Thermoelastic surface properties of seawater in coastal areas of the Baltic Sea

• Autorzy: Boniewicz-Szmyt K. , Pogorzelski S. J.

Identyfikatory

DOI

10.1016/j.oceano.2015.08.003

• Języki publikacji: EN

Abstrakty

EN

Correlations and data for the thermoelastic surface properties of seawater were determined by means of surface tension-temperature and surface pressure-area isotherm measurements performed in Baltic Sea coastal waters (Gulf of Gdańsk, Poland). Thermodynamic surface parameters examined include: surface free energy-γ, entropy, enthalpy, surface specific heat of air-seawater (AW), air-crude oil (AO) and crude oil-seawater (OW) interfaces, and the surface elasticity was quantified in terms of complex viscoelasticity modules with relaxation times of the transition processes. The spatial and temporal evolution of the parameters differed significantly from the literature data for seawater since the effect of surface active substances of natural and municipal origin was likely to be present in these coastal waters. The seawater surface turned out to have the viscoelastic 2D character as well as other interfacial systems AO and OW where three crude oils in contact with the seawater were studied for comparison. The dilational elasticity modules were found to follow the sequence E_AW > E_OW > E_AO. Composite oil lens-covered seawater exhibited a significant drop of E from E_AW (crude oil free surface) even for low oil coverage fraction F₀. The obtained surface and interfacial tension-temperature dependences allowed to correct the spreading coefficient (S = γ_AW − γ_AO − γ_OW) to the desired temperature range, for example. The latter parameter with the sea surface elasticity data allows one to test the modified model of crude oil spreading proposed by the authors (Boniewicz-Szmyt and Pogorzelski, 2008), for spreading kinetics phenomenon at the surface-tension regime.

Słowa kluczowe

EN

Baltic Sea; Surface tension; crude oil-seawater interface; Thermodynamic parameters; Surface viscoelasticity

• Wydawca: Polish Academy of Sciences, Institute of Oceanology ; Elsevier
• Czasopismo: Oceanologia
• Rocznik: 2016
• Tom: No. 58 (1)
• Strony: 25--38
• Opis fizyczny: Bibliogr. 46 poz., rys., tab., wykr., fot.

Twórcy

autor

Boniewicz-Szmyt K.

• Department of Physics, Gdynia Maritime University, Gdynia, Poland

autor

Pogorzelski S. J.

• Institute of Experimental Physics, University of Gdańsk, Gdańsk, Poland

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