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Innovative NPK Fertilizers based on Polyacrylamide and Polyvinyl Alcohol with Controlled Release of Nutrients

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of the present work was the preparation and properties evaluation of two innovative fertilizers based on multicomponent polymers characterized by a controlled release of nutrients. One method was based on a multi-component liquid containing different amounts of microelements NPK 12-5-6 fertilizers with polyacrylamide hydrogel beads. The second method concerned the cross-linking of biodegradable polyvinyl alcohol with multi-component NPK fertilizers. Polyacrylamide-based compositions with the highest amount of NPK salts as well as polyvinyl alcohol-based fertilizers in dense gel form, based on 60 phr crosslinking concentrate have shown optimal properties. Regardless of the type of fertilizers used, their components were released slowly. The obtained fertilizers were classifi ed according to the kinetics of nutrient release. Fertilizers made from polyacrylamide based fertilizers have been classifi ed into a group of controlled release fertilizers (CRF), while those made from biodegradable environmentally friendly polyvinyl alcohol have been defi ned as slow released fertilizers (SRF).
Rocznik
Strony
14--18
Opis fizyczny
Bibliogr. 22 poz., rys., tab., wz.
Twórcy
  • Kazimierz Pulaski University of Technology and Humanities in Radom, Faculty of Chemical Engineering and Commodity Sciences, Chrobrego Street 27, 26-600, Radom, Poland
  • Kazimierz Pulaski University of Technology and Humanities in Radom, Faculty of Chemical Engineering and Commodity Sciences, Chrobrego Street 27, 26-600, Radom, Poland
  • Kazimierz Pulaski University of Technology and Humanities in Radom, Faculty of Chemical Engineering and Commodity Sciences, Chrobrego Street 27, 26-600, Radom, Poland
  • Kazimierz Pulaski University of Technology and Humanities in Radom, Faculty of Chemical Engineering and Commodity Sciences, Chrobrego Street 27, 26-600, Radom, Poland
Bibliografia
  • 1. Izydorczyk, G., Sienkiewicz-Cholewa, U., Baśladyńska, S., Kocek, D., Mironiuk, M. & Chojnacka, K. (2020). New environmentally friendly bio-based micronutrient fertilizer by biosorption: From laboratory studies to the field. Sci. Total Environ. 710, 136061 DOI: 10.1016/j.scitotenv.2019.136061.
  • 2. Kasprzycka, A., Lalak-Kańczugowska, J., Jerzy Tys, J., Chmielewska, M. & Pawłowska, M. (2018). Chemical stability and sanitary properties of pelletized organo-mineral waste-derived fertilizer.
  • 3. Arch. Environ. Prot. 44 (3), 106–113. DOI: 10.24425/122284.
  • 4. Sądej, W., Żołnowski, A.C. & Marczuk, O. (2016). Content of phenolic compounds in soils originating from two long-term fertilization experiments. Arch. Environ. Prot. 42 (4), 104–113. DOI: 10.1515/aep-2016-0047.
  • 5. Davidson, D.W., Verma, M.S. & Gu, F.X. (2013). Controlled root targeted delivery of fertilizer using an ionically crosslinked carboxymethyl cellulose hydrogel matrix. Springer-Plus, 2 (1), 1–9. DOI: 10.1186/2193-1801-2-318.
  • 6. Hridya, A.C. & Byju, G. (2014). Effect of chemical fertilizers and microbial inoculations on soil properties in cassava (Manihot esculenta) growing Vertisols of Tamil Nadu. Indian J. Agr. Sci. 84 (7), 860–866.
  • 7. Kumar, D., Singh, S., Singh, J. & Singh, S.P. (2015). Influence of organic and inorganic fertilizers on soil fertility and productivity of wheat (Triticum aestivum). Indian J. Agr. Sci. 85 (2), 177–181.
  • 8 .NeAmţu, C., Popescu M., Oancea F. & Dima, Ş.O. (2015). Synthesis Optimization and Characterization of Microencapsulated N-P-K Slow-Release Fertilizers. Open Chem. 13 (1), 813–823. DOI: 10.1515/chem-2015-0098.
  • 9. Davidson, D. & Gu, F.X. (2012). Materials for sustained and controlled release of nutrients and molecules to support plant growth. J. Agr. Food Chem. 60, 870–876. DOI: 10.1021/jf204092h.
  • 10. Guilherme, R.M., Aouada, A.F. & Fajardo, R.A. (2015). Superabsorbent hydrogels based on a polysaccharides for application in agriculture as soil conditioner and nutrient carrier: A review. Eur. Polym. J. 72, 365–385. DOI: 10.1016/j.eurpolymj.2015.04.017.
  • 11. Johnson, W.R., Goertz, M.H. & Timmons, R.J. (2008). Controlled release fertilizer and method of its production, U.S. Patent No. 338558.
  • 12. Barth, T., Rieber, N., Gold, R.E., Dressei, J., Erhardt, K., Horchler von Locquengh, K., Leibold, E. & Rittinger, S. (2004). Application of inorganic or organic polyacids for application to mineral fertilizers, mineral fertilizer containing nitrogen and method of mineral fertilizer production. DE Patent No. 331409.
  • 13. Lubkowski, K. & Grzmil, B. (2007). Controlled release fertilizers. Pol. J. Chem. Technol. 9 (4), 81–84. DOI: 10.2478/v10026-007-0096-6.
  • 14. Borowiec, M., Polańska, P. & Hoffmann, J. (2007). Biodegradability of the compounds introduced with microelement fertilizers into the environment. Pol. J. Chem. Technol. 9 (3), 38–41. DOI: 10.2478/v10026-007-0050-7.
  • 15. Watanabe, F.S. & Olsen, S.R. (1965). Test of an ascorbic acid method for determining phosphorus in water and NaHCO3 extracts from soil. Soil Sci. Soc. Am. J. 29 (6), 677–678. DOI: 10.2136/sssaj1965.03615995002900060025x.
  • 16. Breś,W. & Trelka T. (2015). Effect of fertigation on soil pollution during greenhouse plant cultivation. Arch. Environ. Prot. 41 (2), 75–81. DOI: 10.1515/aep-2015-0021.
  • 17. Chiellini, E., Corti, A., Del Sarto, G. & D'Antone, S. (2006). Oxo-biodegradable polymers–Effect of hydrolysis degree on biodegradation behaviour of poly (vinyl alcohol). Polym. Degrad. Stab. 91 (12), 3397–3406. DOI: 10.1016/j.polymdegradstab.2006.05.021.
  • 18. Nagarkar, R. & Patel, J. (2019). Polyvinyl alcohol: A comprehensive study. Acta Sci. Pharm. Sci. 3 (4), 34–44.
  • 19. Martens, P. & Anseth, K.S. (2000). Characterization of hydrogels formed from acrylate modified poly (vinyl alcohol) macromers. Polymer, 41 (21), 7715–7722. DOI: 10.1016/S0032-3861(00)00123-3.
  • 20. Hassan, C. M., Trakampan, P. & Peppas, N.A. (2002). Water solubility characteristics of poly (vinyl alcohol) and gels prepared by freezing/thawing processes. In Water soluble polymers, Springer, Boston, 31–40. DOI: 10.1007/0-306-46915-4_3.
  • 21. Wang, C., Song, S., Yang, Z., Liu, Y., He, Z., Zhou, C., Du, L., Sun, D. & Li, P. (2022). Hydrophobic modification of castor oil-based polyurethane coated fertilizer to improve the controlled release of nutrient with polysiloxane and halloysite. Prog. Org. Coat. 165, 106756. DOI: 10.1016/j.porgcoat.2022.106756.
  • 22. Xie, J., Yang, Y., Gao, B., Wan, Y., Li, Y.C., Xu, J. & Zhao, Q. (2017). Biomimetic superhydrophobic biobased polyurethane-coated fertilizer with atmosphere “Outerwear”. ACS Appl. Mater. Inter. 9 (18), 15868–15879. DOI: 10.1021/acsami.7b02244.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a937f494-5250-4c57-b19f-da782ee77762
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