4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and Its Silver Salt − Synthesis and Characterization

• Autorzy: Musil T. , Matyáš R. , Zeman S. , Růžička A. , Lyčka A. , Majzlík J. , Vala R. , Knotek P.

Identyfikatory

DOI

10.22211/cejem/70730

• Języki publikacji: EN

Abstrakty

EN

4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and its silver salt (AgTNADAzT) were prepared and characterized. Elemental analysis, FTIR, NMR, DSC, AAS and X-ray diffraction were used for analytical characterization. The sensitivities of TNADAzT and AgTNADAzT were determined and compared with common explosives and MTX-1. The crystal density of TNADAzT is 1.794 g·cm−3 and its heat of formation 899 kJ·mol−1. The sensitivity of TNADAzT to impact and friction slightly exceeds PETN; the sensitivity to electrostatic discharge is lower than RDX. The sensitivity of AgTNADAzT is on the level of a primary explosives (between mercury fulminate and PETN). The initiation efficiency of AgTNADAzT is higher than 200 mg (acceptor PETN compressed by 64-70 MPa) and therefore excludes it from practical use as a primary explosive in detonators.

Słowa kluczowe

EN

azido derivative of triazine; silver salt; sensitivity; MTX-1; X-ray

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2017
• Tom: Vol. 14, no. 2
• Strony: 304--320
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Musil T.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Matyáš R.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Zeman S.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Růžička A.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Lyčka A.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Majzlík J.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Vala R.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

autor

Knotek P.

• Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentska 95, 532 10 Pardubice, Czech Republic

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