Removal of methyl violet dye by a photocatalytic process using variations of TiO2/zeolite synthesized from muscovite raw material

Fatimah, Husnul; Taba, Paulina; Fauziah, St.; Karim, Abdul; Liong, Syarifuddin; Kasim, Syahruddin; Sultan, Sahrul; Pardan, Nur Akifah

doi:10.12911/22998993/200503

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Removal of methyl violet dye by a photocatalytic process using variations of TiO2/zeolite synthesized from muscovite raw material

Autorzy

Fatimah Husnul , Taba Paulina , Fauziah St. , Karim Abdul , Liong Syarifuddin , Kasim Syahruddin , Sultan Sahrul , Pardan Nur Akifah

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DOI

10.12911/22998993/200503

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Języki publikacji

Abstrakty

The removal of methyl violet dye through a photocatalytic process has been successfully carried out. This study aimed to evaluate the photocatalytic efficiency of TiO₂/zeolite catalysts in degrading methyl violet dye. Zeolites were synthesized from silica and aluminum sources derived from muscovite raw materials using the hydrothermal method, resulting in two types of zeolites: cancrinite (CAN) in synthesis A and analcime (ANA) in synthesis B. The zeolites were combined with anatase-phase TiO₂ to form photocatalysts, with XRD analysis confirming the cubic structure of analcime and hexagonal cancrinite in the anatase phase. FTIR spectra showed sharp bands in the 468–1005 cm^-1 wave number range. SEM analysis showed that TiO₂/analcime exhibited a hexagonal morphology with a crystal size of 10.58 μm, while TiO₂/cancrinite had a rod-shaped morphology with a crystal size of 21.3 μm. Surface area analysis showed that TiO₂/ANA and TiO₂/CAN had surface areas of 34.80 m²/g and 23.08 m²/g, respectively, with pore diameters > 2 nm, which confirmed their mesoporous nature based on the BJH method. UV-DRS analysis showed band gap energies of 3.13 eV for TiO₂/ANA and 3.11 eV for TiO₂/CAN. Photodegradation tests showed that the TiO₂/ANA catalyst exhibited higher methyl violet degradation efficiency than TiO₂/CAN. This study high-lighted the potential of TiO₂/zeolite-based photocatalysts for effective treatment of dye-contaminated wastewater, contributing to environmental sustainability.

Słowa kluczowe

methyl violet TiO2 semiconductor muscovite raw material TiO2/ANA TiO2/CAN

Wydawca

Polskie Towarzystwo Inżynierii Ekologicznej
Lublin University of Technology

Czasopismo

Journal of Ecological Engineering

Rocznik

2025

Tom

Vol. 26, nr 5

Strony

73--86

Opis fizyczny

Bibliogr. 53 poz., rys., tab.

Twórcy

autor

Fatimah Husnul

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0009-0006-2836-1360

autor

Taba Paulina

paulinataba@unhas.ac.id

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0000-0001-7327-5505

autor

Fauziah St.

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0000-0002-0599-4011

autor

Karim Abdul

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0000-0001-9272-9779

autor

Liong Syarifuddin

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0000-0002-2762-5188

autor

Kasim Syahruddin

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0000-0002-3449-7057

autor

Sultan Sahrul

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0009-0004-7635-9930

autor

Pardan Nur Akifah

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar, Indonesia

https://orcid.org/0000-0003-3307-595X

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