Wykorzystanie danych retencyjnych uzyskanych przy pomocy techniki mikro-TLC w doborze warunków procesu ekstrakcji do fazy stałej (SPE) prowadzonej z użyciem faz odwróconych

Zarzycka, M. B.

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Wykorzystanie danych retencyjnych uzyskanych przy pomocy techniki mikro-TLC w doborze warunków procesu ekstrakcji do fazy stałej (SPE) prowadzonej z użyciem faz odwróconych

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Zarzycka M. B.

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Application of retention data derived from micro-TLC plates for optimization of a reversed phase solid-phase extraction protocol

Języki publikacji

Abstrakty

W pracy dokonano omówienia wyników dostępnych w literaturze, a także z badań własnych dotyczących współczesnej chromatografii planarnej, oraz doboru składu eluentów stosowanych w ekstrakcji do fazy stałej (SPE) z wykorzystaniem danych retencyjnych, otrzymanych z mikro-TLC, zużyciem wysokosprawnych płytek typu HPTLC RP18W. Przedstawiono sposób optymalizacji składu eluentów stosowanych w procedurach SPE dla wybranych hormonów sterydowych z grup estrogenów oraz progestagenów. Zaprezentowano wykresy, które mogą być przydatne do bezpośredniego wyznaczenia składu binarnych metanolowo-wodnych faz wymywających oraz czyszczących. Krzywe ilustrujące zmiany objętości retencji zależnie od składu fazy ruchomej zostały obliczone na podstawie wyznaczonych w poprzednich pracach współczynników równań regresji liniowej typu logkSPE = aRM + b dla wybranych hormonów sterydowych chromatografowanych w układzie faz odwróconych.

This short review communication presents modern planar chromatography, the general ideas of solid-phase extraction (SPE) and especially optimization of the extraction protocol involving retention data derived from micro-TLC plates under reversed phase conditions using wettable with water stationary phase (HPTLC RP18W). Particularly, the graphs that allow a direct selection of an appropriate cleaning end eluting solvents based on the binary methanol/water mixtures for selected estrogens and progestogens were plotted. The computations were based on available in literature slope and intercept coefficients of the linear-regression equation formed as logkSPE = aRM + b for given steroid hormones chromatographed under reversed- phase (RP) conditions.

Słowa kluczowe

Mikro-TLC chromatografia planarna ekstrakcja do fazy satałej układ faz odwróconych hormony sterydy estrogeny progestageny

Micro-TLC planar chromatography solid-phase extraction reversed phase hormones steroids estrogens progestogens

Wydawca

Publishing House of Siedlce University of Natural Sciences and Humanities

Czasopismo

Camera Separatoria

Rocznik

2011

Tom

Vol. 3, No. 1

Strony

129--145

Opis fizyczny

Bibliogr. 64 poz., rys., wykr.

Twórcy

autor

Zarzycka M. B.

mbzarz@wp.pl

Politechnika Koszalińska, Zakład Toksykologii i Bioanalityki, ul. Śniadeckich 2, 75-453 Koszalin

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