Excess Molar Volumes, Intermolecular Free Lengths, Adiabatic Compressibilities and Acoustic Impedance of Binary Mixtures of Anisole, Toluene and Ethylbenzene with Dioxane at Different Temperatures

• Autorzy: Dahire S. L. , Morey Y. C. , Agrawal P. S.

Identyfikatory

DOI

10.18052/www.scipress.com/ILCPA.42.72

• Języki publikacji: EN

Abstrakty

EN

The present study reports densities (ρ), viscosities (η) and ultrasonic speeds (U) of pure dioxane (DOX), anisole (ANS), toluene (TOL) and ethylbenzene (ETB) and their binary liquid mixtures over the entire composition range at 293, 298, 303, 308 and 313 K. From the experimental data excess molar volume (VmE), excess intermolecular free length (LfE), excess adiabatic compressibility (β^E) and excess acoustic impedance (Z^E) have been computed. The excess values were correlated using Redlitch-Kister polynomial equation to obtain their coefficients and standard deviations (σ). With increase in temperature, the binary mixture of DOX+ANS shows larger deviations in βE, LfE and smaller deviations in Z<^E, Vm^E. These results suggest that ANS has strong molecular interactions with DOX than ETB and TOL.

Słowa kluczowe

EN

Acoustical Properties; Excess Parameters; Redlich-Kister polynomial equation; Dioxane and Binary liquid mixtures

• Wydawca: Przedsiębiorstwo Wydawnictw Naukowych "DARWIN"
• Czasopismo: International Letters of Chemistry, Physics and Astronomy
• Rocznik: 2015
• Tom: Vol. 42
• Strony: 72--83
• Opis fizyczny: Bibliogr. 24 poz., rys., tab.

Twórcy

autor

Dahire S. L.

• Department of Chemistry, Sindhu Mahavidyalaya, Nagpur, India

autor

Morey Y. C.

• Department of Chemistry, Hislop College, Nagpur, India

autor

Agrawal P. S.

• Laxminarayan Institute of Technology, Nagpur, India

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