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The present study is focused on development of environmentally friendly intumes-cent/char forming coatings for wood and polymeric materials. For this purpose we have developed the method of oxidation of raw materials: polysaccharides, seeds and lignin by oxygen in the presence of a catalyst. The main products of oxidation of such substrates are the salts of polyoxyand polyphenoxy acids. The efficiency of fireproofing action of novel surface protecting intumescent coating for wood and polymeric materials based on modified renewable raw materials was studied. Flammability tests of wood and polymer samples treated by oxidized raw materials confirm their high-performance in fire protection.
Słowa kluczowe
Czasopismo
Rocznik
Strony
617--624
Opis fizyczny
Bibliogr. 24 poz., rys.
Twórcy
autor
- N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosygin str., 119334 Moscow, Russia
autor
- N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosygin str., 119334 Moscow, Russia
autor
- N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosygin str., 119334 Moscow, Russia
Bibliografia
- 1. Lomakin S.M., Brown J.E., Breese R.S. and Nyden M.R., Polymer Degrad. And Stab. 41, 229-243 (1993).
- 2. Factor A., Char Formation in Aromatic Engineering Polymers, in Fire and Polymers, Ed. Nelson G. L. (Ed.), pp. 274-287, ACS Symposium Series 425, ASC, Washinton DC (1990).
- 3. Lomakin S.M., Zaikov G.E. and Artsis M.I., Intern. J. Polym. Mater. 32 (1-4) 173-202 (1996).
- 4. Lomakin S.M., Zaikov G.E., Artsis M.I., Ruban L.V. and Aseeva R.M., Oxidation Comm. 18 (2), 105-112 (1995).
- 5. Lomakin S.M., Zaikov G.E. and Artsis M.I., Intern. J. Polym. Mater. 26 (3-4), 187-194 (1994).
- 6. R.M. Aseeva, G.E. Zaikov. Combustion of Polymeric Materials. Moscow: Nauka, 1981, pp. 84-135 (in Russian).
- 7. S. Levchik and Ch. A. Wilkie, Char Formation, Chapter 6 in Fire Retardancy of Polymeric Materials, ed. By A.F. Grand and Ch.A. Wilkie, Marcel Dekker, Inc. New York (2000), 171-216
- 8. G. Camino, Flame retardants: Intumescent systems. In: G Pritchard, ed. Plastics Additives, London: Chapmann Hall, 1998, pp. 297-306.
- 9. G. Camino and R. Delobel, Intumescence, Chapter 7 in Fire Retardancy of Polymeric Materials, ed. By A.F. Grand and Ch. A. Wilkie, Marcel Dekker, Inc. New York (2000), 217-244
- 10. G. Camino, S. Lomakin. Intumescent materials In: A R Horrocks and D Price, eds., Fire Retardant Materials, CRC Press, New York, Washington DC (2001), 318-335.
- 11. Vandersall H L, Intumescent coating systems, their development and chemistry J Fire Flamm, 1971, 2 April: 97-140
- 12. R. Kozlowski and M. Wladyka-Przybylak, Natural polymers, wood and lignocellulosic materials In: A R Horrocks and D Price, eds., Fire Retardant Materials, CRC Press, New York, Washington DC (2001), 293-317.
- 13. Hurst N W, Jones T A, A review of products evolved from heated coal, wood and PVC, Fire Mater, 1985, 9(1), 1-9.
- 14. Lewin M, Atlas S M, Pearce E M, „Flame-Retardant Polymeric Materials”, vol 1, New York and London, Plenum Press, 1975.
- 15. Sakharov A.M. In: Chemical and Biochemical Physics: New Frontiers (2006), Editor: Zaikov G.E., Nova Science Publishers, 113.
- 16. Sivenkov A.B., Serkov B.B., Aseeva R.M., Sakharov A.M., Sakharov P.A., Skibida I.P. (2002). Fire & Explosion Safety. 1, 39. (in Russian).
- 17. Floor M., Kieboom A.P.G., H. van Bekhum. (1989). Starch, 41, 303.
- 18. Santacesria E., Trully F., Brussani G.F., Gelosa D., Serio M.Di. (1994).
- 19. C. Skibida I.P., Sakharov An.M., Sakharov Al.M. (1993). EP 91122164.6, Carbohydrate Polymers, 23, 35.
- 20. Sakharov A.M., Skibida I.P. (2001). Chem. Phys., 20, 101.
- 21. Sakharov A.M., Silakhtaryan N.T., Skibida I.P. (1996). Kinetics and Catalysis, 37, 393.
- 22. Cereal Straw as a Resource for Sustainable Biomaterials and Biofuels: Chemistry, Extractives, Lignins, Hemicelluloses and Cellulose, Ed. By Run-Cang Sun Elsevier, 2010, 292 p.
- 23. H. Hatakeyama and T. Hatakeyama, Lignin Structure, Properties, and Applications. In Biopolymers - Lignin, Proteins, Bioactive Nanocomposites, ed. By A. Abe, K. Dušek and Sh. Kobayashi, Springer, Heidelberg, Dordrecht, London, New York, 2010, p.2-64
- 24. Standard Test Method for Screening Test for Mass Loss and Ignitability of Materials (ASTM E2102). American Society for Testing and Materials, Philadelphia, PA.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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