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The process of pyrolysis is investigated in this paper. The pyrolysis results of two samples: waste tyres and rubber at different heating rates (10, 20, 50 K/min), were compared. In other experiments the degradation of two pyrolysis products, char and oil was examined. The kinetic study using the thermogravimetry equipment (TG) was done, which allowed determination of the kinetic mechanism of the process. The elemental analysis of the samples was performed.
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Tom
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802--811
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- Gdansk University of Technology, Narutowicza 11/12, 80-233 Gdansk, Poland
autor
- Institute of Fluid-Flow Machinery Polish Academy of Sciences, Fiszera 14, 80-231Gdansk, Poland
autor
- Gdansk University of Technology, Narutowicza 11/12, 80-233 Gdansk, Poland
autor
- Institute of Fluid-Flow Machinery Polish Academy of Sciences, Fiszera 14, 80-231Gdansk, Poland
Bibliografia
- ABOULKAS A., EL HARFI K., EL BOUADILI A., 2008, Kinetic and mechanism of Tarfaya (Morocco)oil shale and LDPE mixture pyrolysis, J. Mater. Process. Technol.206, 16–24.
- ARABIOURRUTIA M., LOPEZ G., ELORDI G., OLAZAR M., AGUADO R., BILBAO J., 2007, Product distribution obtained in the pyrolysis of tyres in a conical spouted bed reactor, Chem. Eng. Sci. 62, 5271–5275.
- CUNLIFFE A.M., WILLIAMS P.T., 1998, Composition of oils derived from the batch pyrolysis of tyres, J. Anal. Appl. Pyrolysis 44, 131–152.
- DAI X., YIN X., WU C., ZHANG W., CHEN Y., 2001, Pyrolysis of waste tires in a circulating fluidized-bed reactor, Energy 26, 385–399.
- DIEZ C., MARTINEZ O., CALVO L.F., CARA J., MORAN A., 2004, Pyrolysis of tyres. Influence of the final temperature of the process on emissions and the calorific value of the products recovered, Waste Manage. 24, 463–469.
- ENCINAR J.M., GONZALEZ J.F., CANITO J.L., RODRIGUEZ J.J., 2000, Fixed-bed pyrolysis of Cynara cardunculus L. Product yields and compositions., Fuel Process. Technol. 68 (3), 209–222.
- GONZÁLEZ, J. F., ENCINAR, J. M., CANITO, J. L., RODRÍGUEZ, J. J., 2001, Pyrolysis of automobile tyre waste. Influence of operating variables and kinetics study. J. Anal. Appl. Pyrolysis 58–59, 667–683.
- HEYDARI M., RAHMAN M., GUPTA R., 2015, Kinetic study and thermal decomposition behavior of lignite coal, Int. J Chem. Eng, vol. 2015.
- ISLAM M.R., HANIU H., FARDOUSHI J., 2009, Pyrolysis kinetics behavior of solid tire wastes available in Bangladesh, Waste Manage. 29, 668–677.
- JANUSZEWICZ K., 2013., Analiza własności fizykochemicznych i możliwości wykorzystania oleju i gazu, powstających w procesie pirolizy opon samochodowych. in Polish (Analysis of the physicochemical properties and the development of methods of management of oil and gas formed by tire pyrolysis), Thesis for the degree of Doctor of Science, Gdanks University of Technology.
- KAMINSKY W., MENNERICH C., 2001, Pyrolysis of synthetic tire rubber in a fluidized-bed reactor to yield 1,3-butadiene, styrene and carbon black, J. Anal. Appl. Pyrolysis 58–59, 803–811.
- KAMINSKY W., MENNERICH C., ZHANG Z., 2009, Feedstock recycling of synthetic and natural rubber by pyrolysis in a fluidized bed, J. Anal. Appl. Pyrolysis 85, 334–337.
- KIM W.I., KIM S.D., LEE S. B., HONG I.K, 2000, Kinetic characterization of thermal degradation process of commercial rubbers, J. Ind. Eng. Chem. 5 (vol. 6).
- LI S.-Q., YAO Q., CHI Y., YAN J.-H., CEN K.-F., 2004, Pilot-Scale Pyrolysis of Scrap Tires in a Continuous Rotary Kiln Reactor, Ind. Eng. Chem. Res. 43, 5133-5145.
- LOPEZ G., AGUADO R., OLAZAR M., ARABIOURRUTIA M., BILBAO J., 2009, Kinetics of scrap tyre pyrolysis under vacuum conditions, Waste Manage. 29, 2649–2655.
- LOPEZ G., OLAZAR M., AGUADO R., BILBAO J., 2010, Continuous pyrolysis of waste tyres in a conical spouted bed reactor, Fuel 89, 1946–1952.
- MAATEN B., LOO L., KONIST B., NESUMAJER D., PIHU T., KULAOTS I., Decomposition kinetic of American, Chinese and Estonian oil shales kerogen, 2016, Oil shale 33, 167-183.
- MATALA, A., Methods and applications of pyrolysis modeling for polymeric materials, 2013, Thesis for the degree of Doctor of Science.
- OLAZAR M., LOPEZ G., ARABIOURRUTIA M., ELORDI G., AGUADO R., BILBAO J., 2008, Kinetic modelling of tyre pyrolysis in a conical spouted bed reactor, J. Anal. Appl. Pyrolysis 81, 127–13.
- SYED S., QUDAIH R., TALAB I., JANAJREH I., 2011, Kinetics of pyrolysis and combustion of oil shale sample from thermogravimetric data, Fuel 90, 1631–1637.
- QUEK A., BALASUBRAMANIAN R., 2012, Matematical modeling of rubber tire pyrolysis, J. Anal. Appl. Pyrolysis 95, 1–13.
- YAO F., WU Q., LEI Y., GUO W., XU Y., 2008, Thermal decomposition kinetics of natural fi bers: Activation energy with dynamic thermogravimetric analysis, Polym. Degrad. Stabil. 93, 90–98.
Typ dokumentu
Bibliografia
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