Silver(I) recovery on thiomorpholine - modified functional polymer

• Autorzy: Pilśniak-Rabiega Magdalena , Wolska Joanna

Identyfikatory

DOI

10.37190/ppmp/156609

• Języki publikacji: EN

Abstrakty

EN

The functional polymer containing heterocyclic ligands was synthesized by microwave modification of a crosslinked poly(vinylbenzyl chloride–divinylbenzene) matrix with thiomorpholine. The modification yield was 89.3%. The sorbent was used to recover Ag(I) from the synthetic and real chloride solutions. The maximum sorption capacity of Ag(I) was approximately 180 mg Ag/g. The sorption kinetic data were well-fitted to the pseudo-first-order kinetic model. The degree of silver desorption was approximately 50.0% using a 1.0% potassium cyanide solution in a 0.50% hydrogen peroxide solution. The resin retained its capacity toward Ag(I) in five consecutive sorption/desorption cycles. The thiomorpholine modified resin was highly selective toward Ag(I) in relation to Cu(II), Pb(II), Co(II), Ni(II), and Zn(II) from the real chloride leaching solution.

Słowa kluczowe

EN

synthesis; microwave modification; sorption; chloride solutions; selectivity

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2022
• Tom: Vol. 58, iss. 6
• Strony: art. no. 156609
• Opis fizyczny: Bibliogr. 37 poz., rys., wykr.

Twórcy

autor

Pilśniak-Rabiega Magdalena

• Depart. of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Wolska Joanna

• Depart. of Process Engineering and Technology of Polymeric and Carbon Materials, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).