Fabrication of magnetic ordered mesoporous carbon for quantitative analysis of acidic phytohormones in mushroom samples prior to their determination by ultra-high-performance liquid chromatography–tandem mass spectrometry

• Autorzy: Zhang Qianchun , Chen Yan , Yang Yanqun , Liu Yulan , Wen Ming , Wang Xingyi

Identyfikatory

DOI

10.1556/1326.2022.01022

• Języki publikacji: EN

Abstrakty

EN

A novel method was established for analysing trace four acidic phytohormones, namely, indole-3-acetic acid, 3-indolebutyric acid, abscisic acid, and 1-naphthylacetic acid, using magnetic ordered mesoporous carbon (MOMC). MOMC was facilely synthesised via self-assembly strategy with a direct carbonisation process. The properties of MOMC were characterised using various instruments. MOMC exhibited excellent adsorption capacity towards the analytes. Various critical parameters which may influence the enrichment efficiency were evaluated, including amount of MOMC, extraction conditions, and desorption conditions. An efficient method based on MOMC magnetic solid-phase extraction coupled with ultra-high-performance liquid chromatography–tandem mass spectrometry (UHPLC–MS/MS) was developed to analyse the trace four acidic phytohormones, with good correlation coefficients (R² = 0.9965–0.9998) and low limits of detection (0.13–9.7 ng L⁻¹, S/N = 3). Trace acidic phytohormones in Agaricus bisporus and Hypsizygus marmoreus samples were determined with satisfactory recoveries (91.8–108%) and reproducibility (2.6–6.3%). The features indicated that MOMC provides an efficient platform for mushroom sampling; the developed method is convenient, promising, and sensitive for the detection of trace phytohormones in complicated mushroom samples.

Słowa kluczowe

EN

ordered mesoporous carbon; magnetic solid-phase extraction; phytohormones; mushroom samples

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2023
• Tom: Vol. 35, no. 1
• Strony: 60--69
• Opis fizyczny: Bibliogr. 34 poz., tab., rys., wykr.

Twórcy

autor

Zhang Qianchun

• School of Biology and Chemistry, Key Laboratory for Analytical Science of Food and Environment Pollution of Qian Xi Nan, Xingyi Normal University for Nationalities, Xingyi, 562400, PR China

• https://orcid.org/0000-0002-6199-3021

autor

Chen Yan

• School of Biology and Chemistry, Key Laboratory for Analytical Science of Food and Environment Pollution of Qian Xi Nan, Xingyi Normal University for Nationalities, Xingyi, 562400, PR China

autor

Yang Yanqun

• School of Biology and Chemistry, Key Laboratory for Analytical Science of Food and Environment Pollution of Qian Xi Nan, Xingyi Normal University for Nationalities, Xingyi, 562400, PR China
• Guangxi Colleges and Universities Key Laboratory of Food Safety and Detection, College of Chemistry and Bioengineering, Guilin University of Technology, Guangxi, 541004, PR China

autor

Liu Yulan

• School of Biology and Chemistry, Key Laboratory for Analytical Science of Food and Environment Pollution of Qian Xi Nan, Xingyi Normal University for Nationalities, Xingyi, 562400, PR China

autor

Wen Ming

• School of Biology and Chemistry, Key Laboratory for Analytical Science of Food and Environment Pollution of Qian Xi Nan, Xingyi Normal University for Nationalities, Xingyi, 562400, PR China

autor

Wang Xingyi

• School of Biology and Chemistry, Key Laboratory for Analytical Science of Food and Environment Pollution of Qian Xi Nan, Xingyi Normal University for Nationalities, Xingyi, 562400, PR China

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).