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In some volcanic systems, thoron and radon activity and CO2 flux, in soil and fumaroles, show a relationship between (220Rn/222Rn) and CO2 efflux. It is theorized that deep, magmatic sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. In this paper we evaluate whether the observed inverse relationship is a true geochemical signal, or potentially an analytical artifact of high CO2 concentrations. We report results from a laboratory experiment using the RAD7 radon detector, known 222Rn (radon) and 220Rn (thoron), and a controllable percentage of CO2 in the carrier gas. Our results show that for every percentage of CO2, the 220Rn reading should be multiplied by 1.019, the 222Rn radon should be multiplied by 1.003 and the 220Rn/222Rn ratio should be multiplied by 1.016 to correct for the presence of the CO2.
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Czasopismo
Rocznik
Tom
Strony
822--830
Opis fizyczny
Bibliogr. 13 poz.
Twórcy
autor
- Durridge Company Inc., Billerica, MA, USA
autor
- Wyoming High Precision Isotope Laboratory, Dept. of Geology and Geophysics, University of Wyoming, Laramie, USA
Bibliografia
- Cigolini, C., P. Poggi, M. Ripepe, M. Laiolo, C. Ciamberlini, D. Delle Donne, G. Ulivieri, D. Coppola, G. Lacanna, E. Marchetti, D. Piscopo, and R. Genco (2009), Radon surveys and real-time monitoring at Stromboli volcano: Influence of soil temperature, atmospheric pressure and tidal forces on 222Rn degassing, J. Volcanol. Geoth. Res. 184, 3-4, 381-388, DOI: 10.1016/j.jvolgeores.2009.04.019.
- D’Amore, F., and J.C. Sabroux (1976), Signification de la présence de radon 222 dans le fluides géothermiques, B. Volcanol. 40, 2, 106-115, DOI:10.1007/BF02599855 (in French).
- Giammanco, S., K.W.W. Sims, and M. Neri (2007), Measurements of 220Rn and 222Rn and CO2 emissions in soil and fumarole gases on Mt. Etna volcano (Italy): Implications for gas transport and shallow ground fracture, Geochem. Geophys. Geosys. 8, 10, Q10001, DOI: 10.1029/2007GC001644.
- Giammanco, S., G. Immè, G. Mangano, D. Morelli, and M. Neri (2009), Comparison between different methodologies for detecting radon in soil along an active fault: The case of the Pernicana fault system, Mt. Etna (Italy), Appl. Radiat. Isotopes 67, 1, 178-185, DOI: 10.1016/j.apradiso.2008.09.007.
- Huxol, S., M.S. Brenwald, E. Hoehn, and R. Kipfer (2012), On the fate of 220Rn in soil material in dependence of water content: Implications from field and laboratory experiments, Chem. Geol. 298-299, 116-122, DOI: 10.1016/j.chemgeo.2012.01.002.
- Laiolo, M., C. Cigolini, D. Coppola, and D. Piscopo (2012), Developments in realtime radon monitoring at Stromboli volcano, J. Environ. Radioactiv. 105, 21-29, DOI: 10.1016/j.jenvrad.2011.10.006.
- Liotta, M., A. Paonita, A. Caracausi, M. Martelli, A. Rizzo, and R. Favara (2010), Hydrothermal processes governing the geochemistry of the crater fumaroles at Mount Etna volcano (Italy), Chem. Geol. 278, 1-2, 92-104, DOI: 10.1016/j.chemgeo.2010.09.004.
- Martelli, M., A. Caracausi, A. Paonita, and A. Rizzo (2008), Geochemical variations of air-free crater fumaroles at Mt. Etna: New inferences for forecasting shallow volcanic activity, Geophys. Res. Lett. 35, 21, L21302, DOI: 10.1029/2008GL035118.
- Martinelli, G. (1998), Gas geochemistry and 222Rn migration process, Radiat. Prot. Dosim. 78, 1, 77-82, DOI: 10.1093/oxfordjournals.rpd.a032338.
- Neri, M., S. Giammanco, E. Ferrera, G. Patanè, and V. Zanon (2011), Spatial distribution of soil radon as a tool to recognize active faulting on an active volcano: the example of Mt. Etna (Italy), J. Environ. Radioactiv. 102, 9, 863-870, DOI: 10.1016/j.jenvrad.2011.05.002.
- Pérez, N.M., P.A. Hernández, E. Padrón, G. Melián, R. Marrero, G. Padilla, J. Barrancos, and D. Nolasco (2007), Precursory subsurface 222Rn and 220Rn degassing signatures of the 2004 seismic crisis at Tenerife, Canary Islands, Pure Appl. Geophys. 164, 12, 2431-2448, DOI: 10.1007/s00024-007-0280-x.
- Tuccimei, P., and M. Soligo (2008), Correcting for CO2 interference in soil radon flux measurements, Radiat. Meas. 43, 1, 102-105, DOI: 10.1016/j.radmeas.2007.05.056.
- Yang, T.F., H.Y. Wen, C.C. Fu, H.F. Lee, and T.F. Lan (2011), Soil radon flux and concentrations in hydrothermal area of the Tatun Volcano Group, Northern Taiwan, Geochem. J. 45, 6, 483-490.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a8cfc605-8491-4910-8f73-09551ff4dcff