Application of M2+ (Magnesium, Zinc)/Alumina-Metal Oxide Composites as Photocatalysts for the Degradation of Cationic Dyes

• Autorzy: Yuliasari Nova , Wijaya Alfan , Amri , Mohadi Risfidian , Elfita , Lesbani Aldes

Identyfikatory

DOI

10.12912/27197050/150374

• Języki publikacji: EN

Abstrakty

EN

The development of studies on layered double hydroxide (LDH) material as a photocatalyst for the degradation of dye pollutants continues to increase. LDH is an anionic clay, which is a natural or synthetic mixed metal hydroxide. Pristine LDH is written as M²⁺/M³⁺ LDH, (M is metal ion). This study prepared pristine Mg/Al LDH and Zn/Al LDH composited with metal oxide TiO₂ and ZnO, respectively. Composite is denoted by M²⁺/M³⁺ -metal oxide. The coprecipitation method used was accompanied by calcination of the composite at a temperature 300 °C that was not high. The prepared composites were morphologically characterized by SEM. The materials that had been used until the fifth cycle of regeneration were characterized by XRD and FTIR which still indicated the presence of LDH-metal oxide composite structure. The materials degraded cationic dyes namely rhodamine-B (RhB) and methylene blue (MB). RhB degraded better than MB by pristine LDH and composites. The percent degradation of RhB for pristine Mg/Al LDH, composites Mg/Al-TiO₂ and Mg/Al-ZnO were 53.1%, 59.8%, 62.8%, respectively. The percent RhB degradation for pristine Zn/Al LDH, composites Zn/Al-TiO₂ and Zn/Al-ZnO were 51.4%, 58.5%, 58.9%, respectively. The percentage of degradation indicates that the LDH-metal oxide composite has succeeded in increasing the photodegradation catalytic ability and the regeneration ability of LDH pristine.

Słowa kluczowe

EN

photodegradation; layered double hydroxide; TiO2; ZnO; dye

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2022
• Tom: Vol. 23, iss. 4
• Strony: 125--135
• Opis fizyczny: Bibliogr. 31 poz., rys.

Twórcy

autor

Yuliasari Nova

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia

• https://orcid.org/0000-0002-1755-7548

autor

Wijaya Alfan

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia

• https://orcid.org/0000-0001-9974-9764

autor

Amri

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia

• https://orcid.org/0000-0003-0216-3834

autor

Mohadi Risfidian

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia
• Magister Programme Graduate School of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang-South Sumatra, Indonesia

• https://orcid.org/0000-0003-4974-4329

autor

Elfita

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia

• https://orcid.org/0000-0003-2527-6639

autor

Lesbani Aldes

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia
• Doctoral Program, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang 30139, Indonesia

• https://orcid.org/0000-0001-5054-2324

Bibliografia

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