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The removal of Fe from the reduced ilmenite via aeration leaching assessing the effect of operating parameters

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
An upgrade of Malaysian ilmenite (FeTiO3) concentrate to synthetic rutile (TiO2) using aeration leaching was investigated in this study. Carbothermal reduction using Sarawak MukahBalingan coal and compressed National Gas (CNG) as a reductant was used to produce reduced ilmenite (RI) as an intermediate phase consisting of titanium oxide matrix with metallic iron prior to aeration leaching. Metallic iron was dissolved in ammonium chloride solution after the reduction process, separating synthetic rutile in the leaching residue. This study aims to evaluate the leaching parameters, such as concentration, temperature, and leaching time. The optimum conditions established by the design of the experiment (DOE) and the analysis of variance (ANOVA) has indicated that leaching temperature was the most significant parameter for iron dissolution. It was found that iron dissolution at a maximum value of 97.0% was achieved at an optimum condition of 0.5 M NH4Cl at 90°C for 7 hours. With an initial weight of 46 wt.%TiO2 and 37 wt.% Fe2O3, ilmenite was successfully upgraded to 80 wt.% and 8 wt.%, respectively. In conclusion, Malaysian ilmenite has a high potential value to be upgraded to synthetic rutile by aeration leaching with ammonium chloride via Becher process.
Rocznik
Strony
182--195
Opis fizyczny
Bibliogr. 30 poz., rys. kolor.
Twórcy
  • Mineral Strategy Niche Group, School of Material and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
  • Mineral Strategy Niche Group, School of Material and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
  • Mineral Strategy Niche Group, School of Material and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
  • Mineral Strategy Niche Group, School of Material and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
  • Mineral Strategy Niche Group, School of Material and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
  • Mineral Strategy Niche Group, School of Material and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
Bibliografia
  • ADIPURI, A., LI, Y., ZHANG, G., OSTROVSKI, O., 2011. Chlorination of reduced ilmenite concentrates and synthetic rutile. Int.J.Min.Process. 100, 166-171.
  • AHMADI, E., FAUZI, A., HUSSIN, H., BAHARUN, N., ARIFFIN,K.S., REZAN, S.A., 2017. Synthesis of titanium oxycarbonitride by carbothermal reduction and nitridation of ilmenite with recycling of polyethylene terephthalate (PET). Int. J. Min. Metall. and Mater. 24, 444-454.
  • AHMADI, E., SHOPARWE, N.I., IBRAHIM,N., ABDUL HAMID, S.A.R.S., FAUZI, A., ARIFFIN,K.S., HUSSIN, H., BAHARUN, N., , REZAN, S.A., 2018. The effect of experimental variables on iron removal from nitrided Malaysian ilmenite by Becher process. Extract., 1383-1396.
  • DEWAN, M.A., ZHANG, G., OSTROVSKI, O., 2009. Carbothermal Reduction of Titania in Different Gas Atmospheres. Metall. Mater. Trans. B. 40, 62–69.
  • DEWAN, M.A., ZHANG, G., OSTROVSKI, O., 2010. Phase Development in Carbothermal Reduction of Ilmenite Concentrates and Synthetic Rutile, ISIJ International, 50(5), 647-653.
  • FILIPPOU, D. AND HUDON, G. 2009. Iron removal and recovery in the titanium dioxide feedstock and pigment industries. JOM, 61(10), 36-42.
  • FRANCIS A.A., AND EL-MIDANY, A.A., 2008. An assessment of carbothermic reduction of ilmenite ore by statistical design. J. Mater. Process. Techno. 199, 279-286.
  • GÁZQUEZ, M. J., BOLÍVAR, J. P., GARCIA-TENORIO, R., VACA, F. 2014. A review of the production cycle of titanium dioxide pigment. Mater. Sci. and App. 5, 441.
  • GEETHA, K. S. AND SURENDER, G. D. 2000. Experimental and modelling studies on the aeration leaching process for metallic iron removal in the manufacture of synthetic rutile. Hydrometallurgy, 56, 41-62.
  • HAIDER, A.J., JAMEEL, Z.N., AL-HUSSAINI, I.H.M.,2019. Review on titanium dioxide applications. Energy Procedia. 17-29.
  • HASNIYATI, M. R., ZUHAILAWATI, H., RAMAKRISHNAN, S., HAMID, S. A. R. S. A. 2014. Mechanism and optimisation of titanium carbide-reinforced iron composite formation through carbothermal reduction of hematite and anatase. J. Ally. and Comp., 587, 442–450. https://doi.org/10.1016/j.jallcom.2013.10.245
  • HEIKEN, G., RAMOS, N., DUFFIELD, W., MUSGRAVE, J., WOHLETZ, K., PRIEST, S., ALDRICH, J., FLORES, W.,
  • RITCHIE, A., GOFF, F., EPPLER, D.,ESCOBAR, C. 1991. geology of the platanares geothermal area, departamento de copán, honduras. J. Volcano. and Geothe. Res. 45, 41-58.
  • IBRAHIM, N., AHMADI, E., ABDUL RAHMAN, S., AHMAD FAUZI, M.N., REZAN, S.A., 2017.Extraction of titanium from low iron nitrided Malaysia Ilmenite by chlorination. AIP Conference Proceeding 1805.
  • MONTGOMERY, D.C., 2009. Design and analysis of experiments. 7th ed. NJ: John Wiley& Sons,Inc.
  • NGUYEN, T.H., LEE, M.S., 2019. A Review on the Recovery of Titanium Dioxide from Ilmenite Ores by Direct Leaching Technologies. Min. Pro. and Ex. Metall. Rev. 40:4, 231-247.
  • REZAN, S. A., ZHANG, G. & OSTROVSKI, O. 2012a. Effect Of Gas Atmosphere On Carbothermal Reduction And Nitridation Of Titanium Dioxide. Metall. and Mater. Trans. B. 43, 73-81.
  • REZAN, S. A., ZHANG, G. & OSTROVSKI, O. 2012b. Phase development in carbothermal reduction and nitridation of ilmenite concentrates. High Temp. Mater. Pro., 43, 73-81.
  • SAIDIN, H. S., S. A. S. SALIM, HUSSAIN, H., REZAN, S.A.S.A.H., BAHARUN,N. 2014. An Assessment of the Carbothermal Reduction of Malaysian Ilmenite by Statistical Design. Adv. Mater. Res. 858, 221-227.
  • SANJIT, U., CHOONG, K.W., SIVAKUMAR, R., FAUZI, M.N.A., REZAN, S.A. 2019. Kinetic modelling of oxidation of metallic iron to iron sulfate from iron-titanium oxycarbonitride composite. Materials Today: Proceeding 17, 525-533.
  • SHARIFAH, A. S. S., SAIDIN, H. S., BAHARUN, N., REZAN, S. A., & HASHIM, H. 2013. Microstructural Study of Reduced Malaysian Ilmenite by Carbothermal Reduction and Nitridation in Nitrogen Atmosphere. Adv. Mater. Re. 858, 265–271.
  • SHAHIEN, M.G., KHEDR,M.M.H, MAURICE, A.E., FARGHALI A.A.,ALI, R.A.M.,2015. Synthesis of high purity rutile nanoparticles from medium grade Egyptian natural ilmenite. Beni-Seuf University Journal of Basic and Applied Science. 207-213.
  • TRUONG,T.N.,NGUYEN,T.T, DUONG,B.N. 2017. Acetic acid and sodium acetate mixtures as an aeration catalyst in the removal of metallic iron in reduced ilmenite. Acta Metall. Slovaca. 23, 371-377.
  • WANG, X., LI, C., YUE, H., YUAN, S., LIU, C., TANG, S., LIANG, B., 2018. Effects of mechanical activation on the digestion of ilmenite in dilute H2SO4. Chin.J.Chem.Eng., 2019, 27, 575-586.
  • WARREN J., BRUCKARD, C.C., FLETCHER, S., HORNE, M.D, URBAN A.J. 2004. The Application Of Anthraquinone Redox Catalysts For Accelerating The Aeration Step In The Becher Process. Hydrometallurgy, 73, 111-121.
  • XIANG,J., PEI, G., LV, W., LIU, S., LV, X., QIU, Q. 2020. Preparation of synthetic rutile from reduced ilmenite through the aeration leaching process. Chem. Eng. & Pro.: Pro. Intensific. 147, 1-9.
  • YAAKUB, K.N.H. AND A.H.A. RAHMAN, Kajian Potensi Sumber Ilmenite Di Sungai Cheniah Bukit Kelip, Hulu Dungun, Terengganu, in Rancangan Malaysia ke sepuluh. Projek mineral berlogam semenanjung. 2014: Kuala Terengganu. p. 10
  • YARAGHI,A., SAPRI, A., AHMADI,E., BAHARUN,N., REZAN, S.A., SHOPARWE, N.I., RAMAKRISHNAN, S., ARIFFIN, K.S., AHMAD FAUZI, M.N., ZABIDI, H., ISMAIL,H., HAZMAN H.S., 2011. Microstructural Study of Leached Nitrided Malaysian Ilmenite with Coal-Polystyrene Reductant. Key Engineering Materials. 701, 132-137.
  • YIN, T.W., RAMAKRISHNAN, S., ABDUL REZAN, S., MOHD NOOR, A.F., SHOPARWE N.I., , ALIZADEH, R.,ROOHI, R. 2017. Kinetic modeling of liquefied petroleum gas (LPG) reduction of titania in MATLAB. J. of Phy.: Conf. Series, 822, doi:10.1088/1742-6596/822/1/012063.
  • ZHANG, W., ZHU, Z., CHENG, C.Y. 2011. A Literature Review Of Titanium Metallurgical Processes. Hydrometallurgy, 108, 177-188.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a329360f-0563-43b4-a1bb-f7867f0154b9
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