PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Numerical simulation study on NO oxidation by OH radical clusters in flue gas

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Fenton reaction is an important method to remove NO from flue gas. • OH radicals generated in the Fenton reaction can effectively oxidize NO to NO2, which is absorbed and removed by alkali sorbent. To supply guidance for engineering research, numerical simulation of NO oxidation by • OH radical clusters in flue gas has been carried out using Fluent software. The average concentration of NO on the cross sections at various positions of a cylindrical pipe with a circular surface was calculated by simulation. Under various working conditions (temperature, • OH/NO molar ratio, NO concentration in flue gas, and jet velocity), NO oxidation efficiency by • OH radical was simulated and the key factors affecting NO oxidation were analyzed. The results show that temperature and • OH/NO molar ratio are the key factors affecting the oxidation of NO by • OH radicals. The injection velocity has also a significant effect on the oxidation efficiency while the moisture and oxygen content are minor factors influencing the process. The optimum oxidation efficiency of NO is obtained at 473–523 K, the molar ratio of • OH/NO ca. 1.4, the jet velocity 10 m/s, and the flue gas velocity of 3 m/s.
Rocznik
Strony
69--82
Opis fizyczny
Bibliogr. 25 poz., rys.
Twórcy
  • College of Science, Hangzhou Dianzi University, Hangzhou, China, 310018
  • College of Science, Hangzhou Dianzi University, Hangzhou, China, 310018
autor
  • College of Science, Hangzhou Dianzi University, Hangzhou, China, 310018
  • College of Science, Hangzhou Dianzi University, Hangzhou, China, 310018
Bibliografia
  • [1] SRIDAN P., SURAPOLCHAI P., A system approach to biomass energy development. Thailand’s path to-wards sustainable development, ETA-Florence Renewable Energies, 2020, 786–797
  • [2] GUO D., Acid rain and its harm, J. Heilongjiang Water Science Institute, 2006, 1–5. DOI: 10.13524 /j.2095-008x.2006.02.001.
  • [3] NIU J., NIU D., ZHOU H., Review on the harm of acid rain and its prevention and control, J. Dis. Sci., 2008, 23 (4), 110–116.
  • [4] FANG X., Harm and prevention of air pollution to agricultural production, South. Agric. Mach., 2017, 48, 50–55.
  • [5] QI F., Pollution and treatment of nitrogen oxides, Jiangsu Build. Mater., 2016, 7–10.
  • [6] LIU X., Based on the harm of nitrogen oxides and its prevention measures, Low Carbon World, 2017, 9 (3), 8–9. DOI: 10.16844/j.cnki.cn10-1007/tk.2017.09.006. DOI: 10.16844/j.cnki.cn 10-1007/tk. 2017.09.006.
  • [7] JIN C.J., CHEN H.M., WANG L.Y., CHENG X.X., SUN R.F., Adsorption and regeneration of volatile organic compounds (VOCs) on coal-based activated carbon by ferric nitrate modification, China Petr. Proc. Petrochem. Technol., 2021, 23, 137–150.
  • [8] WANG Y., Discussion on the application of SNCR flue gas denitration technology, China El. Power Educ., 2010, S2, 455–456.
  • [9] HU J., Study on the reaction mechanism of ZSM-5 supported Mn/Co-Al/Ce/Ti catalyzed SCR and rapid SCR, Hangzhou Dianzi University, 2017, 6.
  • [10] SAMOJEDEN B., MOTAK M., GRZYBEK T., The influence of the modification of carbonaceous materials Cross Mark on their catalytic properties in SCR-NH3. A short review, Compt. Rend. Chim., 2015, 18, 1049–1073. DOI: 10.1016/j.crci.2015.04.001.
  • [11] CHENG X.X., BI X.T.T., A review of recent advances in selective catalytic NOx reduction reactor technologies, Partic., 2014, 16, 1–18. DOI: 10.1016/j.partic.2014.01.006.
  • [12] YANG J., MEI Y., WANG C., LONG G., LI S., Current status and trends on wet flue gas denitration technology, Chem. Ind. Eng. Progr., 2017, 36, 695–704. DOI: 10.16085/j.issn.1000-6613.2017.02.041.
  • [13] LIN S., Research progress of simultaneous desulfurization and denitrification by liquid phase oxidation absorption, Coal Chem. Ind., 2015, 43, 24–27.
  • [14] PAN J., DENG J., ZHANG Q., Application progress of advanced oxidation technology of hydroxyl radical, J. Guangdong University of Technology, 2019, 2, 70–77.
  • [15] BRILLAS E., GARCIA-SEGURA S., Benchmarking recent advances and innovative technology approaches of Fenton, photo-Fenton, electro-Fenton, and related processes. A review on the relevance of phenol as a model molecule, Sep. Purif. Technol., 2020, 237, 116337. DOI: 10.1016/j.seppur. 2019.116337.
  • [16] CUI R., MA S., WANG J., SUN S., NO oxidation over Fe-based catalysts supported on montmorillonite K10, g-alumina and ZSM-5 with gas-phase H2O2, Chemosphere, 2019, 234, 302–309. DOI: 10.1016 /j.chemosphere.2019.06.029.
  • [17] SONG Z., WANG B., YANG W., CHEN T., MA C., SUN L., Simultaneous removal of NO and SO2 through heterogeneous catalytic oxidation-absorption process using magnetic Fe2.5M0.5O4 (M = Fe, Mn, Ti and Cu) catalysts with vaporized H2O2, Chem. Eng. J., 2020, 386, 123883. DOI: 10.1016 /j.cej.2019.123883.
  • [18] WEN Z., SHEN H., LIU Y., HUANG Q., Experimental study on the NO oxidation and removal by heterogeneous Fenton reaction, J. Environ. Eng., 2022, 148 (1). DOI:10.1061/(asce)ee.1943-7870.0001963.
  • [19] PHAM A.L.T., LEE C., DOYLE F.M., SEDLAK D.L., A silica-supported iron oxide catalyst capable of activating hydrogen peroxide at neutral pH values, Environ. Sci. Technol., 2009, 43, 8930–8935. DOI: 10.1021/es902296k.
  • [20] LI H., WU J., LIU J., Finite element mesh generation and mesh quality judgment index, China Mech. Eng., 2012, 23, 368–377.
  • [21] WENZ.C.,LIUY.,SHEN H.,XU J.,A theoretical study on the destruction of typical biomass tar components(toluene, phenol and naphthalene) by•OHradicals, J. Indian Chem. Soc.,2021,98, 100015. DOI: 10.1016/j.jics.2021.100015.
  • [22] MA S.,MA J.,ZHAO Y., Experimental study on flue gas desulfurization and denitrification with UV/H2O2system, Proc.CSEE,2009, 5, 27–31.
  • [23] LI L.,GAO N., Effect of anionson degradation of bisphenol Aby UV/H2O2microaeration process, China Environ. Sci., 2008,28, 4. DOI: 10.3321/j.issn:1000-6923.2008.03.009.
  • [24] HUANGZ., XIEX., Energy revolution under vision of carbon neutrality, Bull. Chinese Academy of Sciences, 2021,2021, 36, 1010–1018. DOI: 10.16418/j.issn.1000-3045.20210812001.
  • [25] WENZ.C.,LIUY.,SHEN H.Z.,DING N.,LI Y.,LUO D., Mechanism and kinetic study on the degradation of typical biomass tar components (toluene, phenol and naphthalene) by ozone, Ozone Sci. Eng., 2021,43, 78–87. DOI: 10.1080/01919512.2020.1760077.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a586a654-ee6c-4d60-bca8-fc99f1962ad1
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.