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The opportunity of utilizing activated carbon prepared from banana peels (BPAC) as a permeable reactive barrier (PRB) to eliminate copper (Cu+2) from the contaminated ground water has been explored. The activated carbon was prepared from banana peels by chemical activation utilizing a drenching agent, for example, a phosphoric acid (H3PO4). The Influence of different factors including initial copper amount, contacting duration, agitation speed, initial pH of the solution and sorbent dosage was studied in batch experiments. The optimum magnitudes for these factors that resulted in the highest copper removing efficacy (96%) were 40 minutes, 6, 250 rpm, 50 mg/l, and 1 mg/100 ml, respectively. The isotherm models of Freundlich and Langmuir have been utilized to analyze the sorption data for Cu+2 ions acquired via batch studies. The Langmuir model has been utilized to explain the sorption of Cu+2 onto BPAC, according to the findings. The partial differential formulas that describe copper transport in one–dimensional (1D) under equilibrium conditions have been solved utilizing COMSOL Multiphysics 3.5a software based on the finite element technique. The PRB has a significant function in preventing the copper plume from moving, according to the expected findings (COMSOL solution) and experimental findings. Finally, the excellent agreement between anticipated (theoretical) and actual findings, with an RMSE of less comparison with 0.1%, demonstrated that these techniques are useful and efficient instruments for describing copper transport processes.
Słowa kluczowe
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Rocznik
Tom
Strony
83--90
Opis fizyczny
Bibliogr. 14 poz., rys., tab.
Twórcy
- Chemical Engineering and Petroleum Industries Department, Al-Mustaqbal University College, Babylon, Iraq
autor
- Department of Environmental Engineering at Faculty of Engineering, University of Babylon, Iraq
autor
- Al-Mussaib Technical Institute, Al-Furat Al-Awsat Technical University, 51009 Babylon, Iraq
Bibliografia
- 1. Abd Ali Z.T. 2016. Using activated carbon developed from iraqi date palm seeds as permeable reactive barrier for remediation of groundwater contaminated with copper. Al-Khwarizmi Engineering Journal, 12(2), 34–44.
- 2. Abd Ali Z.T., Flayehb H.M., Ibrahimc M.A. 2019. Numerical modeling of performance of olive seeds as permeable reactive barrier for containment of copper from contaminated groundwater. Desalination and Water Treatment, 139, 268–276.
- 3. Anderson M.P., Woessner W.W., Hunt R.J. 2015. Applied groundwater modeling: simulation of flow and advective transport. Academic Press.
- 4. Chen I.-P., Kan C.-C., Futalan C.M., Calagui M.J.C., Lin S.-S., Tsai W.C., Wan M.-W. 2015. Batch and fixed bed studies: Removal of copper (II) using chitosan-coated kaolinite beads from aqueous solution. Sustainable Environment Research, 25(2).
- 5. Di Natale F., Di Natale M., Greco R., Lancia A., Laudante C., Musmarra D. 2008. Groundwater protection from cadmium contamination by permeable reactive barriers. J. Hazard. Mater., 160(2–3), 428–434.
- 6. El-Sayed G., Dessouki H., Ibrahim S. 2010. Biosorption of Ni(II) and Cd(II) ions from aqueous solutions onto rice straw. Chemical Sciences Journal, #A259381893.
- 7. Faisal A.A. and Abd Ali Z.T. 2014. Using granular dead anaerobic sludge as permeable reactive barrier for remediation of groundwater contaminated with phenol. Journal of Environmental Engineering, 141(4), 04014072.
- 8. Jain M., Garg V., Garg U., Kadirvelu K., Sillanpaa M. 2015. Cadmium removal from wastewater using carbonaceous adsorbents prepared from sunfl ower waste. International Journal of Environmental Research, 9(3), 1079–1088.
- 9. Rahmani A., Ghaff ari H., Samadi M. 2010. Removal of arsenic (III) from contaminated water by synthetic nano size zerovalent iron. World Academy of Science, Engineering and Technology, 62, 1116–1119.
- 10.Reddi L. and Inyang H.I. 2000. Geoenvironmental engineering: principles and applications. CRC Press.
- 11. Yagsi N.U. 2004. Production and Characterization of Activated Carbon from Apricot Stones. Thesis. Middle East Technical University.
- 12. Krause P., Boyle D., Bäse F. 2005. Comparison of different efficiency criteria for hydrological model assessment. Advances in Geosciences, 5, 89–97.
- 13. Rouabeh I. and Amrani M. 2012. Equilibrium modeling for adsorption of NO3 from aqueous solution on activated carbon produced from pomegranate peel. Journal of Advances in Environmental Research, 1(2), 143–151.
- 14. Wang S., Nan Z., Li Y., Zhao Z. 2009. The chemical bonding of copper ions on kaolin from Suzhou, China. Desalination, 249(3), 991–995.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a8d734e8-c6ef-47a1-b5fd-1cdc5502e51c