Sorption kinetics of Cd(II) ions on fermented grape marc

• Autorzy: Grudić V. , Bošković I. , Jaćimović Z.

Identyfikatory

DOI

10.5277/epel70419

• Języki publikacji: EN

Abstrakty

EN

The sorption kinetics of Cd(II) ions on the biosorbent which is waste in wine production has been investigated. The sorption process took place relatively quickly, enabling one to achieve equilibrium within a period of 15–20 min only, depending on initial concentration of the sorbate. Kinetic models of pseudo-first and pseudo-second order, model of diffusion in a fluid film and Weber’s and Morris’ intraparticle diffusion model were used to describe the experimental results. The pseudo-second order kinetic model described the sorption process with a high correlation coefficient (R2 = 0.998) better than the other kinetic models. The mass transfer coefficient decreases upon increasing the initial concentration of the solution, which can be explained by the fact that the mechanism of binding of Cd(II) ions to the surface of the sorbent is ion exchange followed by discharge of exchangeable cations from the surface. Characteristic constants in the Weber–Morris model increase upon increasing the initial concentration of the solution.

Słowa kluczowe

EN

activated carbon; cadmium compounds; kinetic parameters; Weber-Morris model

PL

węgiel aktywny; związki kadmu; parametry kinetyczne; model Webera-Morrisona

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2017
• Tom: Vol. 43, nr 4
• Strony: 243--252
• Opis fizyczny: Bibliogr. 25 poz., tab., rys.

Twórcy

autor

Grudić V.

• Faculty of Metallurgy and Technology, University of Montenegro, Džordža Vašingtona BB, 81000 Podgorica, Montenegro

autor

Bošković I.

• Faculty of Metallurgy and Technology, University of Montenegro, Džordža Vašingtona BB, 81000 Podgorica, Montenegro

autor

Jaćimović Z.

• Faculty of Metallurgy and Technology, University of Montenegro, Džordža Vašingtona BB, 81000 Podgorica, Montenegro

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).