China

autor

Chen Senlin

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Wang Junxia

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Wang Yu

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Pan Xiaowei

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Lin Yun

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

autor

Tao Hong

• Technology Centre, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China

• https://orcid.org/0009-0007-8475-4932

autor

Zhang Zhuomin

• School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China

• https://orcid.org/0000-0003-1430-3996

autor

Li Gongke

• School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China

• https://orcid.org/0000-0003-3750-6358

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