Synthesis, characterization and photovoltaic properties of Mn-doped Sb2S3 thin film

• Autorzy: Horoz S. , Sahin O.

Identyfikatory

DOI

10.1515/msp-2017-0107

• Języki publikacji: EN

Abstrakty

EN

Synthesis and characterization of Mn-doped Sb₂S₃ thin films (TFs) prepared by chemical bath deposition (CBD) at room temperature have been documented and their structural, optical, morphological, magnetic and photovoltaic properties have been examined for the first time. Their structural properties reveal that the Mn-doped Sb₂S₃ TF has an orthorhombic phase structure of Sb₂S₃, and that the grain size of the Mn-doped Sb₂S₃ TF (72.9 nm) becomes larger than that of undoped Sb₂S₃ TF (69.3 nm). It has been observed that Mn content causes the Sb₂S₃ TF band gap to decrease. This situation clearly correlates with band tailing due to the impurities that are involved. The morphological properties have revealed that the shape of the Mn-doped Sb₂S₃ TF is more uniform than the shape of its undoped counterpart. The study on its magnetic properties has demonstrated that the Mn-doped Sb₂S₃ TF exhibits paramagnetic behavior. Its paramagnetic Curie-Weiss temperature was found to be -4.1 K. This result suggests that there is an anti-ferromagnetic interaction between Mn moments in the Mn-doped Sb₂S₃ TF. Incident photon to electron conversion efficiency (IPCE) and J-V measurements were also carried out for the Mn-doped Sb₂S₃ TF for the first time. The results have indicated that the Mn-doped Sb₂S₃ TF can be utilized as a sensitizer to improve the performance of solar cells. Another important observation on the photovoltaic properties of Mn-doped Sb₂S₃ TF is that the spectral response range is wider than that of undoped Sb₂S₃ TF. Our study suggests that the introduction of dopant could serve as an effective means of improving the device performance of solar cells.

Słowa kluczowe

EN

characterization; chemical bath deposition; CBD; Mn-doped Sb2S3 thin films; photovoltaic properties

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2017
• Tom: Vol. 35, No. 4
• Strony: 861--867
• Opis fizyczny: Bibliogr. 17 poz., rys., tab.

Twórcy

autor

Horoz S.

• Siirt University, Faculty of Art and Sciences, Department of Physics, 56100, Siirt, Turkey

autor

Sahin O.

• Siirt University, Faculty of Engineering and Architecture, Department of Chemical Engineering, 56100, Siirt, Turkey

Bibliografia

• [1] GROZDANOV I., Semicond. Sci. Tech., 9 (1994), 1234.
• [2] FORGUE S.V., GOODRICH R.R., COPE A.D., RCA Rev., 12 (1951), 335.
• [3] ARUN P., VEDESHWAR G., J. Mater. Sci., 31 (1996), 6507.
• [4] KRISHNAN B., ARATO A., CARDENAS E., Appl. Surf. Sci., 254 (2008), 3200.
• [5] KYONO A., KIMATA M., MATSUHISA M., MIGASHITA Y., OKAMOTO K., Phys. Chem. Miner., 29 (2002), 254.
• [6] VERSAVEL M.I., HABER J.A., Thin Solid Films, 515 (2007), 7171.
• [7] HONGWEI L., GUANG Y., YAXIONG G., LIANGBIN X., PINGLI Q., XIN D., XIAOLU Z., WEIJUN K., HONG T., ZHAO C., BORUI L., GUOJIA F., Phys. Chem. Chem. Phys., 18 (2016), 16436.
• [8] TZOFIA E., EYAL T., LIOZ E., J. Phys. Chem. C., 119 (2015), 12904.
• [9] YAHUITL O.M., THOMAS P.W., RONGPING W., ZHIYONG Y., KYLIE R.C., Phys. Status Solidi A, 213 (2015), 108.
• [10] YONG C.C., DONG U.L., JUN H.N., EUN K.K., Adv. Funct. Mater., 24 (2014), 3587.
• [11] ZHONG J., XIAOJIAN Z., YONGJIA Z., MAN Z., MINGJU W., SUJUAN W., JINWEI G., XINGSEN G., JUN-MING L., HONGBO Z., ACS Appl. Mater. Inter., 5 (2013), 8345.
• [12] MUSHTAQ S., BUSHRA I., MUHAMMAD R., AURANG Z., Nat. Sci., 8 (2016), 33.
• [13] CHEN W., MALM J.O., ZWILLER V., HUANG Y., LIU S., WALLENBERG R., BOVIN J.O., SAMUELSON L., Phys. Rev. B., 61 (2000), 11021.
• [14] REN G., LIN Z., WANG C., LIU W., ZHANG J., HUANG F., LIANG J., Nanotechnol., 18 (2007), 035705.
• [15] SAMBASIVAM S., JOESPH D.P., LIN J.G., VENKATESWARAN C., J. Solid State Chem., 182 (2009), 2598.
• [16] LAKSHMI P.V.B., RAJ K.S., RAMACHANDRAN K., Cryst. Res. Technol., 44 (2009), 153.
• [17] LAZOS C.G., ROSENDO E., JUÁREZ H., SALGADO G.G., DIAZ T., FALFÁN M.R., OLIVA A.I., QUINTANA P., AGUILAR D.H., CAUICH W., J. Electrochem. Soc., 155 (2008), 158.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).