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Effect of depressants in the selective flotation of smithsonite and calcite using cationic collector

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Języki publikacji
EN
Abstrakty
EN
This work studied the effects of sodium hexametaphosphate (SHMP), tanning extract, water glass (WG) and calcium lignosulfonate (CLS) as depressants for the separation of smithsonite from calcite by using a cationic collector called octadecylamine acetate (ODA). Micro-flotation experimental tests showed that CLS can greatly and selectively depress calcite. When the dosages of CLS used were 20 and 40 mg/L, a concentrate with Zn grades of 42.54% and 49.32% and Zn recoveries of 81.66% and 68.00% was achieved in the flotation separation of mixed mineral (1:1 smithsonite:calcite). Zeta potential and adsorption measurements revealed that the adsorption of CLS on calcite’s surface was greater than that on smithsonite’s surface. When CLS was added, the adsorption of ODA was hindered greatly on the calcite’s surface but slightly on the smithsonite’s surface.
Słowa kluczowe
Rocznik
Strony
1--10
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
  • School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China
Bibliografia
  • FENG, Q., S. WEN, X. BAI, W. CHANG, C. CUI., W. ZHAO 2019. Surface modification of smithsonite with ammonia to enhance the formation of sulfidization products and its response to flotation. Minerals Engineering 137, 1-9.
  • GHOSH, M.K., R.P. DAS., A.K. BISWAS. 2002. Oxidative ammonia leaching of sphalerite: Part I: Noncatalytic kinetics. International Journal of Mineral Processing 66, 241-254.
  • LIU, C., Q. FENG., G. ZHANG. 2015. Electrokinetic and flotation behaviors of hemimorphite in the presence of sodium oleate. Minerals Engineering 84, 74-76.
  • IRANNAJAD, M., M. EJTEMAEI., M. GHARABAGHI. 2009. The effect of reagents on selective flotation of smithsonite–calcite–quartz. Minerals Engineering 22, 766-771.
  • LUO, B., Q. LIU, J. DENG, L. YU, H. LAI, C. SONG., S. LI. 2019. Characterization of sulfide film on smithsonite surface during sulfidation processing and its response to flotation performance. Powder Technology 351, 144-152.
  • NAVIDI KASHANI, A.H., F. RASHCHI. 2008. Separation of oxidized zinc minerals from tailings: Influence of flotation reagents. Minerals Engineering 21, 967-972.
  • SHI, Q., G. ZHANG, Q. FENG., H. DENG. 2013. Effect of solution chemistry on the flotation system of smithsonite and calcite. International Journal of Mineral Processing 119, 34-39.
  • HOSSEINI, S.H., E. FORSSBERG. 2007. Physicochemical studies of smithsonite flotation using mixed anionic/cationic collector. Minerals Engineering 20, 621-624.
  • ÖNAL, G., G. BULUT, A. GÜL, O. KANGAL, K.T. PEREK., F. ARSLAN. 2005. Flotation of Aladagˇ oxide lead–zinc ores. Minerals Engineering 18, 279-282.
  • BULATOVIC, S.M. 2010. 24 - Flotation of REO Minerals. Handbook of Flotation Reagents: Chemistry, Theory and Practice. pp. 151-173.
  • KIERSZNICKI, T., J. MAJEWSKI., J. MZYK. 1981. 5-alkylsalicylaldoximes as collectors in flotation of sphalerite, smithsonite and dolomite in a Hallimond tube. International Journal of Mineral Processing 7, 311-318.
  • PEREIRA, C.A., A.E.C. PERES. 2005. Reagents in calamine zinc ores flotation. Minerals Engineering 18: 275-277. WANG, Z., L. XU, J. WANG, L. WANG., J. XIAO. 2017. A comparison study of adsorption of benzohydroxamic acid and amyl xanthate on smithsonite with dodecylamine as co-collector. Applied Surface Science 426, 1141-1147.
  • CHEN, Y., M. LIU, J. CHEN, Y. Li, C. ZHAO., X. MU. 2018. A density functional based tight binding (DFTB+) study on the sulfidization-amine flotation mechanism of smithsonite. Applied Surface Science 458, 454-463.
  • LU, J., M. SUN, Z. YUAN, S. QI, Z. TONG, L. LI., Q. MENG. 2019. Innovative insight for sodium hexametaphosphate interaction with serpentine. Colloids and Surfaces A: Physicochemical and Engineering Aspects 560, 35-41.
  • DING, H., H. LIN., Y. DENG. 2007. Depressing effect of sodium hexametaphosphate on apatite in flotation of rutile. Journal of University of Science and Technology Beijing, Mineral, Metallurgy, Material 14, 200-203.
  • RAMIREZ, A., A. ROJAS, L. GUTIERREZ., J.S. LASKOWSKI. 2018. Sodium hexametaphosphate and sodium silicate as dispersants to reduce the negative effect of kaolinite on the flotation of chalcopyrite in seawater. Minerals Engineering 125, 10-14.
  • SARQUÍS, P.E., J.M. MENÉNDEZ-AGUADO, M.M. MAHAMUD., R. DZIOBA. 2014. Tannins: the organic depressants alternative in selective flotation of sulfides. Journal of Cleaner Production 84, 723-726.
  • LIU, C., G. ZHU, S. SONG., H. LI. 2019. Flotation separation of smithsonite from quartz using calcium lignosulphonate as a depressant and sodium oleate as a collector. Minerals Engineering 131, 385-391.
  • Bo, F., L. XIANPING, W. JINQING., W. PENGCHENG. 2015. The flotation separation of scheelite from calcite using acidified sodium silicate as depressant. Minerals Engineering 80, 45-49.
  • DONG, L., F. JIAO, W. QIN, H. ZHU., W. JIA. 2018. Effect of acidified water glass on the flotation separation of scheelite from calcite using mixed cationic/anionic collectors. Applied Surface Science 444, 747-756.
  • FENG, B., W. GUO, J. PENG., W. ZHANG. 2018. Separation of scheelite and calcite using calcium lignosulphonate as depressant. Separation and Purification Technology 199, 346-350.
  • LE GUERN, C., P. CONIL., R. HOUOT. 2000. Role of calcium ions in the mechanism of action of a lignosulphonate used to modify the wettability of plastics for their separation by flotation. Minerals Engineering 13, 53-63.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a69c30bf-2cba-4c81-a7ba-0040b3d43ebe
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