Tryptophan-Based Organoclay for Aqueous Naphthol Blue Black Removal – Preparation, Characterization, and Batch Adsorption Studies

• Autorzy: Julinawati Julinawati , Febriani Febriani , Mustafa Irfan , Fathurrahmi Fathurrahmi , Rahmi Rahmi , Sheilatina Sheilatina , Ahmad Khairunnas , Puspita Kana , Iqhrammullah Muhammad

Identyfikatory

DOI

10.12911/22998993/165781

• Języki publikacji: EN

Abstrakty

EN

To prevent the serious threat of textile wastewater, researchers have developed adsorption-based wastewater treatment using cheap, yet effective, adsorbent materials. Of which is natural bentonite, that has the advantages for adsorption due to its porous structure and functional groups but still suffers from its low affinity against anionic and hydrophilic azo dyes. Herein, we aimed of improving the affinity by amino acid tryptophan embedment into the locally isolated natural bentonite collected from Aceh Province, Indonesia. The prepared bentonite samples were characterized using Fourier transform infrared, X-ray diffraction, and scanning electron microscopy. Adsorptive removal was performed on naphthol blue black (NBB) in a batch system with variations of contact time, pH, and adsorbent dosage. The isotherm studies were carried out at optimum conditions (contact time=15 minutes; pH 1; adsorbent dosage=0.2 g) with several models including Langmuir, Freundlich, Sips, and Redlich-Peterson isotherm models. The characterization results revealed that the modification altered its functional group, crystallinity, and micro-surface morphology that add more benefits for adsorption. At optimum conditions, 99.2% NBB has been successfully removed from the aqueous solution. The isotherm studies suggested that the NBB adsorption onto the tryptophane-modified natural bentonite was dependent on Sips isotherm model (R²=0.999; root-mean-square-errors=1.11×10^-4 mg/g).

Słowa kluczowe

EN

amino acids; bentonite; diazo dye; freundlich; Sips isotherm model; montmorillonite; textile wastewater

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2023
• Tom: Vol. 24, nr 7
• Strony: 274--284
• Opis fizyczny: Bibliogr. 35 poz., rys., tab.

Twórcy

autor

Julinawati Julinawati

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Febriani Febriani

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Mustafa Irfan

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Fathurrahmi Fathurrahmi

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Rahmi Rahmi

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Sheilatina Sheilatina

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Ahmad Khairunnas

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia
• Innovative Sustainability Lab, PT. Biham Riset dan Edukasi, Banda Aceh, 23243, Indonesia

autor

Puspita Kana

• Department of Chemistry Education, Faculty of Education and Teacher Training, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

autor

Iqhrammullah Muhammad

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia
• Innovative Sustainability Lab, PT. Biham Riset dan Edukasi, Banda Aceh, 23243, Indonesia

• https://orcid.org/0000-0001-8060-7088

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