Magnetic characterization of microcrystalline Na3Ln0.99–xEr0.01Crx(PO4)2 orthophosphates synthesized by Pechini method (Ln = La, Gd)

• Autorzy: Kaczmarek S. M. , Leniec G. , Fuks H. , Skibiński T. , Pelczarska A. , Godlewska P. , Hanuza J. , Szczygieł I.

Identyfikatory

DOI

10.1515/msp-2017-0094

• Języki publikacji: EN

Abstrakty

EN

Na3Ln(PO4)2 orthophosphates (Ln = La, Gd) doped with Er³⁺ and co-doped with Cr³⁺ ions were synthesized by Pechini method and characterized by electron paramagnetic resonance (EPR) and magnetic susceptibility measurements. Low temperature EPR spectra were detected and analyzed in terms of temperature dependence and the structure of the obtained materials. They show that erbium and chromium ions substitute Ln³⁺ and also Na⁺ ions or Na⁺ channels forming complex EPR spectra. Both kinds of ions reveal ferromagnetic type of interaction which shows some anomaly at the temperature between 10 K and 15 K. Magnetic susceptibility reveals a weak antiferromagnetic kind of interaction dominating in the whole temperature range, from 3.5 to 300 K.

Słowa kluczowe

EN

orthophosphates; erbium; chromium; EPR technique; magnetization measurements

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2017
• Tom: Vol. 35, No. 4
• Strony: 733--745
• Opis fizyczny: Bibliogr. 42 poz., rys.

Twórcy

autor

Kaczmarek S. M.

• Institute of Physics, Faculty of Mechanical Engineering and Mechatronics, Westpomeranian University of Technology In Szczecin, Al. Piastów 19, 70-310 Szczecin, Poland

autor

Leniec G.

• Institute of Physics, Faculty of Mechanical Engineering and Mechatronics, Westpomeranian University of Technology In Szczecin, Al. Piastów 19, 70-310 Szczecin, Poland

autor

Fuks H.

• Institute of Physics, Faculty of Mechanical Engineering and Mechatronics, Westpomeranian University of Technology In Szczecin, Al. Piastów 19, 70-310 Szczecin, Poland

autor

Skibiński T.

• Institute of Physics, Faculty of Mechanical Engineering and Mechatronics, Westpomeranian University of Technology In Szczecin, Al. Piastów 19, 70-310 Szczecin, Poland

autor

Pelczarska A.

• Wrocław University of Economics, Faculty of Chemistry and Food Technology, ul. Komandorska 118/120, 53-345 Wrocław, Poland

autor

Godlewska P.

• Wrocław University of Economics, Faculty of Chemistry and Food Technology, ul. Komandorska 118/120, 53-345 Wrocław, Poland

autor

Hanuza J.

• Wrocław University of Economics, Faculty of Chemistry and Food Technology, ul. Komandorska 118/120, 53-345 Wrocław, Poland
• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2, 50-422 Wrocław, Poland

autor

Szczygieł I.

• Wrocław University of Economics, Faculty of Chemistry and Food Technology, ul. Komandorska 118/120, 53-345 Wrocław, Poland

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).