Adsorptive removal of pentachlorophenol from aqueous solutions using powdered eggshell

• Autorzy: Kuśmierek K. , Idźkiewicz P. , Świątkowski A. , Dąbek L.

Identyfikatory

DOI

10.1515/aep-2017-0029

Warianty tytułu

PL

Adsorpcja pentachlorofenolu na skorupkach jaj

• Języki publikacji: EN

Abstrakty

EN

The usefulness of untreated powdered eggshell as low-cost adsorbent for the removal of pentachlorophenol (PCP) from aqueous solutions was investigated. The most important parameters affecting the adsorption process, including the pH and ionic strength, were examined. The adsorption characteristics of PCP onto eggshell were evaluated in terms of kinetic and equilibrium parameters. The kinetic data were studied in terms of the pseudo- -first order, pseudo-second order and intra-particle diffusion kinetic models. The equilibrium data were analyzed using the Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. The pseudo-second order model best described the adsorption kinetics. Using the Langmuir equation, the monolayer adsorption capacity of eggshell for PCP was found to be 0.127 mg/g. The results showed that PCP can be effectively removed from aqueous solution employing eggshell as a cheap adsorbent.

PL

Dokonano oceny przydatność niemodyfikowanych skorupek jaj jako taniego adsorbentu do usuwania pentachlorofenolu (PCP) z roztworów wodnych. Zbadano najważniejsze parametry mające wpływ na proces adsorpcji, między innymi wpływ pH oraz siły jonowej roztworu. Zbadano zarówno kinetykę adsorpcji PCP jak i adsorpcję równowagową. Do opisu kinetyki zastosowano równania kinetyczne pseudo-pierwszego i pseudo-drugiego rzędu oraz model dyfuzji wewnątrzcząstkowej. Izotermy adsorpcji były analizowane za pomocą równań Langmuira, Freundlicha, Sipsa oraz Redlicha-Petersona. Kinetyka adsorpcji PCP na skorupkach jaj przebiegała zgodnie z modelem pseudo-drugiego rzędu. Maksymalna pojemność adsorpcyjna skorupek jaj w stosunku do PCP, wyznaczona na podstawie równania izotermy Langmuira, wynosiła 0,127 mg/g. Wyniki badań pokazały, że skorupki jaj są interesującym adsorbentem do usuwania pentachlorofenolu z roztworów wodnych.

Słowa kluczowe

EN

adsorption; pentachlorophenol; eggshell; low-cost adsorbent

PL

adsorpcja; pentachlorofenol; skorupa jaj; tani adsorbent

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2017
• Tom: Vol. 43, no. 3
• Strony: 10--16
• Opis fizyczny: Bibliogr. 32 poz., rys., tab., wykr.

Twórcy

autor

Kuśmierek K.

• Military University of Technology, Poland, Institute of Chemistry

autor

Idźkiewicz P.

• Military University of Technology, Poland, Institute of Chemistry

autor

Świątkowski A.

• Military University of Technology, Poland, Institute of Chemistry

autor

Dąbek L.

• University of Technology, Kielce, Poland, Faculty of Environmental Engineering, Geomatics and Power Engineering

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).