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Adsorption of copper ions from aqueous solutions on natural zeolite

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The adsorption of copper ions from synthetic aqueous solutions on natural zeolite (clinoptilolite) was examined. In order to determine the rate of adsorption and the copper uptake at equilibrium, a series of experiments were performed under batch conditions from single ion solutions. Equilibrium data were evaluated based on adsorption (Langmuir and Freundlich) isotherms. The adsorption kinetics is reasonably fast. In the first 20 min of the experiment, approximately 80% of Cu2+ ions is adsorbed from the solutions. Data obtained from the kinetic experiments have been described by the pseudo-second order kinetic model as well as by the Weber–Morris and Furusawa–Smith models.
Rocznik
Strony
17--36
Opis fizyczny
Bibliograf. 27 poz., tab., rys.
Twórcy
autor
  • Faculty of Natural and Technical Sciences, Goce Delcev University, Stip, Macedonia
autor
  • Faculty of Natural and Technical Sciences, Goce Delcev University, Stip, Macedonia
autor
  • Faculty of Technology, Goce Delcev University, Probistip, Macedonia
autor
  • Faculty of Natural and Technical Sciences, Goce Delcev University, Stip, Macedonia
autor
  • Faculty of Natural and Technical Sciences, Goce Delcev University, Stip, Macedonia
autor
  • Faculty of Computer Science, Goce Delcev University, Stip, Macedonia
Bibliografia
  • [1] RAJIC N., STOJAKOVIC DJ., JOVANOVIC M., LOGAR N.Z., MAZAJ M., KAUCIC V., Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite, Appl. Surf. Sci., 2010, 257 (5), 1524.
  • [2] SAG Y., AKTAY Y., Mass transfer and equilibrium studies for the sorption of chromium ions onto chitin, Process Biochem., 2000, 36, 157.
  • [3] KOBYA M., DEMIRBAS E., SENTURK E., INCE M., Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone, Bioresource Technol., 2005, 96 (13), 1518.
  • [4] TAFFAREL S.R., RUBIO J., On the removal of Mn2+ ions by adsorption onto natural and activated Chilean zeolites, Miner. Eng., 2009, 22, 336.
  • [5] BOGDANOVIC G.D., STANKOVIC V., ANTIC D.V., PRODANOVIC S., ANDRIC L., VEGNER D., Adsorption of copper and zink ions from acid mine drainage by natural zeolite, Proc. 15th Balkan Mineral Processing Congress, Sozopol, Bulgaria, 2013, 989.
  • [6] MOTSI T., Remediation of acid mine drainage using natural zeolite, Doct. Thesis, School of Chemical Engineering, The University of Birmingham, 2010.
  • [7] ERDEM E., KARAPINAR N., DONAT R., The removal of heavy metal cations by natural zeolites, J. Coll. Interf. Sci., 2004, 280 (2), 309.
  • [8] BOGDANOVIC G.D., ANTIC D.V., BEGOVIC J., STANKOVIC V., Adsorption of heavy metals from aqueous solution by natural zeolite, Proc. 14th Balkan Mineral Processing Congress, Tuzla, Bosnia and Herzegovina, 2011, 773.
  • [9] CONNORS K.A., Chemical Kinetics: The Study of Reaction Rates in Solution, VCH Publishers, USA, 1990.
  • [10] OKEWALE A.O., BABAYEMI K.A., OLALEKAN A.P., Adsorption Isotherms and kinetics models of starchy adsorbents on uptake of water from ethanol. Water systems, Int. J. Appl. Sci. Technol., 2013, 3 (1), 35.
  • [11] HO Y.S., MCKAY G., Pseudo-second order model for sorption processes, Process Biochem., 1999, 34, 451.
  • [12] FURUSAWA T., SMITH J.M., Fluid–particle and intraparticle mass transport rates in slurries, Ind. Eng. Chem. Fund., 1973, 12 (2), 197
  • [13] CRINI G., BADOT P., Sorption processes and pollution. Conventional and non-conventional sorbents for pollutant removal from wastewater, Presses Universitaires de Franche-Comte, 2010.
  • [14] SUTHERLAND C., VENKOBACHAR C., A diffusion-chemisorption kinetic model for simulating biosorption using forest macro-fungus, fomes fasciatus, Int. Res. J. Plant Sci., 2010, 1(4), 107.
  • [15] ARMENANTE P.M., Adsorption, Industrial Waste Control. Physical and Chemical Treatment, New Jersey Institute of Technology, 1999.
  • [16] LANGMUIR I., The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc., 1918, 40, 1361.
  • [17] PAPAGEORGIOU K.S., KATSAROS K.F., KOUVELOS P.E., NOLAN W.J., LEDEIT H., KANELLOPOULOS K.N., Heavy metal sorption by calcium alginate beads from Laminaria digitata, J. Hazard. Mater., 2006, B137, 1765.
  • [18] ALVAREZ-AYUSO E., GARCIA-SANCHEZ A., QUEROL X., Purification of metal electroplating waste waters using zeolites, Water Res., 2003, 37, 4855.
  • [19] AVILA M.A.S., Experiment and modelling of the competitive sorption and transport of chlorinated ethenes in porous media, Cuvillier Verlag, Göttingen 2005.
  • [20] GUNAY A., ARSLANKAYA E., TOSUN I., Lead removal from aqueous solution by natural and pretreated clinoptilolite. Adsorption equilibrium and kinetics, J. Hazard. Mater., 2007, 146, 362.
  • [21] BARRER R.M., Zeolites and clay minerals as sorbents and molecular sieves, Academic Press, Inc., London 1978.
  • [22] CABRERA C., GABALDON C., MARZAL P., Sorption characteristics of heavy metal ions by a natural zeolite, J. Chem. Techn. Biotechn., 2005, 80, 477.
  • [23] HARLAND C.E., Ion Exchange. Theory and Practice, 2nd Ed., The Royal Society of Chemistry, Cambridge 1994.
  • [24] HAMEED B.H., EL-KHAIARY M.I., Malachite Green adsorption by rattan sawdust. Isotherm, kinetic, J. Hazard. Mater., 2008, 159, 574.
  • [25] TAN I.A.W., HAMEED B.H., Adsorption isotherms, kinetics, thermodynamics and desorption studies of basic dye on activated carbon derived from oil palm empty fruit bunch, J. Appl. Sci., 2010, 10, 2565.
  • [26] ÇAGIN V., Use of clinoptilolite for copper and nickel removal from aqueous solutions, The Graduate School of Natural and Applied Sciences of Middle East Technical University, Ankara 2006.
  • [27] BROWN M., BARLEY B., WOOD H., Mine water treatment. Technology, application and policy, IWA Publishing, London 2002, 448.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a4b0520c-b1ea-4066-8e2c-8d42c334123f
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