Commercial Kevlar derived activated carbons for CO2 and C2H4 sorption

• Autorzy: Kaliszewski M. , Zgrzebnicki M. , Kałamaga A. , Pinjara S. , Wróbel R. J.

Identyfikatory

DOI

10.2478/pjct-2021-0021

• Języki publikacji: EN

Abstrakty

EN

The carbonaceous precursor was obtained via pyrolysis of commercial aramid polymer (Kevlar). Additionally the precursor was activated at 1000°C in CO₂ atmosphere for different times. Obtained materials were characterised by BET; XPS; SEM and optical microscopy. The sorption capacities were determined by temperature swing adsorption performed in TGA apparatus for CO₂ and C₂H₄ gases. The obtained materials exhibit high difference in sorption of these gases i.e. 1.5 and 2.8 mmol/g @30°C respectively and high SSA ~1600 m²/g what can be applied in separation applications. The highest uptakes were 1.8 and 3.1 mmol/g @30°C respectively. It was found that the presence of oxygen and nitrogen functional groups enhances C₂H₄/CO₂ uptake ratio.

Słowa kluczowe

EN

activated carbon; carbonaceous catalysts; autoxidation; alpha-pinene; iron particles; biomass

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2021
• Tom: Vol. 23, nr 2
• Strony: 81--87
• Opis fizyczny: Bibliogr. 75 poz., rys., tab., wz.

Twórcy

autor

Kaliszewski M.

• West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Department of Catalytic and Sorbent Materials Engineering, Piastów 42, 71-065 Szczecin, Poland

autor

Zgrzebnicki M.

• West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Department of Catalytic and Sorbent Materials Engineering, Piastów 42, 71-065 Szczecin, Poland

autor

Kałamaga A.

• West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Department of Catalytic and Sorbent Materials Engineering, Piastów 42, 71-065 Szczecin, Poland

autor

Pinjara S.

• West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Department of Catalytic and Sorbent Materials Engineering, Piastów 42, 71-065 Szczecin, Poland

autor

Wróbel R. J.

• West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Department of Catalytic and Sorbent Materials Engineering, Piastów 42, 71-065 Szczecin, Poland

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).

W bibliograffii brak poz. 55