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A successful operational initiative in copper oxide flotation: Sequential sulphidisation-flotation technique

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Języki publikacji
EN
Abstrakty
EN
One of the main challenges in the copper oxide processing industry is implementation of a flotation method to reduce operating costs. Sulphidising flotation is the most common used technique in which a sulphidisation agent is used to sulphidise the surface of the oxide minerals. In this research, the mentioned technique was used sequentially for the concentration of silicate-carbonate ore containing 3.1% Cu (malachite). The presence of 39% Cu in -38 μm size fraction (fine particles) of feed led to poor grades and recoveries in the initial tests. The addition of sodium sulfide and subsequent flotation at three sequential stages was identified as a successful operational initiative to solve this problem in the following tests. The dosages of 1500, 1567 and 100 g/Mg of sodium silicate, sodium sulfide and potassium amyl xanthate, respectively, the conditioning time of 5 min for sulphidisation and pH=9.72 were chosen as optimum operational conditions using central composite design (CCD) method of experiments design. The rougher concentrate with 9.28% grade and 81.15% recovery was obtained under these conditions. The grade of obtained concentrate was reached to 24% in the cleaner step. The total recovery of both steps was over 74%.
Słowa kluczowe
Rocznik
Strony
356--369
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
  • Beneficiation and Hydrometallurgy Research Group, Mineral processing Research Center, Academic Center for Education, Culture and Research (ACECR) on TMU, Tehran, Iran
  • Department of Mining Engineering, Arak University of Technology, Markazi, Iran
  • Beneficiation and Hydrometallurgy Research Group, Mineral processing Research Center, Academic Center for Education, Culture and Research (ACECR) on TMU, Tehran, Iran
  • Department of Mining Engineering, Tarbiat Modares University, Tehran, Iran
  • Department of Mining Engineering, Tarbiat Modares University, Tehran, Iran
Bibliografia
  • BULATOVIC, S. M., 2010. Handbook of flotation reagents: chemistry, theory and practice, Volume 2: flotation of gold, pgm and oxide minerals. Elsevier.
  • CAO, Z.-F., ZHONG, H., LIU, G.-Y., ZHAO, S.-J., 2009. Techniques of copper recovery from Mexican copper oxide ore. Int. J. Min. Sci. Technol. 19, 1, 45-48.
  • CASTRO, S., GOLDFARB, J., LASKOWSKI, J., 1974. Sulphidizing reactions in the flotation of oxidized copper minerals, I. Chemical factors in the sulphidization of copper oxide. Int. J. Miner. Process. 1, 2, 141-149.
  • CASTRO, S., SOTO, H., GOLDFARB, J., LASKOWSKI, J., 1974. Sulphidizing reactions in the flotation of oxidized copper minerals, II. Role of the adsorption and oxidation of sodium sulphide in the flotation of chrysocolla and malachite. Int. J. Miner. Process. 1, 2, 151-161.
  • CHEN, Z., GU, G., ZHU, R., 2017. Structural modification of cellulose to enhance the flotation efficiency of fine copper oxide ore. Physicochem. Probl. Miner. Process. DOI: http://dx.doi.org/10.5277/ppmp1864.
  • CHOI, J., CHOI, S. Q., PARK, K., HAN, Y., KIM, H., 2016. Flotation behaviour of malachite in mono- and di-valent salt solutions using sodium oleate as a collector. Int. J. Miner. Process. 146, 38-45.
  • CORIN, K. C., KALICHINI, M., O‘CONNOR, C. T., SIMUKANGA, S., 2017. The recovery of oxide copper minerals from a complex copper ore by sulphidisation. Miner. Eng. 102, 15-17.
  • FUERSTENAU, M. C., MILLER, J. D., KUHN, M. C., 1985. Chemistry flotation, Society of Mining Engineers of the American Institute of Mining, Metallurgical and Petroleum Engineers.
  • GAO, Y.S., GAO, Z.Y., SUN, W., YIN, Z.G., WANG, J.J., HU Y.H.,2018b. Adsorption of a novel reagent scheme on scheelite and calcite causing an effective flotation separation. J. Colloid Interface Sci. 512, 39 46.
  • GAO, Z.Y., GAO, Y.S., ZHU, Y.Y., HU, Y.H., SUN, W., 2016 b. Selective flotation of calcite from fluorite: a novel reagentschedule . Minerals 6 (4), 114.
  • JORJANI, E., BARKHORDARI, H. R., TAYEBI KHORAMI, M., FAZELI, A., 2011. Effects of aluminosilicate minerals on copper–molybdenum flotation from Sarcheshmeh porphyry ores, Miner. Eng. 24, 8, 754-759.
  • KONGOLO, K., KIPOKA, M., MINANGA, K., MPOYO, M., 2003. Improving the efficiency of oxide copper–cobalt ores flotation by combination of sulphidisers. Miner. Eng. 16, 10, 1023-1026.
  • LEE, K., ARCHIBALD, D., MCLEAN, J., REUTER, M. A., 2009. Flotation of mixed copper oxide and sulphide minerals with xanthate and hydroxamate collectors. Miner. Eng. 22, 4, 395-401.
  • LI, C., GAO Z., 2017. Effect of grinding media on the surface property and flotation behavior of scheelite particles . Powder Technol 322, 386 392.
  • LI, F., ZHONG, H., XU, H., JIA, H., LIU, G., 2015. Flotation behavior and adsorption mechanism of α-hydroxyoctyl phosphinic acid to malachite. Miner. Eng. 71, 188-193.
  • LUTANDULA, M. SH., MALOBA, B., 2013. Recovery of cobalt and copper through reprocessing of tailings from flotation of oxidised ores. J. Environ. Chem. Eng. 1, 1085-1090.
  • MATIS, K. A., GALLIOS, G. P., KYDROS, K. A., 1993. Separation of fines by flotation techniques, Sep. Technol. 3, 2, 76-90.
  • MIRGOROD, YU. A., DOLENKO, T. A., 2015. Liquid Polyamorphous Transition and Self-Оrganization in Aqueous Solutions of Ionic surfactant. Langmuir, 31, 31, 8535-8547.
  • MYERS, R.H., MONTGOMERY, D.C., ANDERSON-COOK, C.M., 2009. Response surface methodology, process and product optimization using designed experiments. Third ed., John Wiley & Sons, Inc., Hoboken, New Jersey.
  • NAIK, P. K., SITA RAMA REDDY, P., 2006. Effect of sodium metasilicate on natural flotability of coal. Colloid. Polym. Sci. 284, 1024-1030.
  • PHETLA, T. P., MUZENDA, E., 2010. A multistage sulphidisation flotation procedure for a low grade malachite copper ore. Worl Academy of Science, Engineering and Technology, International Journal of Chemical and Molecular Engineering. 4, 9, 580-586.
  • SALEH, A.-H. M., RAMADAN, A. M., MOHARAM, M. R., 2008. Beneficiation of Egyptian Abu-Swayel copper ore by flotation. Physicochem. Probl. Miner. Process. 42, 119-130.
  • WHITCOMB, P.J., ANDERSON, M.J., 2004. RSM Simplified: Optimizing Processes Using Response Surface Methods for Design of Experiments. Productivity Press.
  • WIESS, N. L., 1985. SME mineral processing handbook. Society of Mining Engineers.
  • WU, D., MA, W., MAO, Y., DENG, J., WEN, SH., 2017. Enhanced sulfidation xanthate flotation of malachite using ammonium ions as activator. Scientific Reports, 7: 2086, DOI: 10.1038/S41598-017-02136-x.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a35dfcd8-69f8-41ec-80ff-835880843107
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