Surfactant-aided membrane process for copper ion removal from water solutions

• Autorzy: Klimonda A. , Kowalska I.
• Języki publikacji: EN

Abstrakty

EN

The usefulness of micellar-enhanced ultrafiltration (MEUF) for copper ion removal was evaluated. The experiments were performed in a semi-pilot installation in a cross-flow regime with the use of ultrafiltration modules (5 kDa and 10 kDa). The first stage of the tests included copper ion removal in the classic UF process. During the next step, anionic surfactant (sodium dodecylbenzenesulfonate, SDBS) was added to the feed solution in a wide range of concentrations. The effect of copper and surfactant concentrations on separation efficiency and permeate flux was evaluated. It was found that MEUF enables high copper ion removal. Depending on surfactant concentration in the feed solution, the average copper concentration in the permeate was in the range from 0.02 to 0.08 mM (feed solution 0.79 mM). Surfactant rejection was strongly dependent on its concentration in the feed; the highest retention was obtained when surfactant was in the form of micelles, i.e., for concentrations exceeding the CMC.

Słowa kluczowe

EN

copper; anionic surfactants; metal ions

PL

miedź; surfaktant; roztwór wodny

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2018
• Tom: Vol. 44, nr 1
• Strony: 141--152
• Opis fizyczny: Bibliogr. 32 poz., tab., rys.

Twórcy

autor

Klimonda A.

• Faculty of Environmental Engineering, Wrocław University of Science and Technology, Wybrzeże Wyspianskiego 27, Wroclaw; 50-370, Poland

autor

Kowalska I.

• Faculty of Environmental Engineering, Wrocław University of Science and Technology, Wybrzeże Wyspianskiego 27, Wroclaw; 50-370, Poland

Bibliografia

• [1] BARAKAT M.A., New trends in removing heavy metals from industrial wastewater, Arab. J. Chem., 2011, 4, 361.
• [2] AL-RASHDII B.A.M., JOHNSON D.J., HILAL N., Removal of heavy metal ions by nanofiltration, Desalination, 2013, 315, 2.
• [3] QDAIS H.A., MOUSSA H., Removal of heavy metals from wastewater my membrane processes. A comparative study, Desalination, 2004, 164, 105.
• [4] ZAGHBANI N., HAFIANE A., DHAHBI M., Removal of Erichrome Blue Black R from wastewater using micellar enhanced ultrafiltration, J. Hazard. Mater., 2009, 168, 1417.
• [5] JIN-HUI H., YA-LAN X., GUANG-MING Z., SHAO-HUI G., GENG-XIN X., DONG-MEI Z., XIAO-JIAO T., ZHI-FENG L., Separation of phenol from various micellar solutions using MEUF, Sep. Purif. Technol., 2012, 98, 1.
• [6] GEANTA R.M., RUIZ M.O., ESCUDERO I., Micellar-enhanced ultrafiltration for the recovery of lactic acid and citric acid from beet molasses with sodium dodecyl sulphate, J. Membrane Sci., 2013, 430, 11.
• [7] ACERO J.L., BENITEZ J., REAL F.J., TEVA F., Removal of emerging contaminants from secondary effluents by micellar-enhanced ultrafiltration, Sep. Purif. Technol., 2017, 181, 123.
• [8] EXALL K., BALAKRISHNAN V.K., TOITO J., MCFADYEN R., Impact of selected wastewater constituents on the removal of sulfonamide antibiotics via ultrafiltration and micellar enhanced ultrafiltration, Sci. Total Environ., 2013, 461–462, 371.
• [9] PURKAIT M.K., DASGUPTA S., DE S., Micellar enhanced ultrafiltration of eosin dye using hexadecyl pyridinium chloride, J. Hazard. Mater., 2006, B136, 972.
• [10] AHMAD A.L., PUASA S.W., Reactive dyes decolourization from an aqueous solution by combined coagulation/ micellar-enhanced ultrafiltration process, Chem. Eng. J., 2007, 132, 257.
• [11] HUANG J.H., ZENG G.M., ZHOU C.F., LI X., SHI L.J., HE S.B., Adsorption of surfactant micelles and Cd2+/Zn [12] LIN W., JING L., ZHU Z., CAI Q., ZHANG B., Removal of heavy metals from mining wastewater by micellar- enhanced ultrafiltration (MEUF): experimental investigation and Monte Carlo-based artificial neural network modeling, Water Air Soil Pollut., 2017, 228, 205.
• [13] AKITA S., YANG L., TAKEUCHI H., Micellar-enhanced ultrafiltration of gold(III) with nonionic surfactant, J. Membrane Sci., 1997, 133, 189.
• [14] BEOLCHINI F., PAGNANELLI F., DE MICHELIS I., VEGLIÒ F., Micellar enhanced ultrafiltration for arsenic( V) removal: effect of main operating conditions and dynamic modelling, Environ. Sci. Technol., 2006, 40, 2746.
• [15] KAMBLE S. B., MARATHE K. V., Membrane characteristics and fouling study in MEUF for the removal of chromate anions from aqueous streams, Sep. Sci. Technol., 2005, 40, 3051.
• [16] HUANG J., QI F., ZENG G., SHI L., LI X., GU Y., SHI Y., Repeating recovery and reuse of SDS micelles from MEUF retentate containing Cd2+ by acidification UF, Colloid. Surface. A., 2017, 520, 361.
• [17] LI X., ZENG G.M., HUANG J.H., ZHANG C., FANG Y.Y., QU Y.H., LUO F., LIN D., LIU H.L., Recovery and reuse of surfactant SDS from a MEUF retentate containing Cd2+ or Zn2+ by ultrafiltration, J. Membrane Sci., 2009, 337, 92.
• [18] SAMPER E., RODRIGUEZ M., DE LA RUBIA M.A., PRATS D., Removal of metal ions at low concentration by micellar-enhanced ultrafiltration (MEUF) using sodium dodecyl sulfate (SDS) and linear alkylbenzene sulfonate (LAS), Sep. Purif. Technol., 2009, 65, 337.
• [19] TORTORA F., INNOCENZI V., PRISCIANDARO M., VEGLIO F., MAZZIOTTI DI CELSO G., Heavy metal removal from liquid wastes by using micellar-enhanced ultrafiltration, Water Air Soil Poll., 2016, 227, 240.
• [20] KONOPCZYŃSKA B., DYPKO M., PROCHALSKA K., Application of MEUF technique for the separation of chromium(III) ions from model aqueous solutions chromium(III) perchlorate, Proc. ECOpole 2013, 7 (2), 633.
• [21] GHAZI M.M., QOMI M.H., Removal of manganese from an aqueous solution using micellar-enhanced ultrafiltration (MEUF) with SDS surfactants, AET, 2015, 1, 17.
• [22] SANGLE J.S., MARATHE K.V., Removal of manganese from wastewater by using micellar enhanced ultrafiltration (MEUF), IJRDET, 2016, 5, 1.
• [23] YOBILISHETTY S.M., MARATHE K.V., Removal of molybdenum (VI) from effluent waste water streams by cross flow micellar enhanced ultrafiltration (MEUF) using anionic, non-ionic and mixed surfactants, Indian J. Chem. Techn., 2014, 21, 321.
• [24] LI X., HE S., FENG C., ZHU Y., PANG Y., HOU J., LUO K., LIAO X., Non-competitive and competitive adsorption of Pb2+, Cd2+ and Zn2+ ions onto SDS in process of micellar-enhanced ultrafiltration, Sustainability, 2018, 10, 92.
• [25] LEE S.H., SHRESTHA S., Application of micellar enhanced ultrafiltration (MEUF) process for zinc (II) removal in synthetic wastewater: kinetics and two-parameter isotherm models, Int. Biodeter. Biodegr., 2014, 95, 241.
• [26] SCHWARZE M., GROSS M., MORITZ M., BUCHNER G., KAPITZKI L., CHIAPPISI L., GRADZIELSKI M., Micellar enhanced ultrafiltration (MEUF) of metal cations with oleylethoxycarboxylate, J. Membrane Sci., 2015, 478, 140.
• [27] HUANG J.H., ZHAO Y., ZENG G.M., PENG L., LI X., LIU L.X., LI F., SHI L.X., YUAN F., Micellar-enhanced ultrafiltration for the solubilization of various phenolic compounds with different surfactants, Water Sci. Technol., 2015, 72, 623.
• [28] JÖNSSON A.S., JÖNSSON B., The influence of nonionic and ionic surfactants on hydrophobic and hydrophilic ultrafiltration membranes, J. Membrane Sci., 1991, 56, 49.
• [29] HUANG J., YUAN F., ZENG G., LI X., GU Y., SHI L., LIU W., SHI Y., Influence of pH on heavy metal speciation and removal from wastewater using micellar-enhanced ultrafiltration, Chemosphere, 2017, 173, 199.2+ in micellar-enhanced ultrafiltration, J. Hazard. Mater., 2010, 183, 287.
• [30] LI C.W., LIU C.K., YEN W.S., Micellar-enhanced ultrafiltration (MEUF) with mixed surfactants for removing Cu(II) ions, Chemosphere, 2006, 63, 353.
• [31] DE S., MONDAL S., Micellar Enhanced Ultrafiltration, Fundamentals and Applications, Taylor and Francis Group, Boca Raton 2012.
• [32] XU K., ZENG G.M., HUANG J.H. WU J.Y., FANG Y.Y., HUANG G., LI J., XI B., LIU H., Removal of Cd2+ from synthetic wastewater using micellar-enhanced ultrafiltration with hollow fiber membrane, Colloid. Surface. A., 2007, 294, 140.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).