Graphene oxide-multiwalled carbon nanotubes composite as an anode for lithium ion batteries

• Autorzy: Majchrzycki Ł. , Walkowiak M. , Martyła A. , Yablokov M. Y. , Nowicki M. , Czajka R.

Identyfikatory

DOI

10.1515/msp-2016-009

• Języki publikacji: EN

Abstrakty

EN

Nowadays reduced graphene oxide (rGO) is regarded as a highly interesting material which is appropriate for possible applications in electrochemistry, especially in lithium-ion batteries (LIBs). Several methods were proposed for the preparation of rGO-based electrodes, resulting in high-capacity LIBs anodes. However, the mechanism of lithium storage in rGO and related materials is still not well understood. In this work we focused on the proposed mechanism of favorable bonding sites induced by additional functionalities attached to the graphene planes. This mechanism might increase the capacity of electrodes. In order to verify this hypothesis the composite of non-reduced graphene oxide (GO) with multiwalled carbon nanotubes electrodes was fabricated. Electrochemical properties of GO composite anodes were studied in comparison with similarly prepared electrodes based on rGO. This allowed us to estimate the impact of functional groups on the reversible capacity changes. As a result, it was shown that oxygen containing functional groups of GO do not create, in noticeable way, additional active sites for the electrochemical reactions of lithium storage, contrary to what has been postulated previously.

Słowa kluczowe

EN

graphene oxide; reduced graphene oxide; Li-ion battery; composite anode; porous electrode

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2016
• Tom: Vol. 34, No. 3
• Strony: 481--486
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Majchrzycki Ł.

• Institute of Non-Ferrous Metals, Poznań Branch, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland
• Institute of Physics, Poznań University of Technology, Piotrowo 3, 60-965 Poznan, Poland
• Wielkopolska Center for Advanced Technologies, Umultowska 89C, 61-614 Poznań, Poland

autor

Walkowiak M.

• Institute of Non-Ferrous Metals, Poznań Branch, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland

autor

Martyła A.

• Institute of Non-Ferrous Metals, Poznań Branch, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland

autor

Yablokov M. Y.

• Russian Academy of Sciences, Enikolopov Institute of Synthetic Polymer Materials, 70 Profsoyuznaya St., 117393 Moscow, Russian Federation

autor

Nowicki M.

• Institute of Physics, Poznań University of Technology, Piotrowo 3, 60-965 Poznan, Poland

autor

Czajka R.

• Institute of Physics, Poznań University of Technology, Piotrowo 3, 60-965 Poznan, Poland

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.