Degradation of pulp mill wastewater by a heterogeneous Fenton-like catalyst Fe/Mn supported on zeolite

• Autorzy: Wang Y. , Shia S. , Wang C. , Fanga S.

Identyfikatory

DOI

10.5277/epe180209

• Języki publikacji: EN

Abstrakty

EN

A novel heterogeneous catalyst, Fe/Mn supported on NaY zeolite, was effectively applied for treating pulp mill effluents. The results of the wastewater quality analysis showed that aromatic structures were present in raw pulp mill effluents, which indicated the difficulty for biodegradation treatments. Two different catalysts were prepared by impregnation (Fe-Mn/NaYim) and sol-gel (Fe-Mn/NaYsg) methods, respectively. The Fe-Mn/NaYsg catalyst demonstrated higher COD removal efficiency and was more stable than the Fe-Mn/NaYim catalyst. The synergistic effects were found between Fe and Mn for COD removal. The highest COD removal efficiency (75.2%) was yielded with the Fe-Mn/NaYsg catalyst (Fe/Mn molar ratio of 2) with 4 mmol/dm³ of H₂O₂ and 1.2 g/dm³ of catalyst addition. A constant COD removal over time was obtained; the COD removal efficiency amounted to 45% after the Fe-Mn/NaYsg catalyst repeatedly degrading pulp mill effluents for five times. The distribution and transformation of the polarity and molecular weight (MW) of dissolved organic carbon (DOC) in the heterogeneous Fenton process were also studied. Experiments showed that the hydrophobic fraction comprised the largest fraction of DOC (60%) in raw wastewater and high MW molecules were transformed into low MW molecules after the heterogeneous Fenton process. This study broadened the application of the Fenton technology.

Słowa kluczowe

EN

binary alloys; efficiency; effluentsiron alloys; manganese alloys; organic carbon

PL

stopy binarne; wydajność; zanieczyszczenia stopów żelaza; stop manganowy; węgiel organiczny

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2018
• Tom: Vol. 44, nr 2
• Strony: 131--145
• Opis fizyczny: Bibliogr. 27 poz., tab., rys.

Twórcy

autor

Wang Y.

• School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, P.R. China

autor

Shia S.

• School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, P.R. China

autor

Wang C.

• School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, P.R. China

autor

Fanga S.

• School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, P.R. China

Bibliografia

• [1] XIA M., LONG M., YANG Y.D., CHEN C., CAI W.M., ZHOU B.X., A highly active bimetallic oxides catalyst supported on Al-containing MCM-41 for Fenton oxidation of phenol solution, Appl. Catal. B, 2011, 110, 118.
• [2] HUANG Y.K., LI S., WANG C., Simultaneous removal of COD and NH3‐N in secondary effluent of high-salinity industrial wastewater by electrochemical oxidation, J. Chem. Technol. Biot., 2012, 87 (1), 130.
• [3] MERAYO N., HERMOSILLA D., BLANCO L., CORTIJO L., ÁNGELES B., Assessing the application of advanced oxidation processes, and their combination with biological treatment, to effluents from pulp and paper industry, J. Hazard. Mater., 2013, 262 (8), 420.
• [4] HERMOSILLA D., MERAYO N., ORDÓNEZ R., BLANCO A., Optimization of conventional Fenton and ultraviolet- assisted oxidation processes for the treatment of reverse osmosis retentate from a paper mill, Waste Manage., 2012, 32 (6), 1236.
• [5] RACHE M.L., GARCÍA A.R., ZEA H.R., SILVA A.M.T., MADEIRA L.M., RAMÍREZ J.H., Azo-dye orange II degradation by the heterogeneous Fenton-like process using a zeolite Y-Fe catalyst. Kinetics with a model based on the Fermi’s equation, Appl. Catal. B, 2014, 146, 192.
• [6] FANG S., WANG C., CHAO B., Operating conditions on the optimization and water quality analysis on the advanced treatment of papermaking wastewater by coagulation/Fenton process, Desalin. Water Treat., 2016, 57 (27), 12755.
• [7] HERMOSILLA D., MERAYO N., GASCÓ A., BLANCO Á., The application of advanced oxidation technologies to the treatment of effluents from the pulp and paper industry. A review, Environ. Sci. Pollut. R., 2015, 22 (1), 168.
• [8] KUŹNIARSKA-BIERNACKA I., RAPOSO M.M.M., BATISTA R., PARPOT P., BIERNACKI K., MAGALHÃES A.L., NEVES I.C., Highly efficient heterogeneous catalysts for phenol oxidation. Binuclear pyrrolyl–azine metal complexes encapsulated in NaY zeolite, Micropor. Mesopor. Mat., 2016, 227, 272.
• [9] WANG W., ZHOU M.H., MAO Q., YUE J.J., WANG X., Novel NaY zeolite-supported nanoscale zero-valent iron as an efficient heterogeneous Fenton catalyst, Catal. Commun., 2010, 11, 937.
• [10] ZHOU Y., XIAO B., LIU S.Q., MENG Z., CHEN Z.G., ZOU C.Y., ZHOU X., Photo-Fenton degradation of ammonia via a manganese-iron double-active component catalyst of graphene–manganese ferrite under visible light, Chem. Eng. J., 2016, 283 (12). 266.
• [11] HASSAN H., HAMEED B.H., Oxidation decolorization of Acid Red 1 solutions by Fe-zeolite Y type catalyst, Desalination, 2011, 276 (276), 45.
• [12] QUANRUD D.M., KARPISCAK M.M., LANSEY K.E., ARNOLD R.G., Transformation of effluent organic matter during subsurface wetland treatment in the Sonoran Desert, Chemosphere, 2004, 54 (6), 777.
• [13] HOLAKOO L., NAKHLA G., YANFUL E.K., BASSI A.S., Chelating properties and molecular weight distribution of soluble microbial products from an aerobic membrane bioreactor, Water Res., 2006, 40 (40), 1531.
• [14] CHEN W., WESTERHOFF P., LEENHEER J.A., BOOKSH K., Fluorescence excitation – emission matrix regional integration to quantify spectra for dissolved organic matter, Environ. Sci. Technol., 2003, 37 (24), 5701.
• [15] BAKER A., Fluorescence excitation-emission matrix characterization of river waters impacted by a tissue mill effluent, Environ. Sci. Technol., 2002, 36 (7), 1377.
• [16] CARSTEA E.M., BRIDGEMAN J., BAKER A., REYNOLDS D.M., Fluorescence spectroscopy for wastewater monitoring. A review, Water Res., 2016, 95, 205.
• [17] JI R.D., COOPER G.A., BOOKSH K.S., Excitation-emission matrix fluorescence based determination of carbamate pesticides and polycyclic aromatic hydrocarbons, Anal. Chim. Acta, 1999, 397 (1–3), 61.
• [18] LACORTE S., LATORRE A., BARCELÓ D., RIGOL A., MALMQVIST A., WELANDER T., Organic compounds in paper-mill process waters and effluents, Trends Anal. Chem., 2003, 22, 725.
• [19] ZHAO J., YANG J., MA J., Mn(II)-enhanced oxidation of benzoic acid by Fe(III)/H2O2 system, Chem. Eng. J., 2014, 239 (3), 171.
• [20] COSTA R.C.C., LELIS M.F.F., OLIVEIRA L.C.A., FABRIS J.D., ARDISSON J.D., RIOS C.N. SILVA R.R.V.A., LAGO R.M., Novel active heterogeneous Fenton system based on Fe3–xMxO4 (Fe, Co, Mn, Ni). The role of M2+ species on the reactivity towards H2O2 reactions, J. Hazard. Mater., 2006, 129 (1–3), 171.
• [21] JACOBSEN F., HOLCMAN J., SEHESTED K., Manganese(II)-superoxide complex in aqueous solution, J. Phys. Chem. A, 1, 101, 1324.
• [22] GOGOI A., NAVGIRE M., SARMA K.C., GOGOI, P., Fe3O4-CeO2 metal oxide nanocomposite as a Fenton--like heterogeneous catalyst for degradation of catechol, Chem. Eng. J., 2016, 311 (3), 153.
• [23] LI S., ZHANG G., WANG P., ZHENG H., ZHENG Y., Microwave-enhanced Mn-Fenton process for the removal of BPA in water, Chem. Eng. J., 2016, 294, 371.
• [24] ANIPSITAKIS G.P., DIONYSIOU D.D., Radical generation by the interaction of transition metals with common oxidants, Environ. Sci. Technol., 2004, 38 (13), 3705.
• [25] PRANOVICH A.V., REUNANEN M., SJOHOLM R., HOLMBOM B., Dissolved lignin and other aromatic substances in thermomechanical pulp waters, J. Wood Chem. Technol., 2005, 25 (3), 109.
• [26] SHON H.K., VIGNESWARAN S., KIM I.S., CHO J., NGO H.H., The effect of pretreatment to ultrafiltration of biologically treated sewage effluent: a detailed effluent organic matter (EfOM) characterization, Water Res., 2004, 38 (7), 1933.
• [27] HE P.J., ZHENG Z., ZHANG H., SHAO L.M., TANG Q.Y., PAEs and BPA removal in landfill leachate with Fenton process and its relationship with leachate DOM composition, Sci. Total Environ., 2009, 407 (17), 4928.