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Synthesis of citrates of selected lanthanides (Er, Ho and Lu)

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Holmium, erbium and lutetium citrates can be synthesized by transforming freshly precipitated holmium, erbium and lutetium hydroxides in the citric acid solution under the hydrothermal conditions (above 100 ℃) after 3 days of reaction. In this paper in order to determine the synthesis conditions, the hydroxide and citrate stability areas of selected lanthanides were compared. The studies of the structure of the obtained holmium citrate, erbium and lutetium samples showed that these compounds crystallize in a monoclinic system. The crystallite sizes determined by the HalderWagner method were 67.8 ± 8.0nm, 103.7 ± 4.5nm and 68.1 ± 4.2nm, respectively for the holmium citrate, erbium citrate and lutetium citrate samples. The shifts of the hydroxyl and carboxyl groups of citric acid in the FTIR spectrum indicate the interactions of both groups with holmium, erbium and lutetium cations. Then the obtained samples were subjected to the analysis of composition, and their particle size distribution was determined.
Rocznik
Strony
225--234
Opis fizyczny
Bibliogr. 30 poz., rys., wykr., wz.
Twórcy
  • Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20 031 Lublin, Poland.
  • Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20 031 Lublin, Poland.
autor
  • Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20 031 Lublin, Poland.
  • ewunias@hektor.umcs.lublin.pl
  • Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20 031 Lublin, Poland.
Bibliografia
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  • BAGGIO, R., PEREC, M., 2004. Isolation and Characterization of a Polymeric Lanthanum Citrate. Inorg. Chem.43, 6965- 6968.
  • BANERJEE, S., PILLAI, M. R. A., KNAPP, F. F.,2015. Lutetium-177 Therapeutic Radiopharmaceuticals: Linking Chemistry, Radiochemistry, and Practical Applications, Chem. Rev. 115, 2934-2874. DOI: 10.1021/cr500171e.
  • BERTOLI, C., CARVALHO, R., FREITAS, M.P., RAMALHO, T.C., MANCINI, D.T., OLIVEIRA, M.C., DE VARENNES, A., DIAS, A., 2015 Theoretical spectroscopic studies and identification of metal-citrate (Cd and Pb) complexes by ESI-MS in aqueous solution. Spectrochim. Acta A.137, 271–280.
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  • BICHARA, L.C., LANUS, H.E., FERRER, E.G., GRAMAJO, M.B., BRANDAN, S.A., 2011. Vibrational Study and Force Field of the Citric Acid Dimer Based on the SQM Methodology. Advances in Physical Chemistry.
  • BOULTIF, A., LOUER, D., 2004. Powder pattern indexing with the dichotomy method. J. Appl. Cryst.37, 724-731.
  • BRZYSKA, W., 1987. Lantanowce i aktynowce. WNT, Warszawa.
  • CHANDLER, C.D., ROGER, C., HAMPDEN-SMITH, M.J., 1993. Chemical Aspects of Solution Routes to PerovskitePhase Mixed-Metal Oxides from Metal-Organic Precursors. Chem. Rev.93, 1205-1241.
  • EANM, 2003. EANM Procedure Guidelines for Radiosynovectomy. Eur. J. Nucl. Med. 30:BP12–BP16.
  • GAJBHIYE, N.S., BHATTACHARYA, U., DARSHANE, V.S., 1995. Thermal decomposition of zinc-iron citrate precursor. Therm. Acta. 264,219-230.
  • GAJBHIYE, N.S., PRASAD, S., 1996. Thermal decomposition of hexahydrated nickel iron citrate. Thermochim. Acta. 285, 325-336.
  • GAJBHIYE, N.S., BHATTACHARYA, U., DARSHANE, V.S., 1995. Thermal decomposition of zinc-iron citrate precursor. Thermochim. Acta. 264, 219-230.
  • HALDER, N.C., WAGNER, C.N.J., 1966. Separation of particle size and lattice strain in integral breadth measurements. Acta Crystallogr. 20(2), 312–331.
  • JUMANATH, E.C., PRADYUMNAN, P.P., 2019. Growth and structural studies of hybrid single crystal of cadmium citrate hexahydrate. J. Mol. Struct. 1193, 231-238.
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  • LIU, S.G., LIU, W., ZUO, J.L., LI, Y.Z., YOU, X.Z., 2005. Synthesis, structure and luminescent properties of lanthanide(III) polymeric complexes constructed by citric acid. Inorg. Chem. Com. 8, 328–330.
  • MILLER, M.E., MCKINNON, L.P., WALKER, E.B., 2015. Quantitative measurement of metal chelation by fourier transform infrared spectroscopy. Anal. Chem. Res. 6, 32-35.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-acd72e0a-8026-449d-8f8b-b7506d6ff31c
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