Application of micro- and nanostructural multifunctional halloysite-based sorbents from DUNINO deposit in selected biotechnological processes

• Autorzy: Sakiewicz P. , Cebula J. , Piotrowski K. , Nowosielski R. , Wilk R. , Nowicki M.
• Języki publikacji: EN

Abstrakty

EN

Purpose: The aim of this paper was to present some research data from real industrial tests of halloysite-based sorbents in simultaneous removal of various groups of gaseous hazardous substances produced in selected industrial-scale biotechnological processes. Special attention was paid on effectiveness of original, newly developed micro- and nanostructural, universal “Dunino” halloysite-based sorbents in simultaneous removal of odors, ammonia, hydrogen sulphide, silanes, siloxanes and VOCs. Design/methodology/approach: Numerous studies including SEM, analytical method of continuous flame-ion detection (FID), identification of outlet gas stream composition with spectrophotometric methods, olfactometry tests and practical verification in real industrial-scale biotechnological processes were made to examine sorption properties of the halloysite-based filters. Findings: Newly invented nanostructural multifunctional halloysite-based sorbents show high capabilities in respect to simultaneous removal of unwanted substances from biotechnological processes penetrating into natural environment, e.g. odors, ammonia, hydrogen sulphide, silanes, siloxanes, VOCs. Research limitations/implications: Experimental studies described in this work should contribute to improvement of halloysite-based sorbents composition and optimal selection of their work parameters. Practical implications: Enhanced research results in the discussed problem area will make appropriate, rational composition of filtration bed possible – sorbent mixture (halloysite with other sorbents admixtures, natural or synthetic), disintegration degree (granulated form, powder, dust), activation method (physical, chemical) and optimal conditions for interphase contact between sorbent of a given size distribution and purified gas stream to reach the possibly maximal efficiency in unwanted components removal. Originality/value: Newly invented nanostructural halloysite-based sorbents demonstrate higher sorption capabilities in relation to known conventional solutions, moreover simultaneous sorption of many hazardous species is possible.

Słowa kluczowe

EN

halloysite; micro- and nanostructural sorbent; odors; ammonia; hydrogen sulphide

PL

haloizyt; sorbent; odory; amoniak; siarkowodór

• Wydawca: International OCSCO World Press
• Czasopismo: Journal of Achievements in Materials and Manufacturing Engineering
• Rocznik: 2015
• Tom: Vol. 69, nr 2
• Strony: 69--78
• Opis fizyczny: Bibliogr. 42 poz., rys., tab.

Twórcy

autor

Sakiewicz P.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Cebula J.

• Faculty of Materials and Environmental Sciences, Institute of Environmental Protection and Engineering, Unit of Environmental Processes and Technologies, The University of BielskoBiała (ATH), ul. Willowa 2, Bielsko-Biała, Poland

autor

Piotrowski K.

• Gliwice, Faculty of Chemistry, Department of Chemical Engineering and Process Design, Silesian University of Technology, ul. M. Strzody 7, Gliwice, Poland

autor

Nowosielski R.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Wilk R.

• Faculty of Chemistry, Unit of Advanced Material Technologies, Wroclaw University of Technology, ul. Smoluchowskiego 25, Wrocław, Poland

autor

Nowicki M.

• Aquanet SA, ul. Dolna Wilda 126, Poznań, Poland

Bibliografia

• [1] G. Lastella, C. Testa, G. Cornacchia, M. Notornicola, F. Voltasio, V.K. Sharma, Anaerobic digestion of semisolid organic waste: biogas production and its purification, Energy Conversion and Management 43 (2002) 63-75.
• [2] L.V.-A. Truong, N. Abatzoglou, A H2S reactive adsorption process for the purification of biogas prior to its use as a bioenergy vector, Biomass and Bioenergy 29 (2005) 142-151.
• [3] M. Harasimowicz, P. Orluk, G. Zakrzewska-Trznadel, A.G. Chmielewski, Application of polyimide membranes for biogas purification and enrichment. Journal of Hazardous Materials 144 (2007) 698-702.
• [4] X. Lei, N. Sugiura, C. Feng, T. Maekawa, Pretreatment of anaerobic digestion effluent with ammonia stripping and biogas purification, Journal of Hazardous Materials 145 (2007) 391-397
• [5] A. Alonso-Vicario, J.R. Ochoa-Gómez, S. Gil-Rio, O. Gómez-Jimenez-Aberasturi, C.A. Ramirez-López, J. Torrecilla-Soria, A. Dominguez, Purification and upgrading of biogas by pressure swing adsorption on synthetic and natural zeolites, Microporous and Mesoporous Materials 134 (2010) 100-107.
• [6] T.N. Wedraogo, S. Poncin, J. Wu, H.Z. Li, Intensified biogas purification in a stirred tank, Chemical Engineering and Processing: Process Intensification 86 (2014) 1-8.
• [7] R. Dewil, L. Appels, J. Baeyens, Energy use of biogas hampered by the presence of siloxanes, Energy Conversion and Management 47 (2006) 1711-1722.
• [8] B. Tansel, S.C. Surita, Oxidation of siloxanes during biogas combustion and nanotoxicity of Si-based particles released to the atmosphere, Environmental Toxicology and Pharmacology 37 (2014) 166-173.
• [9] J. Raich-Montiu, C. Ribas-Font, N. de Arespacochaga, E. Roig-Torres, F. Broto-Puig, M. Crest, L. Bouchy, J.L. Cortina, Analytical methodology for sampling and analysing eight siloxanes and trimethylsilanol in biogas from different wastewater treatment plants in Europe, Analytica Chimica Acta 2 (2014) 83-91.
• [10] V. Blanes-Vidal, S.G. Sommer, E.S. Nadimi, Modelling surface pH and emissions of hydrogen sulphide, ammonia, acetic acid and carbon dioxide from a pig waste lagoon, Biosystems Engineering 104 (2009) 510-521.
• [11] J.M. Santos, E.S. Lopes, N.C.R. Junior, L.M. de Sa, N.J. Horan, Mathematical modelling of hydrogen sulphide emission and removal in aerobic biofilters comprising chemical oxidation, Water Research 43 (2009) 3355-3364.
• [12] S. Saggar, J. Singh, D.L. Giltrap, M. Zaman, J. Luo, M. Rollo, D.-G. Kim, G. Rys, T.J. van der Weerden,. Quantification of reductions in ammonia emissions from fertiliser urea and animal urine in grazed pastures with urease inhibitors for agriculture inventory: New Zealand as a case study, Science of the Total Environment 465 (2013) 136-146.
• [13] F. Hagenkamp-Korth, A. Haeussermann, E. Hartung, A. Reinhardt-Hanisch, Reduction of ammonia emissions from dairy manure using novel urease inhibitor formulations under laboratory conditions, Biosystems Engineering 130 (2015) 43-51.
• [14] Y. Huang, S.S.H. Ho, K.F. Ho, S.C. Lee, J.Z. Yu, P.K.K. Louie, Characteristics and health impacts of VOCs and carbonyls associated with residential cooking activities in Hong Kong, Journal of Hazardous Materials 186 (2011) 344-351.
• [15] J.E. Colman Lerner, E.Y. Sanchez, J.E. Sambeth, A.A. Porta, Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina, Atmospheric Environment 55 (2012) 440-447.
• [16] T. Petry, D. Vitale, F.J. Joachim, B. Smith, L. Cruse, R. Mascarenhas, S. Schneider, M. Singal, Human health risk evaluation of selected VOC, SVOC and particulate emissions from scented candles, Regulatory Toxicology and Pharmacology 69 (2014) 55-70.
• [17] T.E.M. Hulscher, G. Cornelissen, Effect of temperature on sorption equilibrium and sorption kinetics of organic micropollutants-a review, Chemosphere 32/4 (1996) 609-626.
• [18] R. Zhu, J. Zhu, F. Ge, P. Yuan, Regeneration of spent organoclays after the sorption of organic pollutants: A review, Journal of Environmental Management 90 (2009) 3212-3216
• [19] J. Chen, C. Tong Bin, L. Gao Mei, Z. Guo Di, L. Hong Tao, G. Son Lin, C. Lu, Reducing H2S production by O2 feedback control during large scale sewage sludge composting, Waste Management 31 (2011) 65-70.
• [20] E. Pagans, X. Font, A. Sánchez, Coupling composting and biofiltration for ammonia and volatile organic compound removal, Biosystem Engineering 97 (2007) 491-500.
• [21] A. Kwarciak-Kozłowska, B. Baka, Biofiltration as a method of disposal the odors generated during the composting of a biodegradable fraction of municipal and industrial waste, Engineering and Environmental Protection 17/4 (2014) 631-645 (in Polish).
• [22] J. Matusik, Arsenate, orthophosphate, sulfate, and nitrate sorption equilibria and kinetics for halloysite and kaolinites with an induced positive charge, Chemical Engineering Journal 246 (2014) 244-253.
• [23] D. Bana, A. Kubala-Kuku, J. Braziewicz, et al., Study of properties of chemically modified samples of halloysite mineral with X-ray fluorescence and Xray powder diffraction methods, Radiation Physics and Chemistry 93 (2013) 129-134.
• [24] R. Zhai, B. Zhang, L. Liu, Y. Xie, H. Zhang, J. Liu, Immobilization of enzyme biocatalyst on natural halloysite nanotubes, Catalysis Communications 12 (2010) 259-263.
• [25] J.-W. Tae, B.-S. Jang, J.-R. Kim, I. Kim, D.-W. Park, Catalytic degradation of polystyrene using acid-treated halloysite clays, Solid State Ionics 172 (2004) 129-133.
• [26] G. Liu, F. Kang, B. Li, Z. Huang, X. Chuan, Characterization of the porous carbon prepared by using halloysite as template and its application to EDLC, Journal of Physics and Chemistry of Solids 67 (2006) 1186-1189.
• [27] P. Sakiewicz, R. Nowosielski, W. Pilarczyk, K. Gołombek, M. Lutyski, Selected properties of the halloysite as a component of Geosynthetic Clay Liners, Journal of Achievements in Materials and Manufacturing Engineering 48/2 (2011) 177-191.
• [28] K. Choma-Moryl, The possibilities of using basaltic residual clay soil to seal waste disposal ground, Proceedings of Scientific and Technical Conference „Management of Degraded Lands. Research, Evaluation Criteria, Reclamation”, 2002, (in Polish).
• [29] E. Helios Rybicka, B. Jdrzejczyk, Preliminary studies on mobilisation of copper and lead from contamined soil and readsorption on competing sorbents, Aplied Clay Science 10 (1995) 259-268.
• [30] S. Rooj, A. Das, V. Thakur, R.N. Mahaling, A.K. Bhowmick, Gert Heinrich, Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes, Materials & Design, Design of Nanomaterials and Nanostructures 31/4 (2010) 2151-2156.
• [31] P. Pasbakhsh, H. Ismail, M.N Ahmad Fauzi, A. Abu Bakar, EPDM/modified halloysite nanocomposites, Applied Clay Science 48/3 (2010) 405-413.
• [32] J. Matusik, Minerals of the kaolinite group as precursors of nanotubes mineral, AGH, Kraków, 2010. [33] B. Bolewski, Detailed mineralogy, Geological Publishing, Warszawa, 1982, (in Polish).
• [34] E. Joussein, S. Petit, J. Chrchman, B. Theng, D. Right, B. Delvaux, Halloysite clay minerals-a review, Clay Minerals 40 (2005) 383-426.
• [35] J. Matusik, T. Bajda, Immobilization and reduction of hexavalent chromium in the interlayer space of positively charged kaolinites, Journal of Colloid and Interface Science 398 (2013) 74-81.
• [36] J. Matusik, W. Wcisło, Enhanced heavy metal adsorption on funtionalized nanotubular halloysite interlayer grafted with aminoalcohols, Applied Clay Science 100 (2014) 50-59.
• [37] E. Joussein, S. Petit, J. Chrchman, B. Theng, D. Right, B. Delvaux, Halloysite clay minerals-a review, Clay Minerals 40 (2005) 383-426.
• [38] B. Singh, Why does halloysite roll?-a new model, Clays and Clay Minerals 44 (1996) 191-196.
• [39] J. Cebula, K. Piotrowski, J. Sołtys, M. Sołtys, The new biogas purification technology by halloysite filter deposit, Sorbents Mineral-Raw Materials, Energy, Environment, New Technologies, AGH, Kraków, 2013, (in Polish).
• [40] J. Sołtys, J. Schomburg, P. Sakiewicz, A. Pytliski, K. Jówiak, B. Sołtys, Halloysite from a Dunino deposit as a raw material for the production of mineral sorbents, Sorbents Mineral-Raw Materials, Energy, Environment, New Technologies, AGH, Kraków, 2013, (in Polish).
• [41] P. Yuan, P.D. Southon, Z. Liu, C.J. Kepert, Organosilane functionalization of halloysite nanotubes for enhanced loading and controlled release, Nanotechnology 23 (2012) 1-5.
• [42] K. Czech, P.M. Słomkiewicz, Determination of adsorption isotherms of chlorinated hydrocarbons on halloysite adsorbent by inverse gas chromatography, Journal of Chromatography A 1288 (2013) 96-100.