Modification of Surface Morphology and Surface Properties of Copper-Nickel Alloy by Anodic Treatment in a Deep Eutectic Solvent (Ethaline)

• Autorzy: Protsenko Vyacheslav , Butyrina Tatyana , Makhota Dmytro , Korniy Sergiy , Danilov Felix

Identyfikatory

DOI

10.24425/amm.2023.142425

• Języki publikacji: EN

Abstrakty

EN

A deep eutectic solvent, ethaline (as a typical representative of new-generation room temperature ionic liquids), was used to anodically treat the surface of copper-nickel alloy (55 wt.% Cu). Anodic treatment in ethaline allows flexibly affecting the patterns of surface morphology: formation of stellated crystallites and surface smoothing (i.e. electropolishing) are observed depending on the applied electrode potential. The measured values of roughness coefficient (R_a) well correlate with the changes in surface morphology. Anodic treatment of Cu-Ni alloy in ethaline contributes to a considerable increase in the electrocatalytic activity towards the hydrogen evolution reaction in an alkaline aqueous medium, which can be used to develop new high-efficient and inexpensive electrocatalysts within the framework of the concept of carbon-free hydrogen economy.

Słowa kluczowe

EN

copper-nickel alloy; anodic treatment; deep eutectic solvent; surface morphology; hydrogen production

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2023
• Tom: Vol. 68, iss. 2
• Strony: 477--482
• Opis fizyczny: Bibliogr. 39 poz., fot., rys., tab.

Twórcy

autor

Protsenko Vyacheslav

• Ukrainian State University of Chemical Technology, Department of Physical Chemistry, Gagarin Ave., 8, Dnipro, 49005, Ukraine

• https://orcid.org/0000-0002-5959-0426

autor

Butyrina Tatyana

• Ukrainian State University of Chemical Technology, Department of Physical Chemistry, Gagarin Ave., 8, Dnipro, 49005, Ukraine

• https://orcid.org/0000-0002-0619-6783

autor

Makhota Dmytro

• Ukrainian State University of Chemical Technology, Department of Physical Chemistry, Gagarin Ave., 8, Dnipro, 49005, Ukraine

• https://orcid.org/0000-0003-1541-9704

autor

Korniy Sergiy

• Ukrainian State University of Chemical Technology, Department of Physical Chemistry, Gagarin Ave., 8, Dnipro, 49005, Ukraine
• Karpenko Physico-Mechanical Institute of the NAS of Ukraine, Naukova St. 5, Lviv, 79060, Ukraine

• https://orcid.org/0000-0003-3998-2972

autor

Danilov Felix

• Ukrainian State University of Chemical Technology, Department of Physical Chemistry, Gagarin Ave., 8, Dnipro, 49005, Ukraine

• https://orcid.org/0000-0001-6058-6056

Bibliografia

• [1] M.P. Martínez-Viademonte, S.T. Abrahami, T. Hack, M. Burchardt, H. Terryn, Coatings 10, 1106 (2020). DOI: https://doi.org/10.3390/coatings10111106
• [2] S. Moon, J. Korean Inst. Surf. Eng. 51, 1-10 (2018). DOI: https://doi.org/10.5695/JKISE.2018.51.1.1
• [3] A.C. Alves, F. Wenger, P. Ponthiaux, J.-P. Celis, A.M. Pinto, L.A. Rocha, J.C.S. Fernandes, Electrochim. Acta 234, 16-27 (2017). DOI: https://doi.org/10.1016/j.electacta.2017.03.011
• [4] K. Engelkemeier, A. Sun, D. Voswinkel, O. Grydin, M. Schaper, W. Bremser, ChemElectroChem 8, 2155-2168 (2021). DOI: https://doi.org/10.1002/celc.202100216
• [5] O. Lebedeva, D. Kultin, A. Zakharov, L. Kustov, Metals 11, 959 (2021). DOI: https://doi.org/10.3390/met11060959
• [6] D. Landolt, P.-F. Chauvy, O. Zinger, Electrochim. Acta 48, 3185-3201 (2003). DOI: https://doi.org/10.1016/S0013-4686(03)00368-2
• [7] K. Juodkazis, J. Juodkazytė, R. Vilkauskaitė, V. Jasulaitienė, J. Solid State Electrochem. 12, 1469-1479 (2008). DOI: https://doi.org/10.1007/s10008-007-0484-0
• [8] A. Renjith, A. Roy, V. Lakshminarayanan, J. Colloid Interface Sci. 426, 270-279 (2014). DOI: https://doi.org/10.1016/j.jcis.2014.04.015
• [9] C. Yang, Q.B. Zhang, M.Y. Gao, Y.X. Hua, C.Y. Xu, J. Electrochem. Soc. 163, D469-D475 (2016). DOI: https://doi.org/10.1149/2.0461609jes
• [10] L.I.N. Tomé, V. Baião, W. da Silva, C.M.A. Brett, Appl. Mater. Today 10, 30-50 (2018). DOI: https://doi.org/10.1016/j.apmt.2017.11.005
• [11] E.L. Smith, A.P. Abbott, K.S. Ryder, Chem. Rev. 114, 11060-11082 (2014). DOI: https://doi.org/10.1021/cr300162p
• [12] Q. Zhang, K.D.O. Vigier, S. Royer, F. Jérôme, Deep eutectic solvents: syntheses, properties and applications, Chem. Soc. Rev. 41, 7108-7146 (2012). DOI: https://doi.org/10.1039/c2cs35178a
• [13] B.B. Hansen, S. Spittle, B. Chen, D. Poe, Y. Zhang, J.M. Klein, A. Horton, L. Adhikari, T. Zelovich, B.W. Doherty, B. Gurkan, E.J. Maginn, A. Ragauskas, M. Dadmun, T.A. Zawodzinski, G.A. Baker, M.E. Tuckerman, R.F. Savinell, J.R. Sangoro, Chem. Rev. 121, 1232-1285 (2021). DOI: https://doi.org/10.1021/acs.chemrev.0c00385
• [14] E.L. Smith, Trans. Inst. Met. Finish. 91, 241-248 (2013). DOI: https://doi.org/10.1179/0020296713Z.000000000120
• [15] A. Kityk, M. Hnatko, V. Pavlik, M. Boča, Mater. Res. Bull. 141, 111348 (2021). DOI: https://doi.org/10.1016/j.materresbull.2021.111348
• [16] K. Alrbaey, D.I. Wimpenny, A.A. Al-Barzinjy, A. Moroz, J. Mater. Eng. Perform. 25, 2836-2846 (2016). DOI: https://doi.org/10.1007/s11665-016-2140-2
• [17] A.P. Abbott, G. Capper, K.J. McKenzie, A. Glidle, K.S. Ryder, Phys. Chem. Chem. Phys. 8, 4214-4221 (2006). DOI: https://doi.org/10.1039/b607763n
• [18] A.J. Goddard, R.C. Harris, S. Saleem, M. Azam, C. Hood, D. Clark, J. Satchwell, K.S. Ryder, Trans. Inst. Met. Finish. 95, 137-146 (2017). DOI: https://doi.org/10.1080/00202967.2016.1270616
• [19] W.O. Karim, A.P. Abbott, S. Cihangir, K.S. Ryder, Trans. Inst. Met. Finish. 96, 200-205 (2018). DOI: https://doi.org/10.1080/00202967.2018.1470400
• [20] V.S. Protsenko, T.E. Butyrina, L.S. Bobrova, S.A. Korniy, F.I. Danilov, Mater. Lett. 270, 127719 (2020). DOI: https://doi.org/10.1016/j.matlet.2020.127719
• [21] T.M. Abdel-Fattah, J.D. Loftis, Molecules 25, 5712 (2020). DOI: https://doi.org/10.3390/molecules25235712
• [22] A.A. Kityk, V.S. Protsenko, F.I. Danilov, O.V. Kun, S.A. Korniy, Surf. Coat. Technol. 375, 143-149 (2019). DOI: https://doi.org/10.1016/j.surfcoat.2019.07.018
• [23] W.O. Karim, J.A. Juma, K.M. Omer, Y.M. Salih, K.H.H. Aziz, S.B. Aziz, Electrochemistry 88, 1-4 (2020). DOI: https://doi.org/10.5796/electrochemistry.20-00038
• [24] A. Kityk, V. Protsenko, F. Danilov, V. Pavlik, M. Hnatko, J. Šoltýs, Colloids Surf. A 613, 126125 (2021). DOI: https://doi.org/10.1016/j.colsurfa.2020.126125
• [25] A.A. Kityk, F.I. Danilov, V.S. Protsenko, V. Pavlik, M. Boča, Y. Halahovets, Surf. Coat. Technol. 397, 126060 (2020). DOI: https://doi.org/10.1016/j.surfcoat.2020.126060
• [26] R. Dehdari Vais, H. Yadegari, N. Sattarahmady, H. Heli, J. Electroanal. Chem. 815, 134-142 (2018). DOI: https://doi.org/10.1016/j.jelechem.2018.03.017
• [27] C. Yang, Q.B. Zhang, M.Y. Gao, Y.X. Hua, C.Y. Xu, J. Electrochem. Soc., 163, D469-D475 (2016). DOI: https://doi.org/10.1149/2.0461609jes
• [28] A.P. Abbott, G. Frisch, J. Hartley, W.O. Karim, K.S. Ryder, Prog. Nat. Sci. Mater. Int. 25, 595-602 (2015). DOI: https://doi.org/10.1016/j.pnsc.2015.11.005
• [29] W.O. Karim, J.A. Juma, K.M. Omer, K.H. Hama Aziz, Y.M. Salah, S.B. Aziz, Electrochemistry 89, 71-74 (2021). DOI: https://doi.org/10.5796/electrochemistry.20-00129
• [30] W.O. Karim, S.B. Aziz, M.A. Brza, R.M. Abdullah, M.F.Z. Kadir, Appl. Sci. 9, 4401 (2019). DOI: https://doi.org/10.3390/app9204401
• [31] A.P. Abbott, G. Frisch, S.J. Gurman, A.R. Hillman, J. Hartley, F. Holyoak, K.S. Ryder, Chem. Commun. 47, 10031-10033 (2011). DOI: https://doi.org/10.1039/c1cc13616j
• [32] Q.B. Zhang, Y.X. Hua, Phys. Chem. Chem. Phys. 16, 27088-27095 (2014). DOI: https://doi.org/10.1039/c4cp03041a
• [33] C. Yang, Q.B. Zhang, A.P. Abbott, Electrochem. Commun. 70, 60-64 (2016). DOI: https://doi.org/10.1016/j.elecom.2016.07.004
• [34] J.O’M. Bocris, B.T. Rubin, A. Despic, B. Lovrecek, Electrochim. Acta 17, 973-999 (1972). DOI: https://doi.org/10.1016/0013-4686(72)90017-5
• [35] K.M. Ismail, A.M. Fathi, W.A. Badawy, Corros. Sci. 48, 1912-1925 (2006). DOI: https://doi.org/10.1016/j.corsci.2005.07.004
• [36] J.K. Chang, S.H. Hsu, I.W. Sun, W.T. Tsai, J. Phys. Chem. C 112, 1371-1376 (2008). DOI: https://doi.org/10.1021/jp0772474
• [37] F.K. Crundwell, Electrochim. Acta 36, 2135-2141 (1991). DOI: https://doi.org/10.1016/0013-4686(91)85221-R
• [38] D. Landolt, Electrochim. Acta 32, 1-11 (1987). DOI: https://doi.org/10.1016/0013-4686(87)87001-9
• [39] D. Landolt, P.-F. Chauvy, O. Zinger, Electrochim. Acta 48, 3185-3201 (2003). DOI: https://doi.org/10.1016/S0013-4686(03)00368-2

Uwagi

This work was supported by the Ministry of Education and Science of Ukraine (project no. 0121U109551).